1 Introduction: Matter, Energy, And Measurement 2 Atoms, Molecules, And Ions 3 Chemical Reactions And Reaction Stoichiometry 4 Reactions In Aqueous Solution 5 Thermochemistry 6 Electronic Structure Of Atoms 7 Periodic Properties Of The Elements 8 Basic Concepts Of Chemical Bonding 9 Molecular Geometry And Bonding Theories 10 Gases 11 Liquids And Intermolecular Forces 12 Solids And Modern Materials 13 Properties Of Solutions 14 Chemical Kinetics 15 Chemical Equilibrium 16 Acid—base Equilibrium 17 Additional Aspects Of Aqueous Equilibrium 18 Chemistry Of The Environment 19 Chemical Thermodynamics 20 Electrochemistry 21 Nuclear Chemistry 22 Chemistry Of The Nonmetals 23 Transition Metals And Coordination Chemistry 24 The Chemistry Of Life: Organic And Biological Chemistry expand_more
17.1 The Common Ion Effect 17.2 Buffers 17.3 Acid-base Titrations 17.4 Solubility Equilibria 17.5 Factor That Affect Solubility 17.6 Precipitation And Separation Of Ions 17.7 Qualitative Analysis For Metallic Elements Chapter Questions expand_more
Problem 1DE Problem 1E: The following boxes represent aqueos solutions containing a weak acid, HA and its conjugate base,... Problem 2E Problem 3E Problem 4E Problem 5E Problem 6E Problem 7E Problem 8E Problem 9E: 17.9 The following graphs represent the behavior of BaCO3 under different circumstances. In each... Problem 10E Problem 11E: 17.11 The graph below shows the solubility of a salt as a function of pH. Which of the following... Problem 12E: 17.12 Three cations, Ni+2, Cu+2, and Ag+, are separated using two different precipitating agents.... Problem 13E Problem 14E Problem 15E Problem 16E: Use information from Appendix D to calculate the pH of a solution that is 0.250 M in sodium formate... Problem 17E Problem 18E: a. calculate the percent ionization of 0.125 M lactic acid (Ka= 1.4* 10-4). b. calculate the percent... Problem 19E Problem 20E: 17.20 Which of the following solutions is a buffer?
A solution made by mixing 100 mL of 0.100 M... Problem 21E Problem 22E: Calculate the pH of a buffer that is 0.105n M in NaHCO3 and 0.125 M in Na2CO3. Calculate the pH of a... Problem 23E Problem 24E: A buffer is prepared by adding 10.0 g of ammonium chloride (NH4CI) to 250 mL of 1.00 M NH3 solution.... Problem 25E: You are asked to prepare a pH = 3.00 buffer solution starting from 1.25 L of a 1.00 M solution of... Problem 26E: You are asked to prepare an pH = 4.00 buffer starting from 1.50 L of 0.0200 M solution of benzoic... Problem 27E Problem 28E Problem 29E Problem 30E Problem 31E Problem 32E Problem 33E: The accompanying graph shows the titration curves for two monoprotic acids. a. Which curve is that... Problem 34E Problem 35E: 17.35 The samples of nitric and acetic acids shows here are both titral with a 0.100 M solution of... Problem 36E: 17.36 Determine whether each of the following statements concerning the titration in Problem 17.35... Problem 37E Problem 38E Problem 39E Problem 40E: Assume that 30.0 mL of a M solution of a week base B that accepts one proton is titrated with a 0.10... Problem 41E Problem 42E Problem 43E Problem 44E Problem 45E Problem 46E: Consider the titration of 30.0 mL of 0.050 M NH3 with 0.025 M HCI. Calculate the pH after the... Problem 47E Problem 48E Problem 49E: 17.49 for each statement, incate whether it is true or false.
