INTRO TO CHEMISTRY EBK ACCESS CARD >I<
5th Edition
ISBN: 9781260916430
Author: BAUER
Publisher: MCG
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Question
Chapter 16, Problem 41QP
(a)
Interpretation Introduction
Interpretation:
The IUPAC name of the given compound is to be identified.
(b)
Interpretation Introduction
Interpretation:
The IUPAC name of the given compound is to be identified.
(c)
Interpretation Introduction
Interpretation:
The IUPAC name of the given compound to be identified.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 16 Solutions
INTRO TO CHEMISTRY EBK ACCESS CARD >I<
Ch. 16 - Prob. 1QCCh. 16 - Prob. 2QCCh. 16 - Prob. 3QCCh. 16 - What are cyclic hydrocarbons, and how do they...Ch. 16 - Prob. 5QCCh. 16 - Prob. 6QCCh. 16 - Prob. 7QCCh. 16 - Prob. 8QCCh. 16 - Prob. 9QCCh. 16 - Prob. 1PP
Ch. 16 - Prob. 2PPCh. 16 - Prob. 3PPCh. 16 - Prob. 4PPCh. 16 - Prob. 5PPCh. 16 - Prob. 6PPCh. 16 - Prob. 7PPCh. 16 - Prob. 8PPCh. 16 - Prob. 9PPCh. 16 - Prob. 10PPCh. 16 - Prob. 11PPCh. 16 - Prob. 1QPCh. 16 - Prob. 2QPCh. 16 - Prob. 3QPCh. 16 - Prob. 4QPCh. 16 - Prob. 5QPCh. 16 - Prob. 6QPCh. 16 - Prob. 7QPCh. 16 - Prob. 8QPCh. 16 - Prob. 9QPCh. 16 - Prob. 10QPCh. 16 - Prob. 11QPCh. 16 - Prob. 12QPCh. 16 - Prob. 13QPCh. 16 - Prob. 14QPCh. 16 - Prob. 15QPCh. 16 - Prob. 16QPCh. 16 - Prob. 17QPCh. 16 - Prob. 18QPCh. 16 - Prob. 19QPCh. 16 - Prob. 20QPCh. 16 - Prob. 21QPCh. 16 - Prob. 22QPCh. 16 - Prob. 23QPCh. 16 - Prob. 24QPCh. 16 - Prob. 25QPCh. 16 - Prob. 26QPCh. 16 - Prob. 27QPCh. 16 - Prob. 28QPCh. 16 - Prob. 29QPCh. 16 - Prob. 30QPCh. 16 - Prob. 31QPCh. 16 - Prob. 32QPCh. 16 - Prob. 33QPCh. 16 - Prob. 34QPCh. 16 - Prob. 35QPCh. 16 - Prob. 36QPCh. 16 - Prob. 37QPCh. 16 - Prob. 38QPCh. 16 - Prob. 39QPCh. 16 - Prob. 40QPCh. 16 - Prob. 41QPCh. 16 - Write IUPAC names for the following compounds....Ch. 16 - Prob. 43QPCh. 16 - Prob. 44QPCh. 16 - Prob. 45QPCh. 16 - Prob. 46QPCh. 16 - Prob. 47QPCh. 16 - Prob. 48QPCh. 16 - Prob. 49QPCh. 16 - Prob. 50QPCh. 16 - Prob. 51QPCh. 16 - Prob. 52QPCh. 16 - Prob. 53QPCh. 16 - Prob. 54QPCh. 16 - Prob. 55QPCh. 16 - Prob. 56QPCh. 16 - Prob. 57QPCh. 16 - Prob. 58QPCh. 16 - Prob. 59QPCh. 16 - Prob. 60QPCh. 16 - Prob. 61QPCh. 16 - Prob. 62QPCh. 16 - Prob. 63QPCh. 16 - Prob. 64QPCh. 16 - Prob. 65QPCh. 16 - Prob. 66QPCh. 16 - Prob. 67QPCh. 16 - Prob. 68QPCh. 16 - Prob. 69QPCh. 16 - Prob. 70QPCh. 16 - Prob. 71QPCh. 16 - Prob. 72QPCh. 16 - Prob. 73QPCh. 16 - Prob. 74QPCh. 16 - Prob. 75QPCh. 16 - Prob. 76QPCh. 16 - Prob. 77QPCh. 16 - Prob. 78QPCh. 16 - Prob. 79QPCh. 16 - Prob. 80QPCh. 16 - Prob. 81QPCh. 16 - Prob. 82QPCh. 16 - Prob. 83QPCh. 16 - Prob. 84QPCh. 16 - Prob. 85QPCh. 16 - Prob. 86QPCh. 16 - Prob. 87QPCh. 16 - Prob. 88QPCh. 16 - Predict and explain the relative boiling points of...Ch. 16 - Prob. 90QPCh. 16 - Prob. 91QPCh. 16 - Prob. 92QPCh. 16 - Prob. 93QPCh. 16 - Prob. 94QPCh. 16 - Prob. 95QPCh. 16 - Prob. 96QPCh. 16 - Prob. 97QPCh. 16 - Prob. 98QPCh. 16 - Prob. 99QPCh. 16 - Prob. 100QPCh. 16 - Prob. 101QPCh. 16 - Prob. 102QPCh. 16 - Prob. 103QPCh. 16 - Prob. 104QPCh. 16 - Prob. 105QPCh. 16 - Prob. 106QPCh. 16 - Prob. 107QPCh. 16 - Prob. 108QPCh. 16 - Prob. 109QPCh. 16 - Prob. 110QPCh. 16 - Prob. 111QPCh. 16 - Prob. 112QPCh. 16 - Prob. 113QPCh. 16 - Prob. 114QPCh. 16 - Prob. 115QPCh. 16 - Prob. 116QPCh. 16 - Prob. 117QPCh. 16 - Prob. 118QPCh. 16 - Prob. 119QPCh. 16 - Prob. 120QPCh. 16 - Prob. 121QPCh. 16 - Draw the line structures for the ether and two...Ch. 16 - Prob. 123QPCh. 16 - Prob. 124QPCh. 16 - Prob. 125QPCh. 16 - Prob. 126QPCh. 16 - Write structural formulas for all the isomers of...Ch. 16 - Prob. 128QPCh. 16 - Prob. 129QPCh. 16 - Prob. 130QPCh. 16 - Prob. 131QPCh. 16 - Prob. 132QPCh. 16 - Prob. 133QPCh. 16 - Prob. 134QPCh. 16 - Prob. 135QPCh. 16 - Prob. 136QPCh. 16 - Prob. 137QPCh. 16 - Prob. 138QPCh. 16 - Prob. 139QPCh. 16 - Prob. 140QPCh. 16 - Prob. 141QPCh. 16 - Prob. 142QPCh. 16 - Prob. 143QP
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- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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