A sugar that is C − 3 epimer of D-xylose is to be stated. Concept Introduction: Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example, D-xylose and D-ribose are the C − 3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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Answer 1

Question

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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For D-arabinose:a. Draw its enantiomer.b. Draw an epimer at C3.c. Draw a diastereomer that is not an epimer.d. Draw a constitutional isomer that still contains a carbonyl group.

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Draw the products formed when B-D-galactose is treated with each reagent. a. Ag,0 + CH3I b. NaH + CgHsCH2CI c. The product in (b), then H30* d. Ac20 + pyridine e. CeHsCOCI + pyridine f. The product in (c), then CgHsCOCI + pyridine

Answer 2

Question

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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Answer 3

Question

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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Answer 4

Question

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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Answer 5

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 6

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 7

Chapter 16.3, Problem 4P

(a)

Interpretation Introduction

Interpretation:

A sugar that is C−3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 8

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 9

b)

Interpretation Introduction

Interpretation:

A sugar that is C−5 epimer of D-allose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 10

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 11

c)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 12

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 13

d)

Interpretation Introduction

Interpretation:

A sugar that is C−4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimer: Epimer is one of a pair of stereoisomers. Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,D-xylose and D-ribose are the C−3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 16.1 - Prob. 1P Ch. 16.2 - Prob. 2P Ch. 16.3 - Prob. 3P Ch. 16.3 - Prob. 4P Ch. 16.4 - Prob. 5P Ch. 16.4 - Prob. 6P Ch. 16.5 - Prob. 7P Ch. 16.5 - Prob. 8P Ch. 16.6 - Prob. 10P Ch. 16.8 - Prob. 12P

Solution Summary: The author explains that epimers are monosaccharides that differ in the structure at only one of the asymmetric center.

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Chapter 16 Solutions