CHEMISTRY(LOOSELEAF) W/CONNECT+EBOOK
7th Edition
ISBN: 9781259712500
Author: SILBERBERG
Publisher: MCG CUSTOM
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Chapter 17, Problem 17.3P
Interpretation Introduction
Interpretation:
The reason why the equilibrium state is state is considered dynamic when there is no change in concentration has to be explained.
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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
Chapter 17 Solutions
CHEMISTRY(LOOSELEAF) W/CONNECT+EBOOK
Ch. 17.2 - Write the reaction quotient, Qc, for each of the...Ch. 17.2 - Prob. 17.1BFPCh. 17.2 - The following sequence of steps has been proposed...Ch. 17.2 - Prob. 17.2BFPCh. 17.2 - Prob. 17.3AFPCh. 17.2 - Prob. 17.3BFPCh. 17.3 - Calculate Kp for the following reaction:
PCl3(g) +...Ch. 17.3 - Calculate Kc for the following reaction:
CS2(g) +...Ch. 17.4 - At 338 K, the reaction X(g) ⇌ Y(g) has a Kc of...Ch. 17.4 - Prob. 17.5BFP
Ch. 17.5 - Prob. 17.6AFPCh. 17.5 - Prob. 17.6BFPCh. 17.5 - Prob. 17.7AFPCh. 17.5 - Prob. 17.7BFPCh. 17.5 - Prob. 17.8AFPCh. 17.5 - Prob. 17.8BFPCh. 17.5 - Prob. 17.9AFPCh. 17.5 - Prob. 17.9BFPCh. 17.5 - Prob. 17.10AFPCh. 17.5 - Prob. 17.10BFPCh. 17.5 - An inorganic chemist studying the reactions of...Ch. 17.5 - A chemist studying the production of nitrogen...Ch. 17.6 - In a study of glass etching, a chemist examines...Ch. 17.6 - Prob. 17.12BFPCh. 17.6 - Prob. 17.13AFPCh. 17.6 - Prob. 17.13BFPCh. 17.6 - Prob. 17.14AFPCh. 17.6 - Should T be increased or decreased to yield more...Ch. 17.6 - Prob. 17.15AFPCh. 17.6 - Prob. 17.15BFPCh. 17.6 - Many metabolites are products in branched...Ch. 17 - Prob. 17.1PCh. 17 - When a chemical company employs a new reaction to...Ch. 17 - If there is no change in concentrations, why is...Ch. 17 - Prob. 17.4PCh. 17 - Prob. 17.5PCh. 17 - Prob. 17.6PCh. 17 - Prob. 17.7PCh. 17 - Prob. 17.8PCh. 17 - Prob. 17.9PCh. 17 - Does Q for the formation of 1 mol of NO from its...Ch. 17 - Does Q for the formation of 1 mol of NH3 from H2...Ch. 17 - Balance each reaction and write its reaction...Ch. 17 - Prob. 17.13PCh. 17 - Prob. 17.14PCh. 17 - Prob. 17.15PCh. 17 - At a particular temperature, Kc = 1.6×10−2...Ch. 17 - Prob. 17.17PCh. 17 - Balance each of the following examples of...Ch. 17 - Balance each of the following examples of...Ch. 17 - Balance each of the following examples of...Ch. 17 - Balance each of the following examples of...Ch. 17 - Prob. 17.22PCh. 17 - Prob. 17.23PCh. 17 - Prob. 17.24PCh. 17 - When are Kc and Kp equal, and when are they not?
