CHEMISTRY (LL) W/CNCT >BI<
13th Edition
ISBN: 9781260572384
Author: Chang
Publisher: MCG
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Chapter 17, Problem 17.55QP
Interpretation Introduction
Interpretation:
In which conditions a substance has standard entropy of zero and negative has to be determined.
Concept Introduction:
Spontaneous process: A process which is initiated by itself, without the help of external energy source is called spontaneous process. All spontaneous process is associated with the decrease in free energy in the system.
First law of
Second law of thermodynamics: According to second law of thermodynamics, the entropy of the universe is the sum of the entropy of the system and the surroundings. For all spontaneous process the entropy of the universe increases.
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Draw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw
structure" button to launch the drawing utility.
draw structure ...
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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Chapter 17 Solutions
CHEMISTRY (LL) W/CNCT >BI<
Ch. 17.3 - How does the entropy of a system change for each...Ch. 17.3 - For which of the following physical changes is S...Ch. 17.3 - Determine if the sign for S is positive or...Ch. 17.4 - Prob. 2PECh. 17.4 - Prob. 3PECh. 17.4 - Calculate the standard entropy change for the...Ch. 17.4 - Consider the gas-phase reaction of A2 (blue) and...Ch. 17.5 - Prob. 4PECh. 17.5 - The molar heats of fusion and vaporization of...Ch. 17.5 - Under what circumstances will an endothermic...
Ch. 17.5 - Prob. 2RCFCh. 17.5 - Prob. 3RCFCh. 17.5 - Prob. 4RCFCh. 17.6 - Calculate the equilibrium constant (KP) for the...Ch. 17.6 - Prob. 7PECh. 17.6 - Prob. 8PECh. 17.6 - A reaction has a positive H and a negative S.Is...Ch. 17.6 - For the reaction A(g)+B(g)C(g) G = 33.3 kJ/mol at...Ch. 17.6 - For the reaction C(aq)A(aq)+B(aq) G = 1.95 kJ/mol...Ch. 17 - Explain what is meant by a spontaneous process....Ch. 17 - State which of the following processes are...Ch. 17 - Prob. 17.3QPCh. 17 - Define entropy. What are the units of entropy?Ch. 17 - How does the entropy of a system change for each...Ch. 17 - State the second law of thermodynamics in words...Ch. 17 - State the third law of thermodynamics and explain...Ch. 17 - For each pair of substances listed here, choose...Ch. 17 - Arrange the following substances (1 mole each) in...Ch. 17 - Using the data in Appendix 2, calculate the...Ch. 17 - Using the data in Appendix 2, calculate the...Ch. 17 - Without consulting Appendix 2, predict whether the...Ch. 17 - Prob. 17.14QPCh. 17 - Define free energy. What are its units?Ch. 17 - Why is it more convenient to predict the direction...Ch. 17 - Calculate G for the following reactions at 25C:...Ch. 17 - Calculate G for the following reactions at 25C:...Ch. 17 - From the values of H and S, predict which of the...Ch. 17 - Find the temperatures at which reactions with the...Ch. 17 - Explain the difference between G and G.Ch. 17 - Explain why Equation (17.14). is of great...Ch. 17 - Calculate KP for the following reaction at 25C:...Ch. 17 - For the autoionization of water at 25C,...Ch. 17 - Consider the following reaction at 25C:...Ch. 17 - Calculate G and KP for the following equilibrium...Ch. 17 - (a) Calculate G and KP for the following...Ch. 17 - The equilibrium constant (KP) for the reaction...Ch. 17 - Consider the decomposition of calcium carbonate:...Ch. 17 - The equilibrium constant KP for the reaction...Ch. 17 - At 25C, G for the process H2O(l)H2O(g) is 8.6...Ch. 17 - Calculate G for the process C(diamond)C(graphite)...Ch. 17 - What is a coupled reaction? What is its importance...Ch. 17 - What is the role of ATP in biological reactions?Ch. 17 - Referring to the metabolic process involving...Ch. 17 - In the