GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 16, Problem 77E
The molecular solid
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 16 Solutions
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 16 - According to the Brønsted-Lowry theory, lebel each...Ch. 16 - Write the formula of the conjugate based in the...Ch. 16 - For each of the following, identify the acides and...Ch. 16 - Which of the following species are amphiprotic in...Ch. 16 - Why which of the following bases will the...Ch. 16 - In a manner similar to equation (16.3), represent...Ch. 16 - With the aid of Table 16.2, predict the direction...Ch. 16 - With the aid of Table 16.2, predict the direction...Ch. 16 - Calculate [H2O4] and [OH-] or each solution: (a)...Ch. 16 - What is the pH of each of the following solution?...
Ch. 16 - Calculate [H2O4] and pH in saturated Ba(OH)2(aq) ,...Ch. 16 - A saturated aqueous soon of Ca(OH)2, has a pH of...Ch. 16 - Prob. 13ECh. 16 - What is the PH of the solution obtained when 125mL...Ch. 16 - How many millilaters at concentrated HCI(aq) (360%...Ch. 16 - How many milliliters of a 15.0%, by mass solution...Ch. 16 - What volume of 6.15 N HCI(aq) is required to...Ch. 16 - A 282 L volume of HCl(g), measured at 742 mmHg and...Ch. 16 - 50.00 mL of 0.0155 M Hl(aq) is mixed with 75.00 mL...Ch. 16 - 2500 mL of a HNO2(aq) solution with a pH of 2.12...Ch. 16 - What are the [H2O4] and pH of 0.143 M HNO2 ?Ch. 16 - What are the [H2O4] and pH of 0.085 M C2H2NH2 ?Ch. 16 - For the ionization of phenylacetic acid,...Ch. 16 - A 625 mL sample an aqueous solution containing...Ch. 16 - Fluroaceticectic acid occurs in gifblaar, one of...Ch. 16 - Caproic acid, HCgH11O2 , found in small amounts in...Ch. 16 - What mass of benzoic acid, CgC5COOH , would you...Ch. 16 - Whet must be the molarity of en aqueous solution...Ch. 16 - What are [H2O4] , [OH-] , pH, and pOH of 0.55 M M...Ch. 16 - What are [H2O4],[CH+],NH, and NH of 0.300 M CH2NH2...Ch. 16 - The solubility of 1-naphthylamin, C10H1NH2 ,a...Ch. 16 - A saturated aqueous solution of o-nitropenol,...Ch. 16 - A particular vinegar e found to contain 57% acetic...Ch. 16 - A particular household ammoni a solution (d = 0.97...Ch. 16 - A 275 mL sample of vapor in equilibrium with...Ch. 16 - One handbook lists a value of 95 for pK, of...Ch. 16 - In the diagram below, the sketch on the far on the...Ch. 16 - In the diagram below, the sketch on the far left...Ch. 16 - What is the (a) degree of ionization and (b)...Ch. 16 - What is the (a) degree of ionization and (b)...Ch. 16 - What must be the molarity of an aqueous solution...Ch. 16 - What must be the molarity of an acetic acid...Ch. 16 - Continuing the dilution described in Example 16.4,...Ch. 16 - What is the (a) degree of ionization and (b)...Ch. 16 - Prob. 45ECh. 16 - Cola drinks have a phosphoric acid content that as...Ch. 16 - Determine [H2O+],[HS-] , and [S2-] for the...Ch. 16 - For 0.045 M MH2CO2 , a weak diprotic acid....Ch. 16 - Calculate [H2O4] , [HSO4] , and SO42- in (a) 0.75M...Ch. 16 - Adipic acid, HOOC( CH2)4COOH , is among the top 50...Ch. 16 - The antimalarial dru g quinine, C20H24O2N2 , is a...Ch. 16 - For hydrazine, N2H4,pKa1=6.07 end