Ch. 17 - A certain reaction at equilibrium has more moles...Ch. 17 - Prob. 17.27PCh. 17 - Determine Δngas for each of the following...Ch. 17 - Prob. 17.29PCh. 17 - Prob. 17.30PCh. 17 - Prob. 17.31PCh. 17 - Prob. 17.32PCh. 17 - Prob. 17.33PCh. 17 - The following molecular scenes depict the aqueous...Ch. 17 - At 425°C, Kp = 4.18 × 10−9 for the...Ch. 17 - At 100°C, Kp = 60.6 for the reaction
2NOBr(g) ⇌...Ch. 17 - The water-gas shift reaction plays a central role...Ch. 17 - In the 1980s, CFC-11 was one of the most heavily...Ch. 17 - For a problem involving the catalyzed reaction of...Ch. 17 - What is the basis of the approximation that avoids...Ch. 17 - Prob. 17.41PCh. 17 - Gaseous ammonia was introduced into a sealed...Ch. 17 - Prob. 17.43PCh. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - Prob. 17.46PCh. 17 - Prob. 17.47PCh. 17 - Prob. 17.48PCh. 17 - Prob. 17.49PCh. 17 - Nitrogen dioxide decomposes according to the...Ch. 17 - Hydrogen iodide decomposes according to the...Ch. 17 - Compound A decomposes according to the...Ch. 17 - In an analysis of interhalogen reactivity, 0.500...Ch. 17 - A toxicologist studying mustard gas, S(CH2CH2Cl)2,...Ch. 17 - Prob. 17.55PCh. 17 - A key step in the extraction of iron from its ore...Ch. 17 - What does “disturbance” mean in Le Châtelier’s...Ch. 17 - Prob. 17.58PCh. 17 - Prob. 17.59PCh. 17 - Prob. 17.60PCh. 17 - Le Châtelier’s principle is related ultimately to...Ch. 17 - An equilibrium mixture of two solids and a gas, in...Ch. 17 - Consider this equilibrium system:
CO(g) + Fe3O4(s)...Ch. 17 - Sodium bicarbonate undergoes thermal decomposition...Ch. 17 - Prob. 17.65PCh. 17 - Prob. 17.66PCh. 17 - Predict the effect of decreasing the container...Ch. 17 - Prob. 17.68PCh. 17 - Prob. 17.69PCh. 17 - Prob. 17.70PCh. 17 - Prob. 17.71PCh. 17 - Prob. 17.72PCh. 17 - Prob. 17.73PCh. 17 - The formation of methanol is important to the...Ch. 17 - Prob. 17.75PCh. 17 - The oxidation of SO2 is the key step in H2SO4...Ch. 17 - A mixture of 3.00 volumes of H2 and 1.00 volume of...Ch. 17 - You are a member of a research team of chemists...Ch. 17 - For the following equilibrium system, which of the...Ch. 17 - Prob. 17.80PCh. 17 - Prob. 17.81PCh. 17 - Prob. 17.82PCh. 17 - Prob. 17.83PCh. 17 - Prob. 17.84PCh. 17 - Prob. 17.85PCh. 17 - Prob. 17.86PCh. 17 - Prob. 17.87PCh. 17 - Prob. 17.88PCh. 17 - When 0.100 mol of CaCO3(s) and 0.100 mol of CaO(s)...Ch. 17 - Prob. 17.90PCh. 17 - Prob. 17.91PCh. 17 - Prob. 17.92PCh. 17 - Highly toxic disulfur decafluoride decomposes by a...Ch. 17 - A study of the water-gas shift reaction (see...Ch. 17 - Prob. 17.95PCh. 17 - Prob. 17.96PCh. 17 - Prob. 17.97PCh. 17 - Prob. 17.98PCh. 17 - Prob. 17.99PCh. 17 - Prob. 17.100PCh. 17 - The molecular scenes below depict the reaction Y ⇌...Ch. 17 - For the equilibrium
H2S(g) ⇌ 2H2(g) + S2(g) Kc =...Ch. 17 - Prob. 17.103PCh. 17 - Prob. 17.104PCh. 17 - The kinetics and equilibrium of the decomposition...Ch. 17 - Isopentyl alcohol reacts with pure acetic acid to...Ch. 17 - Isomers Q (blue) and R (yellow) interconvert. They...Ch. 17 - Glauber’s salt, Na2SO4·10H2O, was used by J. R....Ch. 17 - Prob. 17.109PCh. 17 - Synthetic diamonds are made under conditions of...
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