(a) Interpretation: The effect of the given changes on the position of the equilibrium is to be predicted. Concept Introduction: The chemical equilibrium is the state in which the rates of both forward and backward reactions become equal. The concentration of both reactants and products do not change on reaching an equilibrium state. The general chemical equation is shown below. aA + bB ⇌ cC + dD The general equilibrium expression for a reaction is shown below. K = C c D d A a B b .
(a) Interpretation: The effect of the given changes on the position of the equilibrium is to be predicted. Concept Introduction: The chemical equilibrium is the state in which the rates of both forward and backward reactions become equal. The concentration of both reactants and products do not change on reaching an equilibrium state. The general chemical equation is shown below. aA + bB ⇌ cC + dD The general equilibrium expression for a reaction is shown below. K = C c D d A a B b .
Solution Summary: The author explains that the chemical equilibrium is the state in which the rates of both forward and backward reactions become equal.
Definition Definition State where the components involved in a reversible reaction, namely reactants and product, do not change concentration any further with time. Chemical equilibrium results when the rate of the forward reaction becomes equal to the rate of the reverse reaction.
Chapter 17, Problem 103AP
Interpretation Introduction
(a)
Interpretation:
The effect of the given changes on the position of the equilibrium is to be predicted.
Concept Introduction:
The chemical equilibrium is the state in which the rates of both forward and backward reactions become equal. The concentration of both reactants and products do not change on reaching an equilibrium state.
The general chemical equation is shown below.
aA+bB⇌cC+dD
The general equilibrium expression for a reaction is shown below.
K=CcDdAaBb.
Interpretation Introduction
(b)
Interpretation:
The effect of the given changes on the position of the equilibrium is to be predicted.
Concept Introduction:
The chemical equilibrium is the state in which the rates of both forward and backward reactions become equal. The concentration of both reactants and products do not change on reaching an equilibrium state.
The general chemical equation is shown below.
aA+bB⇌cC+dD
The general equilibrium expression for a reaction is shown below.
Substance X is known to exist at 1 atm in the solid, liquid, or vapor phase, depending on the temperature. Additionally, the values of these other properties of X
have been determined:
melting point
enthalpy of fusion
90. °C
8.00 kJ/mol
boiling point
130. °C
enthalpy of
vaporization
44.00 kJ/mol
density
2.80 g/cm³ (solid)
36. J.K mol (solid)
2.50 g/mL (liquid)
heat capacity
32. J.Kmol (liquid)
48. J.Kmol (vapor)
You may also assume X behaves as an ideal gas in the vapor phase.
Ex
Suppose a small sample of X at 50 °C is put into an evacuated flask and heated at a constant rate until 15.0 kJ/mol of heat has been added to the sample.
Graph the temperature of the sample that would be observed during this experiment.
o0o
150-
140
130-
120-
110-
100-
G
Ar
?
Mechanism. Provide the mechanism for the reaction below. You must include all arrows, intermediates, and formal
charges. If drawing a Sigma complex, draw all major resonance forms. The ChemDraw template of this document is
available on Carmen.
Br
FeBr3
Br
Check the box under each compound that exists as a pair of mirror-image twins. If none of them do, check the none of the above box under the table.
CH3
OH
CH3
CH2
-CH-CH3
CH3
OH
OH
CH-CH2-CH-
-CH3
CH3
CH3
OH
OH
CH3
C
-CH2- C. -CH3
CH3- -CH2- -CH-CH2-OH
OH
CH3
none of the above
ك
Chapter 17 Solutions
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