EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 16, Problem 40P
Interpretation Introduction
Interpretation:
Whether
Concept Introduction:
Carbohydrates are made from carbon, oxygen and hydrogen atoms and the wide numbers of isomers exist for the carbohydrates because of the presence of chiral Carbon atoms.
Pyranose are the compounds that comprise six-membered ring made of one Oxygen and five Carbon atoms, whereas furanose is the carbohydrates that comprise five-membered ring made of one Oxygen and four carbon atoms.
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4) Structure:
the appropriate box.
CHO
-OH
H-
HO- -H
HO -H
Write the requested cyclized form of the given carbohydrates in
B-pyranose
a-furanose
CH₂OH
Q2: Write the structure of the product formed in each case
(A)
C6H₂CH₂CH₂C6H₁
H₂C=CHCCH₂
NaOCH,
CH₂OH
β-d-gulopyranose + hydrogen gas and a platinum catalyst.
Chapter 16 Solutions
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
Ch. 16.1 - Prob. 1PCh. 16.2 - Prob. 2PCh. 16.3 - Prob. 3PCh. 16.3 - Prob. 4PCh. 16.4 - Prob. 5PCh. 16.4 - Prob. 6PCh. 16.5 - Prob. 7PCh. 16.5 - Prob. 8PCh. 16.6 - Prob. 10PCh. 16.8 - Prob. 12P
Ch. 16.8 - Prob. 14PCh. 16.9 - Prob. 15PCh. 16.10 - Prob. 16PCh. 16.11 - Refer to Figure 16.4 to answer the following...Ch. 16 - Prob. 18PCh. 16 - Prob. 19PCh. 16 - Prob. 20PCh. 16 - Prob. 21PCh. 16 - Prob. 22PCh. 16 - Prob. 23PCh. 16 - Prob. 24PCh. 16 - Prob. 25PCh. 16 - Name the following compounds:Ch. 16 - Prob. 28PCh. 16 - Prob. 29PCh. 16 - Prob. 31PCh. 16 - Prob. 32PCh. 16 - Prob. 33PCh. 16 - Prob. 34PCh. 16 - Prob. 35PCh. 16 - Prob. 36PCh. 16 - Prob. 37PCh. 16 - Draw the mechanism for the acid-catalyzed...Ch. 16 - Prob. 39PCh. 16 - Prob. 40PCh. 16 - Prob. 41P
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- Comparing Two Different Methods of Hydration of an Alkene Draw the product formed when CH3CH2CH2CH2CH=CH2 is treated with either (a) H2O, H2SO4; or (b) BH3 followed by H2O2, HO−.arrow_forwardWhat is the product (from the image below) of the starting material D-glyceraldehyde which will (1) produce aldaric acid upon reacting with HNO3 + H2O, NaOCH2, NH2OH, and (CH3CO)2O + NaOCOCH3 (2) produce tartaric acid upon reacting with HNO3 + H2O, NaOCH3, NH2OH, and (CH3CO)2O + NaOCOCH3arrow_forwardDraw the structure of 5-methylhexanoic acid; d-methylcaproic acid:arrow_forward
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- Identify A, B, C, and D in the preceding problem if D is oxidized to an optically inactive aldaric acid; if A, B, and C are oxidized to optically active aldaric acids; and if interchanging the aldehyde and alcohol groups of A leads to a different sugar.arrow_forwardComplete the table by drawing the bond line structure, number of carbons in the parent chain, and its respective IUPAC namearrow_forwardb) Disaccharide E is a reducing sugar. It is hydrolyzed by an α-glycosidase enzyme, which means it contains an α- glycoside link. Treatment of E with Ag2O and excess Mel gives an octamethyl derivative F. Hydrolysis of F in dilute aqueous acid gives the pair of molecules shown below. Write the structures of E and F. (If the stereochemistry at a particular carbon is not determined by the above data, indicate this with a wavy line as shown below.) HO OMe OMe Is is MeO MeO MOH OMe mOH OMe OMearrow_forward
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