Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 16, Problem 17QAP
. What does it mean to say that an acid is strong in aqueous solution? What does this reveal about the ability of the acids anion to attract protons?
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Students have asked these similar questions
5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 16 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 16.1 - Exercise 16.1 Which of the following represent...Ch. 16.2 - Vinegar contains acetic acid and is used in salad...Ch. 16.3 - Exercise 16.2 Calculate [H+] in a solution in...Ch. 16.4 - Prob. 16.3SCCh. 16.4 - Prob. 1CTCh. 16.4 - Prob. 16.4SCCh. 16.4 - Exercise 16.5 The pH of rainwater in a polluted...Ch. 16.4 - Exercise 16.6 The pOH of a liquid drain cleaner...Ch. 16.5 - Exercise 16.7 Calculate the pH of a solution of...Ch. 16 - You are asked for the H+ concentration in a...
Ch. 16 - Explain why Cl- does not affect the pH of an...Ch. 16 - Write the general reaction for an acid acting in...Ch. 16 - Differentiate among the terms concentrated,...Ch. 16 - What is meant by “pH”? True or false: A strong...Ch. 16 - Consider two separate solutions: one containing a...Ch. 16 - Prob. 7ALQCh. 16 - Prob. 8ALQCh. 16 - Stanley’s grade-point average (GPA) is 3.28. What...Ch. 16 - Prob. 10ALQCh. 16 - . Mixing together aqueous solutions of acetic acid...Ch. 16 - Prob. 12ALQCh. 16 - . Consider the equation:...Ch. 16 - . Choose the answer that best completes the...Ch. 16 - Prob. 15ALQCh. 16 - . The following figures are molecular-level...Ch. 16 - Prob. 17ALQCh. 16 - What are some physical properties that...Ch. 16 - Write an equation showing how HCl(g) behaves as an...Ch. 16 - Prob. 3QAPCh. 16 - How do the components of a conjugate acid—base...Ch. 16 - 5. Given the general equation illustrating the...Ch. 16 - According to Arrhenius, ____________ produce...Ch. 16 - Which of the following do not represent a...Ch. 16 - Which of the following do not represent a...Ch. 16 - In each of the following chemical equations,...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - . Write the conjugate acid for each of the...Ch. 16 - Prob. 13QAPCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . Write a chemical equation showing how each of...Ch. 16 - . What does it mean to say that an acid is strong...Ch. 16 - Prob. 18QAPCh. 16 - . How is the strength of an acid related to the...Ch. 16 - . A strong acid has a weak conjugate base, whereas...Ch. 16 - . Write the formula for the hydronium ion. Write...Ch. 16 - Prob. 22QAPCh. 16 - . Organic acids contain the carboxyl group Using...Ch. 16 - Prob. 24QAPCh. 16 - 25. Which of the following acids have relatively...Ch. 16 - . The “Chemistry in Focus” segment Plants Fight...Ch. 16 - . Water is the most common amphoteric substance,...Ch. 16 - . Anions containing hydrogen (for example. HCO3and...Ch. 16 - . What is meant by the iou-product constant for...Ch. 16 - . What happens to the hydroxide ion concentration...Ch. 16 - Prob. 31QAPCh. 16 - Prob. 32QAPCh. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - . Calculate the [OH-] in each of the following...Ch. 16 - 35. For each pair of concentrations, tell which...Ch. 16 - . For each pair of concentrations, tell which...Ch. 16 - . Why do scientists tend to express the acidity of...Ch. 16 - . Using Fig. 16.3, list the approximate pH value...Ch. 16 - . For a hydrogen ion concentration of 2.33106M,...Ch. 16 - . The “Chemistry in Focus” segment Garden-Variety...Ch. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 42QAPCh. 16 - Prob. 43QAPCh. 16 - Prob. 44QAPCh. 16 - Prob. 45QAPCh. 16 - . Calculate the pOH value corresponding to each of...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . For each hydrogen ion concentration listed,...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - Prob. 54QAPCh. 16 - 55. When 1 mole of gaseous hydrogen chloride is...Ch. 16 - . A bottle of acid solution is labeled “3 M HNO3.”...Ch. 16 - . Calculate the hydrogen ion concentration and the...Ch. 16 - . Calculate the pH of each of the following...Ch. 16 - . What characteristic properties do buffered...Ch. 16 - Prob. 60QAPCh. 16 - . Which component of a buffered solution is...Ch. 16 - Prob. 62QAPCh. 16 - . Which of the following combinations would act as...Ch. 16 - . A buffered solution is prepared containing...Ch. 16 - . The concepts of acid-base equilibria were...Ch. 16 - . Strong buses are bases that completely ionize in...Ch. 16 - Prob. 67APCh. 16 - Prob. 68APCh. 16 - Prob. 69APCh. 16 - Prob. 70APCh. 16 - Prob. 71APCh. 16 - Prob. 72APCh. 16 - Prob. 73APCh. 16 - Prob. 74APCh. 16 - 75. A conjugate acid-base pair Consists of two...Ch. 16 - . Acetate ion, C2H3O2- , has a stronger affinity...Ch. 16 - Prob. 77APCh. 16 - Prob. 78APCh. 16 - Prob. 79APCh. 16 - Prob. 80APCh. 16 - Prob. 81APCh. 16 - Prob. 82APCh. 16 - Prob. 83APCh. 16 - Prob. 84APCh. 16 - . A(n) _________ solution contains a conjugate...Ch. 16 - . When sodium hydroxide, NaOH, is added dropwise...Ch. 16 - . When hydrochloric acid, HCI. is added dropwise...Ch. 16 - . The following are representations of acid-base...Ch. 16 - . In each of the following chemical equations,...Ch. 16 - Prob. 90APCh. 16 - . Write the conjugate base for each of the...Ch. 16 - . Of the following combinations, which would act...Ch. 16 - Prob. 93APCh. 16 - . Calculate [H+] in each of the following...Ch. 16 - Prob. 95APCh. 16 - . Calculate the pH corresponding to each of the...Ch. 16 - Prob. 97APCh. 16 - Prob. 98APCh. 16 - Prob. 99APCh. 16 - . For each hydrogen or hydroxide ion concentration...Ch. 16 - . Calculate the hydrogen ion concentration, in...Ch. 16 - Prob. 102APCh. 16 - Prob. 103APCh. 16 - Prob. 104APCh. 16 - . Write the formulas for three combinations of...Ch. 16 - . Choose pairs in which the species listed first...Ch. 16 - . Complete the table for each of the following...Ch. 16 - . Consider 0.25 M solutions of the following...
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