Bundle: Introductory Chemistry: A Foundation, Loose-leaf Version, 9th + OWLv2 with MindTap Reader, 1 term (6 months) Printed Access Card
9th Edition
ISBN: 9780357000922
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 17, Problem 106AP
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Chapter 17 Solutions
Bundle: Introductory Chemistry: A Foundation, Loose-leaf Version, 9th + OWLv2 with MindTap Reader, 1 term (6 months) Printed Access Card
Ch. 17.2 - Most modern refrigerators have an internal...Ch. 17.2 - Many conditions need to be met to produce a...Ch. 17.5 - Prob. 17.1SCCh. 17.6 - Prob. 17.2SCCh. 17.7 - Prob. 17.3SCCh. 17.7 - Prob. 17.4SCCh. 17.7 - Exercise 17.5 For the exothermic reaction...Ch. 17.9 - Prob. 17.6SCCh. 17.9 - Prob. 17.7SCCh. 17.9 - The Kspvalue for lead chromate, PbCrO4, is...
Ch. 17 - Consider an equilibrium mixture of four chemicals...Ch. 17 - The boxes shown below represent a set of initial...Ch. 17 - For the reaction H2+I22HI, consider two...Ch. 17 - Given the reaction A+BC+D, consider the following...Ch. 17 - Consider the reaction A+BC+D. A friend asks the...Ch. 17 - Prob. 6ALQCh. 17 - The value of the equilibrium constant, K, is...Ch. 17 - You are browsing through the Handbook of...Ch. 17 - What do you suppose happens to the Ksp, value of a...Ch. 17 - . Consider an equilibrium mixture consisting of...Ch. 17 - . Equilibrium is microscopically dynamic but...Ch. 17 - In Section 17.3 of your text, it is mentioned that...Ch. 17 - Prob. 13ALQCh. 17 - . Consider the figure below in answering the...Ch. 17 - For a chemical reaction to take place, some or all...Ch. 17 - For the simple reaction 2H2(g)+O2(g)2H2O(l)list...Ch. 17 - How do chemists envision reactions taking place in...Ch. 17 - When molecules collide, a certain minimum energy...Ch. 17 - How does a catalyst work to speed up a chemical...Ch. 17 - Why are enzymes important? For example, what is...Ch. 17 - How does equilibrium represent the balancing of...Ch. 17 - Consider the equilibrium process depicted in Fig....Ch. 17 - When writing a chemical equation for a reaction...Ch. 17 - . How do chemists recognize a system that has...Ch. 17 - . What does it mean to say that a state of...Ch. 17 - . Consider an initial mixture of N2 and H2 gases...Ch. 17 - . In general terms. what does the equilibrium...Ch. 17 - . There is only one value of the equilibrium...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Suppose that for the reaction...Ch. 17 - . Ammonia. a very important industrial chemical....Ch. 17 - . At high temperatures, elemental nitrogen and...Ch. 17 - . Suppose that for the reaction...Ch. 17 - . What is a homogeneous equilibrium system? Give...Ch. 17 - . True or false? The position of a heterogeneous...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Indicate whether the stated equilibrium...Ch. 17 - . In your own words, describe what Le Châtelier’s...Ch. 17 - . Consider the reaction 2CO(g)+O2(g)2CO2(g)Suppose...Ch. 17 - . For an equilibrium involving gaseous substances,...Ch. 17 - . What is the effect on the equilibrium position...Ch. 17 - . For the reaction system...Ch. 17 - . For the reaction system P4(s)+6F2(g)4PF3(g)which...Ch. 17 - . Suppose the reaction system...Ch. 17 - . Consider the general reaction...Ch. 17 - . Hydrogen gas and chlorine gas in the presence of...Ch. 17 - . Hydrogen gas, oxygen gas, and water vapor are in...Ch. 17 - . The reaction C2H2(g)+2Br2(g)C2H2Br4(g)is...Ch. 17 - . Old fashioned “smelling salts” consist of...Ch. 17 - . Plants synthesize the sugar dextrose according...Ch. 17 - . Consider the exothermic reaction...Ch. 17 - . Suppose are action has the equilibrium constant...Ch. 17 - . Suppose a reaction has the equilibrium constant...Ch. 17 - . For the reaction Br2(g)+5F2(g)2BrF5(g)the system...Ch. 17 - . Consider the reaction...Ch. 17 - . For the reaction 2CO(g)+O2(g)2CO2(g)it is found...Ch. 17 - . For the reaction CO2(g)+H2(g)CO(g)+H2O(g)the...Ch. 17 - . The equilibrium constant for the reaction...Ch. 17 - . For the reaction 2H2O(g)2H2(g)+O2(g)K=2.4103at a...Ch. 17 - . For the reaction 3O2(g)2O3(g)The equilibrium...Ch. 17 - . For the reaction N2O4(g)2NO(g)the equilibrium...Ch. 17 - . Explain how the dissolving of an ionic solute in...Ch. 17 - . What is the special name given to the...Ch. 17 - . Why does the amount of excess solid solute...Ch. 17 - . Which of the following will affect the total...Ch. 17 - . Write the balanced chemical equation describing...Ch. 17 - . Write the balanced chemical equation describing...Ch. 17 - . K for copper(II)hydroxide, Cu(OH)2, has a value...Ch. 17 - Prob. 60QAPCh. 