OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 16, Problem 85QRT
The biological oxidation of ethanol, C2H5OH, is also a source of Gibbs free energy.
- (a) Does the oxidation of 1 g ethanol give more or less energy than the oxidation of 1 g glucose? (Hint: Write the balanced equation for the production of carbon dioxide and water from ethanol and oxygen, and use Appendix J.)
- (b) Comment on potential problems of replacing glucose with ethanol in your diet.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
may you please show all steps! i am having a hard time understanding and applying in this format, thank you!
10. Complete the substitution reaction of 2 pentanol with these reagents.
Reagents & Reaction Conditions use practice sheet. Please write only
major products, minor product like water, other gases are not
required.
Hint: In substitution of alcohol, we generally substitute OH group
with Halogens like cl, Br, F using some reagent containing
halogens. Ensure to add halogens to the same carbon number
where you are removing OH from
Examples
Alcohols can be converted to Alkyl Halides with HX acids
HBr
H₂O
HCI
+ H₂O
HI
+
H₂O
CH,CH₂OH + SOCI₂
CH,CH₂OH + PCI₁₂
A
BBYJU'S
CH CHCI + SO₂+ HCI
CH₂CH CIP(OH), + HCI
CH,CH₂OH + PCI CHCHCI + POCI + HCI
CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr
1. Reaction with HBr with 2 Pentanol
2.Reaction with HI with 2 pentanol
© Byjus.com
3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role)
4.Reaction with SOCI,, with 2 Pentanol
5.Reaction with PBr; or PCl, with 2 pentanol
3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write
out the
structures of 2-methyl-2-propanol and also any oxidation products of 2-
methyl-2-
propanol. If there is more than one oxidation product, give the structure of
each
of the products.
4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a
common name
by which it is much better known (You'll see it in the grocery store or
pharmacy).
Give that common name
5. Aldehydes can be synthesized by the oxidation of. Please choose from
below choices
A. Primary alcohols
B. Secondary alcohols
C. Organic acids
D. Inorganic acids
6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the
product.
Chapter 16 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 16.1 - Write a chemical equation for each process and...Ch. 16.2 - Prob. 16.2CECh. 16.3 - A chemical reaction transfers 30.8 kJ to a thermal...Ch. 16.3 - Prob. 16.3CECh. 16.3 - Prob. 16.2PSPCh. 16.3 - For each process, predict whether entropy...Ch. 16.4 - Calculate the entropy change for each of these...Ch. 16.5 - The reaction of carbon monoxide with hydrogen to...Ch. 16.5 - Prob. 16.4PSPCh. 16.5 - Prob. 16.6CE
Ch. 16.5 - Prob. 16.8ECh. 16.6 - Prob. 16.9CECh. 16.6 - In the text we concluded that the reaction to...Ch. 16.6 - Prob. 16.10CECh. 16.6 - Prob. 16.6PSPCh. 16.7 - Prob. 16.7PSPCh. 16.7 - Prob. 16.8PSPCh. 16.7 - Prob. 16.9PSPCh. 16.8 - Predict whether each reaction is reactant-favored...Ch. 16.9 - Prob. 16.13ECh. 16.9 - Prob. 16.11PSPCh. 16.9 - Prob. 16.12PSPCh. 16.9 - Prob. 16.14ECh. 16.11 - All of these substances are stable with respect to...Ch. 16 - Define the terms product-favored System and...Ch. 16 - What are the two ways that a final chemical state...Ch. 16 - Define the term entropy, and give an example of a...Ch. 16 - Prob. 4QRTCh. 16 - Prob. 5QRTCh. 16 - Prob. 6QRTCh. 16 - Prob. 7QRTCh. 16 - Prob. 8QRTCh. 16 - Prob. 9QRTCh. 16 - Prob. 10QRTCh. 16 - Prob. 11QRTCh. 16 - Prob. 12QRTCh. 16 - Prob. 13QRTCh. 16 - Prob. 14QRTCh. 16 - Prob. 15QRTCh. 16 - Prob. 16QRTCh. 16 - Prob. 17QRTCh. 16 - Suppose you have four identical molecules labeled...Ch. 16 - For each process, tell whether the entropy change...Ch. 16 - Prob. 20QRTCh. 16 - For each situation described in Question 13,...Ch. 16 - Prob. 22QRTCh. 16 - Prob. 23QRTCh. 16 - Prob. 24QRTCh. 16 - Prob. 25QRTCh. 16 - Prob. 26QRTCh. 16 - Prob. 27QRTCh. 16 - Prob. 28QRTCh. 16 - Prob. 29QRTCh. 16 - Prob. 30QRTCh. 16 - Prob. 31QRTCh. 16 - Diethyl ether, (C2H5)2O, was once used as an...Ch. 16 - Calculate rS for each substance when the quantity...Ch. 16 - Prob. 34QRTCh. 16 - Prob. 35QRTCh. 