metabolism of glucose, the first step is...Ch. 17 - Explain the following nursery rhyme in terms of...Ch. 17 - Calculate G for the reaction H2O(l)H+(aq)+OH(aq)...Ch. 17 - Calculate the Ssoln for the following processes:...Ch. 17 - The following reaction is spontaneous at a certain...Ch. 17 - Which of the following thermodynamic functions are...Ch. 17 - A student placed 1 g of each of three compounds A,...Ch. 17 - Use the data in Appendix 2 to calculate the...Ch. 17 - Predict the signs of H, S, and G of the system for...Ch. 17 - Prob. 17.45QPCh. 17 - Ammonium nitrate (NH4NO3) dissolves spontaneously...Ch. 17 - Calculate the equilibrium pressure of CO2 due to...Ch. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Carbon monoxide (CO) and nitric oxide (NO) are...Ch. 17 - Prob. 17.51QPCh. 17 - Use the thermodynamic data in Appendix 2 to...Ch. 17 - Consider the reaction A B + C at 298 K. Given...Ch. 17 - The Ksp of AgCl is given in Table 16.2. What is...Ch. 17 - Prob. 17.55QPCh. 17 - Water gas, a mixture of H2 and CO, is a fuel made...Ch. 17 - Consider the following Brnstead acid-base reaction...Ch. 17 - Crystallization of sodium acetate from a...Ch. 17 - Prob. 17.59QPCh. 17 - A certain reaction is spontaneous at 72C. If the...Ch. 17 - Predict whether the entropy change is positive or...Ch. 17 - 17.62The reaction NH3(g)+HCl(g)NH4Cl(s) proceeds...Ch. 17 - Prob. 17.63QPCh. 17 - The molar heat of vaporization of ethanol is 39.3...Ch. 17 - Prob. 17.65QPCh. 17 - In the Mond process for the purification of...Ch. 17 - Calculate G and KP for the following processes at...Ch. 17 - Calculate the pressure of O2 (in atm) over a...Ch. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Consider the reaction N2(g)+O2(g)2NO(g) Given that...Ch. 17 - Prob. 17.72QPCh. 17 - Prob. 17.73QPCh. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - Prob. 17.76QPCh. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - Prob. 17.84QPCh. 17 - Shown here are the thermodynamic data for ethanol:...Ch. 17 - The reaction shown here is spontaneous at a...Ch. 17 - Consider two carboxylic acids (acids that contain...Ch. 17 - Many hydrocarbons exist as structural isomers,...Ch. 17 - Use the thermodynamic data in Appendix 2 to...Ch. 17 - A rubber band is stretched vertically by attaching...Ch. 17 - One of the steps in the extraction of iron from...Ch. 17 - Derive the equation G=RTln(Q/K) where Q is the...Ch. 17 - The sublimation of carbon dioxide at 78C is...Ch. 17 - Entropy has sometimes been described as times...Ch. 17 - Referring to Figure 17.1, we see that the...Ch. 17 - A student looked up the Gf, Hf, and S values for...Ch. 17 - Consider the following reaction at 298 K:...Ch. 17 - As an approximation, we can assume that proteins...Ch. 17 - Which of the following are not state functions: S,...Ch. 17 - Which of the following is not accompanied by an...Ch. 17 - Hydrogenation reactions (for example, the process...Ch. 17 - Give a detailed example of each of the following,...Ch. 17 - At 0 K, the entropy of carbon monoxide crystal is...Ch. 17 - Comment on the correctness of the analogy...Ch. 17 - The standard enthalpy of formation and the...Ch. 17 - In chemistry, the standard state for as solution...Ch. 17 - The following diagram shows the variation of the...Ch. 17 - Consider the gas-phase reaction between A2 (green)...Ch. 17 - The KP for the reaction N2+3H22NH3 is 2.4 103 at...Ch. 17 - The table shown here lists the ion-product...Ch. 17 - Draw the missing distributions in Figure 17.2....Ch. 17 - The reaction NH3(g)+HCl(g)NH4Cl(s) is spontaneous...Ch. 17 - The boiling point of diethyl ether is 34.6C....Ch. 17 - Nicotine is the compound in tobacco responsible...Ch. 17 - Estimate S for the process depicted in Figure...Ch. 17 - At what point in the series HOnH(g) (n = 1, 2, 3,...
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