Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 16.3, Problem 16.2SC
Exercise 16.2 Calculate [H+] in a solution in which
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Examine the reaction below. Highlight all bonds that have broken in the reactant.
Br H
H₂C-C-
-H
5
H-C-H
H-C-H
BIE
们
OH
H H
H₂C-C=
H-C-H
H-C-H
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH2=CH₂
CH2=C-CH2-OH + Br₂
Br-CH2-C
-CH₂-OH
Br
CH,CH3
CH3-C-CH-CH2-CH3
он
° CH₂
HO
C-C-CH3 + NH3
CH₂
он
CH3-CH-O-CH3
O-CH3
CH3-C-CH3 + H₂O
O-CH3
CH3CH₂
H
+ H₂O
CH3-C=C-CH2-CH3
• CHI
Δ
Å CH
CH3
H+
CH3
C-H + HO-CH3
H"
Q-CH₂
CH3-C-CH3 + HO-CH3
OH
O substitution
O elimination
addition
substitution
O elimination
addition
O substitution
elimination
addition
O substitution
O elimination
addition
substitution
O elimination
00
addition
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Quiz 9
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Quiz #9 =
Name:
Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
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HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
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KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
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H
HBr
Br2
J
CH2N2
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K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Chapter 16 Solutions
Introductory Chemistry: A Foundation
Ch. 16.1 - Exercise 16.1 Which of the following represent...Ch. 16.2 - Vinegar contains acetic acid and is used in salad...Ch. 16.3 - Exercise 16.2 Calculate [H+] in a solution in...Ch. 16.4 - Prob. 16.3SCCh. 16.4 - Prob. 1CTCh. 16.4 - Prob. 16.4SCCh. 16.4 - Exercise 16.5 The pH of rainwater in a polluted...Ch. 16.4 - Exercise 16.6 The pOH of a liquid drain cleaner...Ch. 16.5 - Exercise 16.7 Calculate the pH of a solution of...Ch. 16 - You are asked for the H+ concentration in a...
Ch. 16 - Explain why Cl- does not affect the pH of an...Ch. 16 - Write the general reaction for an acid acting in...Ch. 16 - Differentiate among the terms concentrated,...Ch. 16 - What is meant by “pH”? True or false: A strong...Ch. 16 - Consider two separate solutions: one containing a...Ch. 16 - Prob. 7ALQCh. 16 - Prob. 8ALQCh. 16 - Stanley’s grade-point average (GPA) is 3.28. What...Ch. 16 - Prob. 10ALQCh. 16 - . Mixing together aqueous solutions of acetic acid...Ch. 16 - Prob. 12ALQCh. 16 - . Consider the equation:...Ch. 16 - . Choose the answer that best completes the...Ch. 16 - Prob. 15ALQCh. 16 - . The following figures are molecular-level...Ch. 16 - Prob. 17ALQCh. 16 - What are some physical properties that...Ch. 16 - Write an equation showing how HCl(g) behaves as an...Ch. 16 - Prob. 3QAPCh. 16 - How do the components of a conjugate acid—base...Ch. 16 - 5. Given the general equation illustrating the...Ch. 16 - According to Arrhenius, ____________ produce...Ch. 16 - Which of the following do not represent a...Ch. 16 - Which of the following do not represent a...Ch. 16 - In each of the following chemical equations,...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - Prob. 13QAPCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . What does it mean to say that an acid is strong...Ch. 16 - Prob. 18QAPCh. 16 - . How is the strength of an acid related to the...Ch. 16 - . A strong acid has a weak conjugate base, whereas...Ch. 16 - . Write the formula for the hydronium ion. Write...Ch. 16 - Prob. 22QAPCh. 16 - . Organic acids contain the carboxyl group Using...Ch. 16 - Prob. 24QAPCh. 16 - 25. Which of the following acids have relatively...Ch. 16 - . The “Chemistry in Focus” segment Plants Fight...Ch. 16 - . Water is the most common amphoteric substance,...Ch. 16 - . Anions containing hydrogen (for example. HCO3and...Ch. 16 - . What is meant by the iou-product constant for...Ch. 16 - . What happens to the hydroxide ion concentration...Ch. 16 - Prob. 31QAPCh. 