Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
Question
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Chapter 17, Problem 17.41P

(a)

Interpretation Introduction

Interpretation:

The half reaction for upper plateau and lower plateau of given graph has to be written.

Concept introduction:

Half reaction is one of oxidation or reduction in redox reaction.  Half reaction is given by oxidation state change in reactants or products in redox reaction.

(b)

Interpretation Introduction

Interpretation:

The radius of microelectrode in cyclic voltammetry for ferrocyanide has to be calculated.

Concept introduction:

Limiting current is given as

Ilimit=4nFDCr

r is radius of electrode.

D is diffusion coefficient.

C is analyte’s concentration

F is faraday constant.

n is number of electrons transported in half reaction.

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