Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 16, Problem 126IE
Elemental cesium reacts more violently with water than does elemental sodium. Which of the following best explains this difference in reactivity? (i) Sodium has greater metallic character than does cesium. (ii) The first ionization energy of cesium is less than that of sodium. (iii) The
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(a) Why do successive IEs of a given element always increase? (b) When the difference between successive IEs of a given element is exceptionally large (for example, between IE1 and IE2 of K), what do we learn about its electron configuration? (c) The bars represent the relative magnitudes of the first five ionization energies of an atom: Identify the element and write its complete electron config uration, assuming it comes from (a) Period 2; (b) Period 3; (c) Period 4.
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.
(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B?
(b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons?
(c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons.
(d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas.
(e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine.
(f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Chapter 16 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 16.2 - Consider the following equation: Ca + (g) + e-...Ch. 16.2 -
7.55(a) Does metallic character increase,...Ch. 16.2 - Prob. 16.2.1PECh. 16.2 - Predict whether each of the following oxides is...Ch. 16.2 - Prob. 16.3.1PECh. 16.2 - Would you expect manganese(II) oxide, MnO, react...Ch. 16.3 - Prob. 16.4.1PECh. 16.3 - Prob. 16.4.2PECh. 16.3 - An element X reacts with oxygen to form X02 and...Ch. 16.3 - Prob. 16.5.2PE
Ch. 16.4 - Prob. 16.6.1PECh. 16.4 - Prob. 16.6.2PECh. 16.4 - Prob. 16.7.1PECh. 16.4 - Prob. 16.7.2PECh. 16.5 - Write a balanced equation for the reaction that...Ch. 16.5 - (a) As described in Section 7.7 , the alkali...Ch. 16.5 - Prob. 16.9.1PECh. 16.5 - Prob. 16.9.2PECh. 16.6 - Arrange each of the following sets of atoms and...Ch. 16.6 - Prob. 16.10.2PECh. 16.6 - In the ionic compoundsLiF,NaCI,KBr, andRbl, the...Ch. 16.6 - Prob. 16.11.2PECh. 16.6 -
7.38 Write equations that show the process for...Ch. 16.6 - Prob. 16.12.2PECh. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - (a) What is the trend in first ionization energies...Ch. 16.6 - Prob. 16.14.2PECh. 16.7 - Prob. 16.15.1PECh. 16.7 - Prob. 16.15.2PECh. 16.7 - Prob. 16.16.1PECh. 16.7 - Prob. 16.16.2PECh. 16.8 - Prob. 16.17.1PECh. 16.8 - Write an equation for the second electron affinity...Ch. 16.9 - If the electron affinity for an element is a...Ch. 16.9 - Prob. 16.18.2PECh. 16.9 -
7.52 What is the relationship between the...Ch. 16.9 - Prob. 16.19.2PECh. 16.10 - Prob. 16.20.1PECh. 16.10 - Prob. 16.20.2PECh. 16 - Mercury in the environment can exist in oxidation...Ch. 16 - When magnesium metal is burned in air (Figure 3.6...Ch. 16 - The dipole moment of chlorine monofluoride,...Ch. 16 - Prob. 3ECh. 16 - Consider the element silicon, Si. Write its...Ch. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Which of the these elements is most likely to from...Ch. 16 - Prob. 22ECh. 16 - Which of the following bond is the most polar? H-F...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Which of the following bonds is the most polar? a....Ch. 16 - Which of the following bonds is most polar: S-Cl,...Ch. 16 - Prob. 29ECh. 16 -
How many valence electrons should appear in the...Ch. 16 - Compare the lewis symbol for neon the structure...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Which of the statements about resonance is true?...Ch. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - A portion of a two-dimensional "slab" of NaCl(s)...Ch. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Incomplete Lewis structures for the nitrous acid...Ch. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - True or false: The hydrogen atom is most stable...Ch. 16 - Prob. 50ECh. 16 - What is the Lewis symbol for each of the following...Ch. 16 - Using Lewis symbols, diagram the reaction between...Ch. 16 - Use Lewis symbols to represent the reaction that...Ch. 16 - Predict the chemical formula of the ionic compound...Ch. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Is lattice energy usually endothermic or...Ch. 16 - NaCI and KF have the same crystal structure. The...Ch. 16 - Consider the ionic compounds KF, NaCl, NaBr, and...Ch. 16 - Which of the following trends in lattice energy is...Ch. 16 - Energy is required to remove two electrons from Ca...Ch. 16 - Prob. 63ECh. 16 - Use data from Appendix C, Figure 7.10, and Figure...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Using Lewis symbols and Lewis structures, diagram...Ch. 16 - Use Lewis symbols and Lewis structures to diagram...Ch. 16 - Prob. 70ECh. 16 - What is the trend in electronegativity going from...Ch. 16 - Prob. 72ECh. 16 - By referring only to the periodic table, select...Ch. 16 - which of the following bonds are polar? B-F,...Ch. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - In the following pairs of binary compounds,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Draw the dominant Lewis structure for the...Ch. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - 8.62 For Group 3A-7A elements in the third row of...Ch. 16 - Draw the Lewis structures for each of the...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 -
8.66
Describe the molecule xenon trioxide, XeO3,...Ch. 16 -
8.67 There are many Lewis structures you could...Ch. 16 - Prob. 97ECh. 16 - Using Table 8.3, estimate H for each of the...Ch. 16 - Using Table 8.3, estimate H for the following...Ch. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Consider the stable elements through lead (Z =...Ch. 16 -
17.80]Figure 7.4 shows the radial probability...Ch. 16 - (a) If the core electrons were totally effective...Ch. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Prob. 109AECh. 16 - The following observations are made about two...Ch. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - Prob. 120IECh. 16 - The electron affinities. in kJ/mol, for the group...Ch. 16 -
7.99 Hydrogen is an unusual element because it...Ch. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Which of the following is the expected product of...Ch. 16 - Elemental cesium reacts more violently with water...
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