17 - . A saturated solution of nickel(II) sulfide...Ch. 17 - . Most hydroxides are not very soluble in water....Ch. 17 - . The solubility product constant, Ksp, for...Ch. 17 - . Calcium sulfate, CaSO4, is only soluble in water...Ch. 17 - . Approximately 1.5103of iron(II) hydroxide....Ch. 17 - . Chromiurn(III) hydroxide dissolves in water only...Ch. 17 - . Magnesium fluoride dissolves in water to the...Ch. 17 - . Lead(II) chloride, PbCl2(s), dissolves in water...Ch. 17 - . Mercury(I) chloride, Hg2Cl2, was formerly...Ch. 17 - . The solubility product of iron(III) hydroxide is...Ch. 17 - . Before two molecules can react, chemists...Ch. 17 - . Why does an increase in temperature favor an...Ch. 17 - . The minimum energy required for molecules to...Ch. 17 - . A(n) _______ speeds up a reaction without being...Ch. 17 - . Equilibrium may be defined as the ________ of...Ch. 17 - . When a chemical system has reached equilibrium,...Ch. 17 - . What does it mean to say that all chemical...Ch. 17 - . What does it mean to say that chemical...Ch. 17 - . At the point of chemical equilibrium, the rate...Ch. 17 - . Equilibria involving reactants or products in...Ch. 17 - . According to Le Châtelier’s principle, when a...Ch. 17 - . Addition of an inert substance (one that does...Ch. 17 - . When the volume of a vessel containing a gaseous...Ch. 17 - . Consider the following reaction at some...Ch. 17 - . What is meant by the solubility product for a...Ch. 17 - . For a given reaction at a given temperature, the...Ch. 17 - . Many sugars undergo a process called...Ch. 17 - . Suppose K=4.5103at a certain temperature for the...Ch. 17 - . For the reaction CaCO3(s)CaO(s)+CO2(g)the...Ch. 17 - Prob. 90APCh. 17 - . Teeth and bones are composed, to a first...Ch. 17 - . Under what circumstances can we compare the...Ch. 17 - . How does the collision model account for the...Ch. 17 - Prob. 94APCh. 17 - . Explain why the development of a vapor pressure...Ch. 17 - Prob. 96APCh. 17 - Prob. 97APCh. 17 - . For the reaction N2(g)+3Cl2(g)2NCl3(g)an...Ch. 17 - . Gaseous phosphorus pentachloride decomposes...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Write the equilibrium expression for each of the...Ch. 17 - . Consider the following generic reaction:...Ch. 17 - Prob. 103APCh. 17 - . The reaction PCl3(l)+Cl2(g)PCl5(s)liberates 124...Ch. 17 - Prob. 105APCh. 17 - . For the reaction N2(g)+3H2(g)2NH3(g)K=1.3102at a...Ch. 17 - . The equilibrium constant for the reaction...Ch. 17 - Prob. 108APCh. 17 - Prob. 109APCh. 17 - Prob. 110APCh. 17 - . Mercuric sulphide, HgS, is one of the least...Ch. 17 - Prob. 112APCh. 17 - . For the reaction N2(g)+3H2(g)2NH3(g), list the...Ch. 17 - . What does the activation energy for a reaction...Ch. 17 - Prob. 115APCh. 17 - Prob. 116APCh. 17 - Prob. 117APCh. 17 - Prob. 118APCh. 17 - Prob. 119APCh. 17 - Prob. 120CPCh. 17 - . Suppose that for a hypothetical reaction:...Ch. 17 - Prob. 122CPCh. 17 - . The reaction H2(g)+I2(g)2HI(g)has Kp=45.9at 763...Ch. 17 - Prob. 124CPCh. 17 - Prob. 125CPCh. 17 - . Consider the following exothermic reaction at...Ch. 17 - Prob. 1CRCh. 17 - Prob. 2CRCh. 17 - Prob. 3CRCh. 17 - How is the strength of an acid related to the...Ch. 17 - Prob. 5CRCh. 17 - How is the pH scale defined? What range of pH...Ch. 17 - 7. Describe a buffered solution. Give three...Ch. 17 - Prob. 8CRCh. 17 - Prob. 9CRCh. 17 - . Explain what it means that a reaction has...Ch. 17 - . Describe how we write the equilibrium expression...Ch. 17 - Prob. 12CRCh. 17 - Prob. 13CRCh. 17 - . In your own words, paraphrase Le Châtelier’s...Ch. 17 - Prob. 15CRCh. 17 - Prob. 16CRCh. 17 - . a. Write the conjugate acid for each of the...Ch. 17 - . Identify the Brønsted-Lowry conjugate acid-base...Ch. 17 - Prob. 19CRCh. 17 - Prob. 20CRCh. 17 - Prob. 21CRCh. 17 - Prob. 22CRCh. 17 - Prob. 23CRCh. 17 - . The solubility product of magnesium carbonate,...
