The following structural characteristics are to be matched with their respective polysaccharide. a. Contains both α ( 1 → 4 ) and α ( 1 → 6 ) glycosidic linkages b. is composed of glucose monosaccharide units c. Contains acetal linkages between monosaccharide units d. is composed of highly branched molecular chains e. is composed of unbranched molecular chains f. Contains only α ( 1 → 4 ) glycosidic linkages g. Contains only β ( 1 → 4 ) glycosidic linkages Concept introduction: A large molecule formed by combining the multiple numbers of monosaccharides is called polysaccharide. These monosaccharides can be same, known as homo-polysaccharide, or different, known as hetero-polysaccharides. A molecule with a straight chain is called linear polysaccharide and that with a branched chain is called a branched polysaccharide.

Question

Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9

Answer 1

Question

Chapter 17, Problem 17.53E

Interpretation Introduction

Interpretation:

The following structural characteristics are to be matched with their respective polysaccharide.

a. Contains both α(1→4) and α(1→6) glycosidic linkages

b. is composed of glucose monosaccharide units

c. Contains acetal linkages between monosaccharide units

d. is composed of highly branched molecular chains

e. is composed of unbranched molecular chains

f. Contains only α(1→4) glycosidic linkages

g. Contains only β(1→4) glycosidic linkages

Concept introduction:

A large molecule formed by combining the multiple numbers of monosaccharides is called polysaccharide. These monosaccharides can be same, known as homo-polysaccharide, or different, known as hetero-polysaccharides. A molecule with a straight chain is called linear polysaccharide and that with a branched chain is called a branched polysaccharide.

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Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9

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