pK32=15.05 ....Ch. 16 - Codeine, C12H21O2N , is an opiate and...Ch. 16 - Approximately 4 metric tons of quinoline, C8H7N ,...Ch. 16 - Complete the following equations in those...Ch. 16 - From data in Table 16.4, determine (a) Kgfor...Ch. 16 - Predict whether a solution of each of the...Ch. 16 - Arrange the following 0.010M solutions in order of...Ch. 16 - What is the pH of an aqueous solution that is...Ch. 16 - What is the pH of an aqueous solution that is...Ch. 16 - Sorbic acid, CH2CH=CH=CH2CO2H(pKg=4.772) , is...Ch. 16 - Pyridine, C3H2N(pKb=8.82) , from a salt,...Ch. 16 - For each of the blowing ions, write two equations—...Ch. 16 - Suppose you wanted to produce an aqueous solution...Ch. 16 - Predict which is the stronger acid: (a) HClO2 or...Ch. 16 - Explain why trichloroacetic acid, CCl2COOH , is a...Ch. 16 - Which is the stronger acid of each of the...Ch. 16 - Indicate Which of the following the weakest ac,...Ch. 16 - From the following bases, select the one with the...Ch. 16 - For the molecular models shown, write the formula...Ch. 16 - For each reaction draw a Lewis structure for each...Ch. 16 - In the following reactions indicate which is the...Ch. 16 - Indicate whether each of the following is a Lewis...Ch. 16 - Each of the following is a Lewis acid-base...Ch. 16 - The three following reactions are acid-base...Ch. 16 - CO2(g) can be removed from confined quarters (such...Ch. 16 - The molecular solid l2(s) e only slightly in...Ch. 16 - The following very strong acids are formed by the...Ch. 16 - Use Lewis structures to diagram the following...Ch. 16 - Use Lewis structures to diagram the following...Ch. 16 - Prob. 81IAECh. 16 - Prob. 82IAECh. 16 - Prob. 83IAECh. 16 - Prob. 84IAECh. 16 - Prob. 85IAECh. 16 - Prob. 86IAECh. 16 - From the observation that 0.0500M vinylacetic acid...Ch. 16 - Prob. 88IAECh. 16 - Use material balance and an electroneutrality...Ch. 16 - Prob. 90IAECh. 16 - Prob. 91IAECh. 16 - Prob. 92IAECh. 16 - Prob. 93IAECh. 16 - What mass of acetic acad, CH2COOH , must be...Ch. 16 - Prob. 95IAECh. 16 - Prob. 96IAECh. 16 - Prob. 97IAECh. 16 - Prob. 98IAECh. 16 - Prob. 99IAECh. 16 - Prob. 100IAECh. 16 - In this problem, we will use material balance and...Ch. 16 - Prob. 102IAECh. 16 - Prob. 103IAECh. 16 - Prob. 104IAECh. 16 - Maleic acid is a carbon-hydrogen-oxygen compound...Ch. 16 - In Example 16-9, rather than use the quadratic...Ch. 16 - Apply the general method for solution equilibrium...Ch. 16 - Prob. 108SAECh. 16 - Prob. 109SAECh. 16 - Explain the important distinctions between each...Ch. 16 - Prob. 111SAECh. 16 - Prob. 112SAECh. 16 - Prob. 113SAECh. 16 - Prob. 114SAECh. 16 - Prob. 115SAECh. 16 - Prob. 116SAECh. 16 - Prob. 117SAECh. 16 - Prob. 118SAECh. 16 - Determine the pH of 2.05 M NaCH2 ClCOO. (Use data...Ch. 16 - Prob. 120SAECh. 16 - A solution is found to have pH=5pOH . Is this...Ch. 16 - Propionic acid, CH2CHCOOH , is 0.42% ionized in...Ch. 16 - The conjugate acid of HPO42- is (a) PO42 ; (b)...Ch. 16 - Prob. 124SAECh. 16 - Prob. 125SAECh. 16 - Appendix E describes a useful study aid known as...
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
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