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- Consider 0.200 mol phosphorus pentachloride sealed in a 2.0-L container at 620 K. The equilibrium constant, Kc, is 0.60 for PCl5(g) PCl3(g) + Cl2(g) Calculate the concentrations of all species after equilibrium has been reached.arrow_forwardSuppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this constant tell you about the relative concentrations of products and reactants that will be present once equilibrium is reached? Is this reaction likely to be a good source of the products?arrow_forwardThe decomposition of PCl5(g) to form PCl3(g) and Cl2(g) has Kc = 33.3 at a high temperature. If the initial concentration of PCl5 is 0.1000 M, what are the equilibrium concentrations of the reactants and products?arrow_forward
- A solution is prepared by dissolving 0.050 mol of diiodocyclohexane, C5H10I2, in the solvent CCl4.The total solution volume is 1.00 L When the reaction C6H10I2 C6H10 + I2 has come to equilibrium at 35 C, the concentration of I2 is 0.035 mol/L. (a) What are the concentrations of C6H10I2 and C6H10 at equilibrium? (b) Calculate Kc, the equilibrium constant.arrow_forwardBecause calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?arrow_forwardFor the reactionH2(g)+I2(g)2HI(g), consider two possibilities: (a) you mix 0.5 mole of each reactant. allow the system to come to equilibrium, and then add another mole of H2 and allow the system to reach equilibrium again. or (b) you mix 1.5 moles of H2 and 0.5 mole of I2 and allow the system to reach equilibrium. Will the final equilibrium mixture be different for the two procedures? Explain.arrow_forward
- For the reaction N2(g)+3H2(g)2NH3(g) show that Kc = Kp(RT)2 Do not use the formula Kp = Kc(RT)5n given in the text. Start from the fact that Pi = [i]RT, where Pi is the partial pressure of substance i and [i] is its molar concentration. Substitute into Kc.arrow_forwardAt 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g) (a) Analysis shows that the concentrations of N2 and O2 are both 0.25 M, and that of NO is 0.0042 M under certain conditions. Is the system at equilibrium? (b) If the system is not at equilibrium, in which direction does the reaction proceed? (c) When the system is at equilibrium, what are the equilibrium concentrations?arrow_forwardWrite an equation for an equilibrium system that would lead to the following expressions (ac) for K. (a) K=(Pco)2 (PH2)5(PC2H6)(PH2O)2 (b) K=(PNH3)4 (PO2)5(PNO)4 (PH2O)6 (c) K=[ ClO3 ]2 [ Mn2+ ]2(Pcl2)[ MNO4 ]2 [ H+ ]4 ; liquid water is a productarrow_forward
- At room temperature, the equilibrium constant Kc for the reaction 2 NO(g) ⇌ N2(g) + O2(g) is 1.4 × 1030. Is this reaction product-favored or reactant-favored? Explain your answer. In the atmosphere at room temperature the concentration of N2 is 0.33 mol/L, and the concentration of O2 is about 25% of that value. Calculate the equilibrium concentration of NO in the atmosphere produced by the reaction of N2 and O2. How does this affect your answer to Question 11?arrow_forward12.103 Methanol, CH3OH, can be produced by the reaction of CO with H2, with the liberation of heat. All species in the reaction are gaseous. What effect will each of the following have on the equilibrium concentration of CO? (a) Pressure is increased, (b) volume of the reaction container is decreased, (c) heat is added, (d) the concentration of CO is increased, (e) some methanol is removed from the container, and (f) H2 is added.arrow_forwardConsider the system 4NH3(g)+3O2(g)2N2(g)+6H2O(l)H=1530.4kJ (a) How will the concentration of ammonia at equilibrium be affected by (1) removing O2(g)? (2) adding N2(g)? (3) adding water? (4) expanding the container? (5) increasing the temperature? (b) Which of the above factors will increase the value of K? Which will decrease it?arrow_forward
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