(a) Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn. Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are: 1. When the ring is mono-substituted, then there is no need of numbering. 2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number. 3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority. 4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Question

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Answer 1

Question

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 2

Question

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

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Answer 3

Question

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

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Answer 4

Question

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

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Answer 5

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

Answer 6

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Answer 7

Chapter 17, Problem 17.4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 8

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 1

Figure 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The IUPAC name of the compound is isobutyl benzene. The parent ring is benzene. 2-methylpropyl is isobutyl group which is present on first carbon. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 2

Figure 1

Answer 13

Conclusion

The structure corresponding to given compound is shown in Figure 1.

Answer 14

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Answer 15

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 16

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 3

Figure 2

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The IUPAC name of the compound is o-dichlorobenzene. The parent ring is benzene. Two chlorine atoms are adjacent to each other in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 4

Figure 2

Answer 21

Conclusion

The structure corresponding to given compound is shown in Figure 2.

Answer 22

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Answer 23

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 24

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 5

Figure 3

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The IUPAC name of the compound is cis-l, 2-diphenylcyclohexane. The parent compound is cyclohexane. Two phenyl groups are present on first and second carbon atom. The orientation of these rings is in the same direction. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 6

Figure 3

Answer 29

Conclusion

The structure corresponding to given compound is shown in Figure 3.

Answer 30

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Answer 31

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 32

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 7

Figure 4

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The IUPAC name of the compound is m-bromoaniline. The parent ring is aniline. Bromine atom is present on third carbon atom i.e. meta position. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 8

Figure 4

Answer 37

Conclusion

The structure corresponding to given compound is shown in Figure 4.

Answer 38

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Answer 39

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 40

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 9

Figure 5

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

The IUPAC name of the compound is 4-chloro-1, 2-diethylbenzene. The parent ring is benzene. Chlorine atom is present on forth carbon and two ethyl groups are present on first and second carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 10

Figure 5

Answer 45

Conclusion

The structure corresponding to given compound is shown in Figure 5.

Answer 46

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6

Conclusion

The structure corresponding to given compound is shown in Figure 6.

Answer 47

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 48

Expert Solution

Answer to Problem 17.4P

The structure corresponding to given compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 11

Figure 6

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

The IUPAC name of the compound is 3-tert-butyl-2-ethyltoluene. The parent ring is toluene. Ethyl group is present on second carbon and ethyl group is present on third carbon in benzene ring. Hence, the structure of the compound is,

Organic Chemistry, Chapter 17, Problem 17.4P , additional homework tip 12

Figure 6