16 - Prob. 32QAPCh. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - 35. For each pair of concentrations, tell which...Ch. 16 - Prob. 36QAPCh. 16 - . Why do scientists tend to express the acidity of...Ch. 16 - . Using Fig. 16.3, list the approximate pH value...Ch. 16 - . For a hydrogen ion concentration of 2.33106M,...Ch. 16 - . The “Chemistry in Focus” segment Garden-Variety...Ch. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 42QAPCh. 16 - Prob. 43QAPCh. 16 - Prob. 44QAPCh. 16 - Prob. 45QAPCh. 16 - Calculate the pOH value corresponding to each of...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 50QAPCh. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - Prob. 54QAPCh. 16 - 55. When 1 mole of gaseous hydrogen chloride is...Ch. 16 - . A bottle of acid solution is labeled “3 M HNO3.”...Ch. 16 - . Calculate the hydrogen ion concentration and the...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - . What characteristic properties do buffered...Ch. 16 - Prob. 60QAPCh. 16 - . Which component of a buffered solution is...Ch. 16 - Prob. 62QAPCh. 16 - . Which of the following combinations would act as...Ch. 16 - . A buffered solution is prepared containing...Ch. 16 - . The concepts of acid-base equilibria were...Ch. 16 - . Strong buses are bases that completely ionize in...Ch. 16 - Which of the following conditions indicate an...Ch. 16 - Which of the following conditions indicate a basic...Ch. 16 - Prob. 69APCh. 16 - Prob. 70APCh. 16 - Prob. 71APCh. 16 - Prob. 72APCh. 16 - Prob. 73APCh. 16 - Prob. 74APCh. 16 - 75. A conjugate acid-base pair Consists of two...Ch. 16 - . Acetate ion, C2H3O2- , has a stronger affinity...Ch. 16 - Prob. 77APCh. 16 - Prob. 78APCh. 16 - Prob. 79APCh. 16 - Prob. 80APCh. 16 - Prob. 81APCh. 16 - Prob. 82APCh. 16 - Prob. 83APCh. 16 - Prob. 84APCh. 16 - . A(n) _________ solution contains a conjugate...Ch. 16 - . When sodium hydroxide, NaOH, is added dropwise...Ch. 16 - . When hydrochloric acid, HCI. is added dropwise...Ch. 16 - . The following are representations of acid-base...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - Prob. 90APCh. 16 - . Write the conjugate base for each of the...Ch. 16 - Prob. 92APCh. 16 - Prob. 93APCh. 16 - . Calculate [H+] in each of the following...Ch. 16 - Prob. 95APCh. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 97APCh. 16 - Prob. 98APCh. 16 - Prob. 99APCh. 16 - . For each hydrogen or hydroxide ion concentration...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 102APCh. 16 - Prob. 103APCh. 16 - Prob. 104APCh. 16 - . Write the formulas for three combinations of...Ch. 16 - . Choose pairs in which the species listed first...Ch. 16 - . Complete the table for each of the following...Ch. 16 - . Consider 0.25 M solutions of the following...
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- Select the stronger base: H-CEN equally basic H H H H-C-N H Select the stronger acid: Select the stronger base: Select the stronger base: H -H equally acidic о equally basic NH equally basic оarrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3 CH3 CH3-CH-CH2-C-CH3 + Br₂ CH3 CH3 CH3 CH3-C-CH2-C-CH3 + HBr substitution ○ elimination Br CH3 CHI CHO CHA HO CH он Cl CH3-CH2-CH-CH2-CH3 CH₂ DBU H* - CHI CHO CH3 + H2O Ӧ CH3 CH3-CH2-CH=CH-CH3 + HCI OH Pd/C CH3 CH3-CH-CH2-C-CH3 CH3 H C-CH2-CH3 + HO-CH3 addition substitution elimination ○ addition ○ substitution ○ elimination O addition substitution O elimination addition substitution O elimination addition CH3 C-CH3 + H2 CH3 CH3-O-CH-CH2-CH3 Онarrow_forward=> (8 pts) Use retrosynthetic analysis (that is, use retrosynthetic arrows as was done in class) to suggest a synthesis route for the transformation shown below. Sear bonsarrow_forward
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