16 - Check your predictions in Question 28 by...Ch. 16 - Prob. 37QRTCh. 16 - Prob. 38QRTCh. 16 - Prob. 39QRTCh. 16 - Prob. 40QRTCh. 16 - Prob. 41QRTCh. 16 - Prob. 42QRTCh. 16 - Prob. 43QRTCh. 16 - Prob. 44QRTCh. 16 - Prob. 45QRTCh. 16 - Prob. 46QRTCh. 16 - Hydrogen bums in air with considerable heat...Ch. 16 - Prob. 48QRTCh. 16 - Prob. 49QRTCh. 16 - Prob. 50QRTCh. 16 - Prob. 51QRTCh. 16 - The reaction of magnesium with water can be used...Ch. 16 - Prob. 53QRTCh. 16 - Prob. 54QRTCh. 16 - Prob. 55QRTCh. 16 - Prob. 56QRTCh. 16 - Prob. 57QRTCh. 16 - Prob. 58QRTCh. 16 - Prob. 59QRTCh. 16 - Prob. 60QRTCh. 16 - Prob. 61QRTCh. 16 - Estimate ΔrG° at 2000. K for each reaction in...Ch. 16 - Prob. 63QRTCh. 16 - Some metal oxides, such as lead(II) oxide, can be...Ch. 16 - Prob. 65QRTCh. 16 - Prob. 66QRTCh. 16 - Use data from Appendix J to obtain the equilibrium...Ch. 16 - Prob. 68QRTCh. 16 - Prob. 69QRTCh. 16 - Use the data in Appendix J to calculate rG andKPat...Ch. 16 - Prob. 71QRTCh. 16 - Prob. 72QRTCh. 16 - Prob. 73QRTCh. 16 - Prob. 74QRTCh. 16 - Prob. 75QRTCh. 16 - Prob. 76QRTCh. 16 - Prob. 77QRTCh. 16 - Prob. 78QRTCh. 16 - Prob. 79QRTCh. 16 - The molecular structure shown is of one form of...Ch. 16 - Another step in the metabolism of glucose, which...Ch. 16 - In muscle cells under the condition of vigorous...Ch. 16 - The biological oxidation of ethanol, C2H5OH, is...Ch. 16 - Prob. 86QRTCh. 16 - For one day, keep a log of all the activities you...Ch. 16 - Billions of pounds of acetic acid are made each...Ch. 16 - Determine the standard Gibbs free energy change,...Ch. 16 - There are millions of organic compounds known, and...Ch. 16 - Actually, the carbon in CO2(g) is...Ch. 16 - The standard molar entropy of methanol vapor,...Ch. 16 - The standard molar entropy of iodine vapor, I2(g),...Ch. 16 - Prob. 94QRTCh. 16 - Prob. 96QRTCh. 16 - Prob. 97QRTCh. 16 - Prob. 98QRTCh. 16 - Prob. 99QRTCh. 16 - Prob. 100QRTCh. 16 - Appendix J lists standard molar entropies S, not...Ch. 16 - When calculating rSfromSvalues, it is necessary to...Ch. 16 - Prob. 103QRTCh. 16 - Explain how the entropy of the universe increases...Ch. 16 - Prob. 105QRTCh. 16 - Prob. 106QRTCh. 16 - Prob. 107QRTCh. 16 - Prob. 108QRTCh. 16 - Prob. 109QRTCh. 16 - Reword the statement in Question 109 so that it is...Ch. 16 - Prob. 111QRTCh. 16 - Prob. 112QRTCh. 16 - Prob. 113QRTCh. 16 - Prob. 114QRTCh. 16 - Prob. 115QRTCh. 16 - Prob. 116QRTCh. 16 - From data in Appendix J, estimate (a) the boiling...Ch. 16 - Prob. 118QRTCh. 16 - Prob. 119QRTCh. 16 - Prob. 120QRTCh. 16 - Prob. 121QRTCh. 16 - Prob. 122QRTCh. 16 - Prob. 123QRTCh. 16 - Prob. 124QRTCh. 16 - Prob. 125QRTCh. 16 - Prob. 126QRTCh. 16 - The standard equilibrium constant is 2.1109for...Ch. 16 - Prob. 16.ACPCh. 16 - Prob. 16.CCPCh. 16 - Prob. 16.DCPCh. 16 - Consider planet Earth as a thermodynamic system....
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
- Indicate whether the product of the reaction between Naphthalene and CrO3 in acetic acid at 25ºC is 1,4 naphthoquinone or phthalic anhydride.arrow_forwardIndicate the products of the reaction between CH3COCH2COOC2H5 and Na+-OC2H5.arrow_forwardPrimary, Secondary, and Tertiary Alcohols O-H O-H O-H R₁-C-H R₁-C-H R₁-C-R₁ H R₂ R₂ Primary Alcohol Secondary Alcohol ChemistryLearner.com R stands for Carbon group like ethyl methyl propyl Tertiary Alcohol If 1 carbon group with two H attached to alcoholic carbon, then primary If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary IF 3 carbon group and no H attach to alcoholic carbon then tertiary. The bottom line Starting "Weak" oxidant material PCC, DMP, Swern, etc Primary alcohol Aldehyde OH Secondary alcohol Ketone OH "Strong" oxidant KMnO4, H₂CrO4 (or equivalent) OH Carboxylic acid 요 Ketone No reaction No reaction Tertiary alcohol 1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the structures of ethanol and any oxidation products of ethanol. If there is more than one oxidation product, give the structure of each of the products. 2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-propanol and any…arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY