Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
thumb_up100%
Chapter 16, Problem 45E
Incomplete Lewis structures for the nitrous acid molecule, HNO2, and the nitrite ion, NO2 are shown here.
- Complete each Lewis structure by adding electron pairs as needed.
- Is the formal charge on N the same or different in these two species?
- Would either HNO2 or NO2 be expected to exhibit resonance?
- Would you expect the N=0 bond in HNO2 to be longer, shorter, or the same length as the N_________-O bonds in NO2-? [Sections 8.5 and 8.6] H-O-N= O-N=O
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
What possible error(s) exist in the Lewis structure (assume we are trying to represent the best
possible Lewis structure for the NO₂S ion knowing N is the central atom in this polyatomic ion)?
[:ö==S:
N=
CO
:O:
The best structure would have double bond and two lone pairs on each oxygen atom and a single bond with
three lone pairs on the sulfur.
There are no errors. This is the best possible structure.
The Lewis structure above does not minimize formal charges, thus is the not the best possible structure.
The nitrogen atom has an expanded octet, and this structure is impossible.
The Lewis structure contains the wrong number of electrons, thus this structure is impossible.
17) Is each proposed structure in Figure 4, a plausible Lewis structure for CO₂? Why or why not?
Figure 4: Two Possible Lewis Structures for CO2
Ö=
-C
II
I
EO:
(+)
(-)
Experimentally, we find that both C-O bonds in CO 2 are identical. The C-O bond energy in CO₂
is 804 kJ/mol; that is it requires 804 kI to break one mole of C-O bonds in CO₂
Hydrogen azide (HN3) is a shock-sensitive liquid, which means it explodes when subjected to a physical shock. The HN3molecule contains two N-N bonds with bond lengths 113 pm and 124 pm. The H-N-N bond angle is 112°. Draw two Lewis structures of HN3 that obey the octet rule. What is the formal charge of each atom in your structures? Which structure is most consistent with the experimental data?
Chapter 16 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 16.2 - Consider the following equation: Ca + (g) + e-...Ch. 16.2 -
7.55(a) Does metallic character increase,...Ch. 16.2 - Prob. 16.2.1PECh. 16.2 - Predict whether each of the following oxides is...Ch. 16.2 - Prob. 16.3.1PECh. 16.2 - Would you expect manganese(II) oxide, MnO, react...Ch. 16.3 - Prob. 16.4.1PECh. 16.3 - Prob. 16.4.2PECh. 16.3 - An element X reacts with oxygen to form X02 and...Ch. 16.3 - Prob. 16.5.2PE
Ch. 16.4 - Prob. 16.6.1PECh. 16.4 - Prob. 16.6.2PECh. 16.4 - Prob. 16.7.1PECh. 16.4 - Prob. 16.7.2PECh. 16.5 - Write a balanced equation for the reaction that...Ch. 16.5 - (a) As described in Section 7.7 , the alkali...Ch. 16.5 - Prob. 16.9.1PECh. 16.5 - Prob. 16.9.2PECh. 16.6 - Arrange each of the following sets of atoms and...Ch. 16.6 - Prob. 16.10.2PECh. 16.6 - In the ionic compoundsLiF,NaCI,KBr, andRbl, the...Ch. 16.6 - Prob. 16.11.2PECh. 16.6 -
7.38 Write equations that show the process for...Ch. 16.6 - Prob. 16.12.2PECh. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - (a) What is the trend in first ionization energies...Ch. 16.6 - Prob. 16.14.2PECh. 16.7 - Prob. 16.15.1PECh. 16.7 - Prob. 16.15.2PECh. 16.7 - Prob. 16.16.1PECh. 16.7 - Prob. 16.16.2PECh. 16.8 - Prob. 16.17.1PECh. 16.8 - Write an equation for the second electron affinity...Ch. 16.9 - If the electron affinity for an element is a...Ch. 16.9 - Prob. 16.18.2PECh. 16.9 -
7.52 What is the relationship between the...Ch. 16.9 - Prob. 16.19.2PECh. 16.10 - Prob. 16.20.1PECh. 16.10 - Prob. 16.20.2PECh. 16 - Mercury in the environment can exist in oxidation...Ch. 16 - When magnesium metal is burned in air (Figure 3.6...Ch. 16 - The dipole moment of chlorine monofluoride,...Ch. 16 - Prob. 3ECh. 16 - Consider the element silicon, Si. Write its...Ch. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Which of the these elements is most likely to from...Ch. 16 - Prob. 22ECh. 16 - Which of the following bond is the most polar? H-F...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Which of the following bonds is the most polar? a....Ch. 16 - Which of the following bonds is most polar: S-Cl,...Ch. 16 - Prob. 29ECh. 16 -
