Bundle: Physical Chemistry, 2nd + Student Solutions Manual
Bundle: Physical Chemistry, 2nd + Student Solutions Manual
2nd Edition
ISBN: 9781285257594
Author: David W. Ball
Publisher: Cengage Learning
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Chapter 17, Problem 17.15E
Interpretation Introduction

Interpretation:

The different distinguishable distributions for total system energy of 5EU is to be stated and equation 17.7 for the occupation numbers is to be verified.

Concept introduction:

The thermodynamic state of a large microscopic system is understood using the statistical thermodynamics. The large microscopic system is separated into tiny parts known as microsystems. Each microsystem is defined by the parameters known as microstates of that system.

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Given the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism:  1) NO + NO ⇄ N2O2 (fast);   2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
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Chapter 17 Solutions

Bundle: Physical Chemistry, 2nd + Student Solutions Manual

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