a.(a) the solubility of a slighty... Problem 50E: The solubility of two slighty soluble salts of M2+, MA and MZ2, is the same, 4*10-4 mol/L. a. which... Problem 51E Problem 52E: 17.52
a. true or false: solubility and solubility-product constant are the same number for a given... Problem 53E: If the molar solubility CaF2 at 35 C is 1.24 *10-3 mol/L what is Ksp at this temperature? b. it is... Problem 54E Problem 55E Problem 56E Problem 57E: using calculate the molar solubility of AgBr in a. pure water b. 3.0 *10-2 M AgNO3 solution, c. 0.10... Problem 58E: calculate the solubility of LaF3 in grams per liter in a. pure water, b. 0.010 M KF solution. c.... Problem 59E Problem 60E: Consider a beaker containing a saturated solution of Pbl2 in equilibrium with undissolved Pbl2 (S).... Problem 61E: Calculate the solubility of Mn (OH) 2 in grams per liter when buffered at pH 7.0, 9.5, 11.8. Problem 62E: Calculate the molar solubility of Ni (OH) 2 when buffered at pH 8.0, 10.0, 12.0. Problem 63E: 17.63 Which of the following salts will be substantially more soluble in acidic solution than in... Problem 64E: For each of the following slightly soluble salts, write the net ionic equation, if any, for reaction... Problem 65E Problem 66E Problem 67E: Use values of Kap for Agl and Kf for Ag (CN) 2- to Calculate the molar solubility of Agl in pure... Problem 68E Problem 69E Problem 70E Problem 71E: Calculate the minimum pH needed to precipitate Mn (OH)2 so completely that the concentration of Mn2+... Problem 72E Problem 73E Problem 74E Problem 75E Problem 76E Problem 77E: A solution containing several metal ions is treated with dilute HCl; no precipitate forms. The pH is... Problem 78E: An unknown solid is entirely soluble in water. On addition of dilute HCl, a precipitate forms. After... Problem 79E Problem 80E Problem 81E: 17.81
Precipitation of the group 4 cautions of Figure 17.23 require a basic medium. Why is this... Problem 82E Problem 83AE Problem 84AE Problem 85AE: Furoic acid (HC5H3O3) has a K value of 6.76 x 10-4 at 25 C. Calculate then pH at 25 OC of A solution... Problem 86AE Problem 87AE: Equal quantities of 0.010 M solution of an acid HA and a base B are mixed. The pH of the resulting... Problem 88AE Problem 89AE: 17.89 A biochemist needs 750 ml of an acetic acid-sodium acetate buffer with pH 4.50. Solid sodium... Problem 90AE: A sample of 0.2140 g of an unknown monophonic acid was dissolved in 25.0 mL of water and titrated... Problem 91AE: A sample of 0.1687 g of an unknown monoprotic acid was dissolved in 25.0 mL of water and titrated... Problem 92AE Problem 93AE Problem 94AE: What is the pH of a solution made by mixing 0.30 mol NaOH, 0.25 mol Na2HPO4, and 0.20 mol H3PO4 with... Problem 95AE: Suppose you want to do a physiological experiment that calls for a pH 6.50 buffer. You find that the... Problem 96AE Problem 97AE Problem 98AE: For each pair of compounds, use Kap values to determine which has the greater molar solubility: CdS... Problem 99AE Problem 100AE: Tooth enamel is composed of hydroxyapatite, whose simplest formula is Ca5 (PO4)3OH, and whose... Problem 101AE: Salts containing the phosphate ion are added to municipal water supplies to prevent the corrosion of... Problem 102AE Problem 103AE: 17.103 The solubility –product constant for barium permanganate, Ba(MnO4)2, is 2.5 × 10-10. Assume... Problem 104AE Problem 105AE Problem 106AE: A buffer of what pH is needed to give a Mg2+ concentration of 3.0 10-2 M in equilibrium with solid... Problem 107AE: The value of Kap for Mg3(AsO4)2 is 2.1 10-20 . The AsO43- ion is derived from the weak acid H3AsO4... Problem 108AE Problem 109AE Problem 110IE Problem 111IE Problem 112IE Problem 113IE Problem 114IE Problem 115IE Problem 116IE Problem 117IE: A concentration of 10-100 parts per billion (by mass) of Ag+ is an effective disinfectant in... Problem 118IE Problem 119IE Problem 120IE: In nonaqueous solvents, it is possible to react HF to crease H2F+. Which of these statements follows... format_list_bulleted