Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 16.6, Problem 10P

a)

Interpretation Introduction

Interpretation:

The structure of the given sugar β-D-galactopyranose is to be drawn by using Haworth projections.

Concept Introduction:

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

Furanose: A five-member closed chain form of a monosaccharide.

Pyranose: A six-member cyclic form of a monosaccharide.

b)

Interpretation Introduction

Interpretation:

The structure of the given sugar α-D-tagatopyranose is to be drawn by using Haworth projections.

Concept Introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

Furanose: A five-member closed chain form of a monosaccharide.

Pyranose: A six-member cyclic form of a monosaccharide.

c)

Interpretation Introduction

Interpretation: The structure of the given sugar α-D-Glucopyranose is to be drawn by using Haworth projections.

Concept Introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

Furanose: A five-member closed chain form of a monosaccharide.

Pyranose: A six-member cyclic form of a monosaccharide.

Blurred answer
Students have asked these similar questions
Answer the following questions about monosaccharide A.a. Draw the α anomer of A in a Haworth projection.b. Draw the β anomer of A in a three-dimensional representation using a chair conformation.c. What two aldoses yield A in a Wohl degradation?d. What product is formed when A undergoes a Wohl degradation?e. What product is formed when A reacts with Ag2O in NH4OH?
Draw the structure of the following dissaccharide: A. beta-D-sorbofuranosyl-(2->4)-alpha-D-allopyranose B. alpha-D-allopyranosyl-(1->6)-beta-D-sorbofuranose
Answer the following questions about monosaccharide B.a. Draw the β anomer of B in a Haworth projection.b. Draw the α anomer of B in a three-dimensional representation using a chair conformation.c. What products are formed when B undergoes the Kiliani–Fischer synthesis?d. What product is formed when B is treated with NaBH4 in CH3OH?e. Draw the disaccharide formed when two molecules of B are joined by a 1→4-β-glycosidic linkage.
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole
Text book image
Pushing Electrons
Chemistry
ISBN:9781133951889
Author:Weeks, Daniel P.
Publisher:Cengage Learning
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning