(a) Interpretation: The reason for the negative value of Δ S ∘ when number of gaseous molecules increases in a system needs to be determined. Concept introduction: Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If number of gaseous molecules increases, entropy also increases.
(a) Interpretation: The reason for the negative value of Δ S ∘ when number of gaseous molecules increases in a system needs to be determined. Concept introduction: Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If number of gaseous molecules increases, entropy also increases.
Solution Summary: The author explains that entropy is defined as degree of randomness in a system, due to the random motion of molecules in the reaction system.
The reason for the negative value of ΔS∘ when number of gaseous molecules increases in a system needs to be determined.
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If number of gaseous molecules increases, entropy also increases.
Interpretation Introduction
(b)
Interpretation:
The reason for ΔS∘ value to be independent of T needs to be explained.
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion. If temperature of a system is increased, the random movement of molecules of gases increases.
Interpretation Introduction
(c)
Interpretation:
The reason for a solid to have lower entropy than liquid needs to be explained.
Concept introduction:
Entropy is defined as degree of randomness in a system. It is due to the random motion of molecules in the reaction system. The entropy of a gaseous system is more than a liquid system as gaseous molecules are in constant motion.
Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain.
Q2: Explain why epoxides that react in an SN1 manner will not show any stereochemical
inversion in the product.
Q3: Rationalize why Alcohol B will react under the indicated reaction conditions, but Alcohol A
will not.
A
☑
OH
B
OH
PBr3
R-Br
Q1: Predict the major organic product(s) of the following reactions. Include stereochemistry
when necessary. Write NR if no reaction, try to explain.
1.) LDA, THF
2.)
СОН
CI
OH
H2SO4, heat
OH
m......
OH
1.) PCC, CH2Cl2
2.) CH3CH2MgBr, THF
3.) H3O+
4.) TsCl, pyr
5.) tBuOK, tBuOH
1.) SOCI 2, CHCI 3
2.) CH3CH2ONA, DMF
OH
1.) HBr
2.) Mg, THF
3.) H₂CO, THE
4.) H3O+
OH
NaH, THF
Chapter 16 Solutions
OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
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