The validation of the statement that the equation 17.54 is observed by simplifying the expression immediately before it is to be stated. Concept introduction: The partition function of a system is given by the formula, q = ( 2 π m k T h 2 ) 3 / 2 ⋅ V Where, • h is Plank’s constant. • m is the mass. • T is the temperature. • V is the volume.

Question

Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)

Answer 1

Question

Chapter 17, Problem 17.40E

Interpretation Introduction

Interpretation:

The validation of the statement that the equation 17.54 is observed by simplifying the expression immediately before it is to be stated.

Concept introduction:

The partition function of a system is given by the formula,

q=(2πmkTh2)3/2⋅V

Where,

• h is Plank’s constant.

• m is the mass.

• T is the temperature.

• V is the volume.

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Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)

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