Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 17, Problem 17.38CP
Interpretation Introduction
Interpretation:
We need to understand the changes of (A ? B) in the given pictures and accordingly we have to find out will the change be an exothermic reaction or endothermic reaction.
Concept Introduction:
If the temp of the reaction rises on going forward then the reaction will be an exothermic reaction and in case of an exothermic reaction the change of enthalpy (δH) is negative.
To determine:
To determine the value of δH0&?S0 for the forward reaction i.e A ? B
Given:
δH0&?S0 are not dependent on temperature.
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1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
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CN
Chapter 17 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 17 - Prob. 17.1PCh. 17 - Prob. 17.2PCh. 17 - Prob. 17.3ACh. 17 - Prob. 17.4PCh. 17 - Prob. 17.5PCh. 17 - Prob. 17.6ACh. 17 - Prob. 17.7PCh. 17 - Prob. 17.8ACh. 17 - Prob. 17.9PCh. 17 - APPLY 17.10 Use the values of Hf and S in Appendix...
Ch. 17 - Prob. 17.11PCh. 17 - Conceptual APPLY 17.12 What are the signs (+, -,...Ch. 17 - PRACTICE 17.13 Consider the thermal decomposition...Ch. 17 - Prob. 17.14ACh. 17 - Prob. 17.15PCh. 17 - Prob. 17.16ACh. 17 - Prob. 17.17PCh. 17 - Prob. 17.18ACh. 17 - Prob. 17.19PCh. 17 - Prob. 17.20ACh. 17 - Prob. 17.21PCh. 17 - APPLY 17.22 If the vapour pressure of ethanol (...Ch. 17 - Prob. 17.23PCh. 17 - Prob. 17.24PCh. 17 - Prob. 17.25PCh. 17 - Prob. 17.26PCh. 17 - Prob. 17.27PCh. 17 - 17.28 Consider the gas-phase reaction of AB3 and...Ch. 17 - 17.29 Ideal gases A (red spheres) and B (blue...Ch. 17 - What are the signs (+, —, or 0) of H, S, and G...Ch. 17 - Prob. 17.31CPCh. 17 - Prob. 17.32CPCh. 17 - 17.33 Consider the following spontaneous reaction...Ch. 17 - Prob. 17.34CPCh. 17 - Consider again the dissociation reaction A2g 2...Ch. 17 - Prob. 17.36CPCh. 17 - Prob. 17.37CPCh. 17 - Prob. 17.38CPCh. 17 - Prob. 17.39CPCh. 17 - Which of the following processes are spontaneous,...Ch. 17 - Prob. 17.41SPCh. 17 - Assuming that gaseous reactants and products are...Ch. 17 - Prob. 17.43SPCh. 17 - Prob. 17.44SPCh. 17 - Prob. 17.45SPCh. 17 - 17.46 Predict the sign of the entropy change in...Ch. 17 - Predict the sign of S in the system for each of...Ch. 17 - Prob. 17.48SPCh. 17 - Prob. 17.49SPCh. 17 - Prob. 17.50SPCh. 17 - Prob. 17.51SPCh. 17 - Prob. 17.52SPCh. 17 - Prob. 17.53SPCh. 17 - Prob. 17.54SPCh. 17 - Prob. 17.55SPCh. 17 - Prob. 17.56SPCh. 17 - Prob. 17.57SPCh. 17 - Prob. 17.58SPCh. 17 - Prob. 17.59SPCh. 17 - Prob. 17.60SPCh. 17 - Prob. 17.61SPCh. 17 - Prob. 17.62SPCh. 17 - Prob. 17.63SPCh. 17 - Prob. 17.64SPCh. 17 - Prob. 17.65SPCh. 17 - Prob. 17.66SPCh. 17 - Prob. 17.67SPCh. 17 - Prob. 17.68SPCh. 17 - Prob. 17.69SPCh. 17 - Prob. 17.70SPCh. 17 - Prob. 17.71SPCh. 17 - Prob. 17.72SPCh. 17 - Prob. 17.73SPCh. 17 - Prob. 17.74SPCh. 17 - Prob. 17.75SPCh. 17 - Prob. 17.76SPCh. 17 - Prob. 17.77SPCh. 17 - Prob. 17.78SPCh. 17 - Prob. 17.79SPCh. 17 - Prob. 17.80SPCh. 17 - Prob. 17.81SPCh. 17 - Prob. 17.82SPCh. 17 - Prob. 17.83SPCh. 17 - Prob. 17.84SPCh. 17 - Prob. 17.85SPCh. 17 - Prob. 17.86SPCh. 17 - Prob. 17.87SPCh. 17 - Prob. 17.88SPCh. 17 - Prob. 17.89SPCh. 17 - Prob. 17.90SPCh. 17 - Prob. 17.91SPCh. 17 - Use the data in Appendix B to calculate H° and ...Ch. 17 - Prob. 17.93SPCh. 17 - Prob. 17.94SPCh. 17 - Prob. 17.95SPCh. 17 - Prob. 17.96SPCh. 17 - Prob. 17.97SPCh. 17 - Use the values of G°, in Appendix B to calculate...Ch. 17 - Prob. 17.99SPCh. 17 - Prob. 17.100SPCh. 17 - Prob. 17.101SPCh. 17 - Prob. 17.102SPCh. 17 - Prob. 17.103SPCh. 17 - Prob. 17.104SPCh. 17 - Prob. 17.105SPCh. 17 - Prob. 17.106SPCh. 17 - Prob. 17.107SPCh. 17 - Prob. 17.108SPCh. 17 - Prob. 17.109SPCh. 17 - Prob. 17.110SPCh. 17 - Prob. 17.111SPCh. 17 - Prob. 17.112SPCh. 17 - Prob. 17.113SPCh. 17 - Prob. 17.114SPCh. 17 - Prob. 17.115SPCh. 17 - Prob. 17.116SPCh. 17 - Prob. 17.117SPCh. 17 - Prob. 17.118SPCh. 17 - Prob. 17.119SPCh. 17 - Prob. 17.120CPCh. 17 - Prob. 17.121CPCh. 17 - Prob. 17.122CPCh. 17 - Prob. 17.123CPCh. 17 - Prob. 17.124CPCh. 17 - Prob. 17.125CPCh. 17 - Prob. 17.126CPCh. 17 - Prob. 17.127CPCh. 17 - Prob. 17.128CPCh. 17 - Prob. 17.129CPCh. 17 - Prob. 17.130CPCh. 17 - Use the data in Appendix B to calculate H°, S°,...Ch. 17 - Prob. 17.132CPCh. 17 - Prob. 17.133CPCh. 17 - Nickel tetracarbonyl, a volatile liquid used to...Ch. 17 - Prob. 17.135CPCh. 17 - Prob. 17.136CPCh. 17 - Prob. 17.137CPCh. 17 - Prob. 17.138CPCh. 17 - Prob. 17.139CPCh. 17 - Prob. 17.140CPCh. 17 - Prob. 17.141CPCh. 17 - Prob. 17.142CPCh. 17 - Prob. 17.143CPCh. 17 - Prob. 17.144CPCh. 17 - Prob. 17.145CPCh. 17 - Prob. 17.146CPCh. 17 - Consider the equilibriumN2O42NO2g. (a) Use the...Ch. 17 - Prob. 17.148MPCh. 17 - Prob. 17.149MPCh. 17 - Prob. 17.150MPCh. 17 - Prob. 17.151MPCh. 17 - Prob. 17.152MPCh. 17 - Prob. 17.153MPCh. 17 - Prob. 17.154MPCh. 17 - Prob. 17.155MP
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