How many valence electrons should appear in the...Ch. 16 - Compare the lewis symbol for neon the structure...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Which of the statements about resonance is true?...Ch. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - A portion of a two-dimensional "slab" of NaCl(s)...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Incomplete Lewis structures for the nitrous acid...Ch. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - True or false: The hydrogen atom is most stable...Ch. 16 - Prob. 50ECh. 16 - What is the Lewis symbol for each of the following...Ch. 16 - Using Lewis symbols, diagram the reaction between...Ch. 16 - Use Lewis symbols to represent the reaction that...Ch. 16 - Predict the chemical formula of the ionic compound...Ch. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Is lattice energy usually endothermic or...Ch. 16 - NaCI and KF have the same crystal structure. The...Ch. 16 - Consider the ionic compounds KF, NaCl, NaBr, and...Ch. 16 - Which of the following trends in lattice energy is...Ch. 16 - Energy is required to remove two electrons from Ca...Ch. 16 - Prob. 63ECh. 16 - Use data from Appendix C, Figure 7.10, and Figure...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Using Lewis symbols and Lewis structures, diagram...Ch. 16 - Use Lewis symbols and Lewis structures to diagram...Ch. 16 - Prob. 70ECh. 16 - What is the trend in electronegativity going from...Ch. 16 - Prob. 72ECh. 16 - By referring only to the periodic table, select...Ch. 16 - which of the following bonds are polar? B-F,...Ch. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - In the following pairs of binary compounds,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Draw the dominant Lewis structure for the...Ch. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - 8.62 For Group 3A-7A elements in the third row of...Ch. 16 - Draw the Lewis structures for each of the...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 -
8.66
Describe the molecule xenon trioxide, XeO3,...Ch. 16 -
8.67 There are many Lewis structures you could...Ch. 16 - Prob. 97ECh. 16 - Using Table 8.3, estimate H for each of the...Ch. 16 - Using Table 8.3, estimate H for the following...Ch. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Consider the stable elements through lead (Z =...Ch. 16 -
17.80]Figure 7.4 shows the radial probability...Ch. 16 - (a) If the core electrons were totally effective...Ch. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Prob. 109AECh. 16 - The following observations are made about two...Ch. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - Prob. 120IECh. 16 - The electron affinities. in kJ/mol, for the group...Ch. 16 -
7.99 Hydrogen is an unusual element because it...Ch. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Which of the following is the expected product of...Ch. 16 - Elemental cesium reacts more violently with water...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardConsider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forwardUsing the bond dissociation enthalpies in Table 8.8, estimate the enthalpy of combustion of gaseous methane, CH4, to give water vapor and carbon dioxide gas.arrow_forward
- A common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called methyl cyanoacrylate, the main ingredient in Super Glue. Draw a complete Lewis structure for methyl cyanoacrylate in which all atoms have a formal charge of zero.arrow_forwardGiven the bonds C N, C H, C Br, and S O, (a) which atom in each is the more electronegative? (b) which of these bonds is the most polar?arrow_forwardDraw a Lewis structure for each of the following molecules or ions. (a) CS2 (b) BF4 (c) HNO2 (where the bonding is in the order HONO) (d) OSCl2 (where S is the central atom)arrow_forward
- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is In this molecule, which is the (a) weakest carbon-containing bond? (b) strongest carbon-containing bond? (c) most polar bond?arrow_forwardFor each of the following, use formal charges to choose the Lewis formula that gives the best description of the electron distribution: a ClO2F b SO2 c ClO3arrow_forwardDraw the structure of hydroxylamine, H3NO, and assign formal charges; look up the structure. Is the actual structure consistent with the formal charges?arrow_forward
- Four hypothetical elements, A, B, C, and D, have electronegativities A = 3.8, B = 3.3, C = 2.8, and D = 1.3. These elements form the compounds BA, DA, DB, and CA. Arrange the compounds in order of a. Increasing ionic bond character b. Decreasing covalent bond characterarrow_forward1. For which of the following species, SO32−, NO+, or NO2+, is the bonding described by two or more resonance structures? SO32− and NO+ NO+ and NO2+ NO2+ SO32−arrow_forwardThis Lewis structure for SF5+ is drawn incorrectly. What error was made when determining the number of valence electrons?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY