Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 16, Problem 16.78P
Interpretation Introduction
Interpretation:
The proposed mechanism is valid or not has to be predicted; the three criteria have to be valid.
Concept introduction:
Reaction: Substances which are mutually involved each other in a chemical process and changed into different substances.
Mechanism of a reaction: The representation of step by step process involved in the chemical process is said to be mechanism of a
Elementary step: The first step in a reaction mechanism is said to be elementary step.
Intermediate: Sometimes, in between the reaction some separable amount and useful amount of substances are formed during the reaction and which are said to be intermediates
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
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while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
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2000
1500
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500
HAVENUMBERI-11
Chapter 16 Solutions
Chemistry: The Molecular Nature of Matter and Change
Ch. 16.2 - Balance the following equation and express the...Ch. 16.2 - Prob. 16.1BFPCh. 16.3 - Prob. 16.2AFPCh. 16.3 - Prob. 16.2BFPCh. 16.3 - Find the rate law, the individual and overall...Ch. 16.3 - Prob. 16.3BFPCh. 16.3 - Prob. 16.4AFPCh. 16.3 - Prob. 16.4BFPCh. 16.4 - Prob. 16.5AFPCh. 16.4 - Prob. 16.5BFP
Ch. 16.4 - Substance X (black) changes to substance Y (red)...Ch. 16.4 - Prob. 16.6BFPCh. 16.4 - Prob. 16.7AFPCh. 16.4 - Prob. 16.7BFPCh. 16.4 - Prob. 16.8AFPCh. 16.4 - Prob. 16.8BFPCh. 16.5 - Prob. 16.9AFPCh. 16.5 - Prob. 16.9BFPCh. 16.5 - Prob. 16.10AFPCh. 16.5 - Prob. 16.10BFPCh. 16.6 - Prob. 16.11AFPCh. 16.6 - Prob. 16.11BFPCh. 16.6 - Prob. 16.12AFPCh. 16.6 - Prob. 16.12BFPCh. 16.7 - Prob. 16.1PCh. 16.7 - Aircraft in the stratosphere release NO, which...Ch. 16.7 - Prob. 16.3PCh. 16 - Prob. 16.1PCh. 16 - Prob. 16.2PCh. 16 - A reaction is carried out with water as the...Ch. 16 - Prob. 16.4PCh. 16 - Prob. 16.5PCh. 16 - Prob. 16.6PCh. 16 - Prob. 16.7PCh. 16 - Prob. 16.8PCh. 16 - Prob. 16.9PCh. 16 - Prob. 16.10PCh. 16 - Prob. 16.11PCh. 16 - Prob. 16.12PCh. 16 - Prob. 16.13PCh. 16 - Prob. 16.14PCh. 16 - Prob. 16.15PCh. 16 - Prob. 16.16PCh. 16 - Prob. 16.17PCh. 16 - Prob. 16.18PCh. 16 - Prob. 16.19PCh. 16 - Prob. 16.20PCh. 16 - Prob. 16.21PCh. 16 - Prob. 16.22PCh. 16 - Prob. 16.23PCh. 16 - Prob. 16.24PCh. 16 - Prob. 16.25PCh. 16 - Prob. 16.26PCh. 16 - Prob. 16.27PCh. 16 - Prob. 16.28PCh. 16 - By what factor does the rate in Problem 16.27...Ch. 16 - Prob. 16.30PCh. 16 - Prob. 16.31PCh. 16 - Prob. 16.32PCh. 16 - Prob. 16.33PCh. 16 - Prob. 16.34PCh. 16 - Prob. 16.35PCh. 16 - Prob. 16.36PCh. 16 - Give the overall reaction order that corresponds...Ch. 16 - Phosgene is a toxic gas prepared by the reaction...Ch. 16 - How are integrated rate laws used to determine...Ch. 16 - Define the half-life of a reaction. Explain on the...Ch. 16 - Prob. 16.41PCh. 16 - Prob. 16.42PCh. 16 - The first-order rate constant for the reaction A...Ch. 16 - The molecular scenes below represent the...Ch. 16 - In a first-order decomposition reaction, 50.0% of...Ch. 16 - A decomposition reaction has a rate constant of...Ch. 16 - Prob. 16.47PCh. 16 - Prob. 16.48PCh. 16 - In a study of ammonia production, an industrial...Ch. 16 - Prob. 16.50PCh. 16 - Prob. 16.51PCh. 16 - Prob. 16.52PCh. 16 - Prob. 16.53PCh. 16 - Prob. 16.54PCh. 16 - Prob. 16.55PCh. 16 - Prob. 16.56PCh. 16 - Prob. 16.57PCh. 16 - Assuming the activation energies are equal, which...Ch. 16 - For the reaction A(g) + B(g) ⟶AB(g), how many...Ch. 16 - Prob. 16.60PCh. 16 - Prob. 16.61PCh. 16 - For the reaction A2 + B2 → 2AB, Ea(fwd) = 125...Ch. 16 - Prob. 16.63PCh. 16 - Prob. 16.64PCh. 16 - The rate constant of a reaction is 4.7×10−3 s−1 at...Ch. 16 - The rate constant of a reaction is 4.50×10−5...Ch. 16 - Prob. 16.67PCh. 16 - Prob. 16.68PCh. 16 - Prob. 16.69PCh. 16 - Explain why the coefficients of an elementary step...Ch. 16 - Is it possible for more than one mechanism to be...Ch. 16 - What is the difference between a reaction...Ch. 16 - Why is a bimolecular step more reasonable...Ch. 16 - Prob. 16.74PCh. 16 - If a fast step precedes a slow step in a two-step...Ch. 16 - Prob. 16.76PCh. 16 - Prob. 16.77PCh. 16 - In a study of nitrosyl halides, a chemist proposes...Ch. 16 - Prob. 16.79PCh. 16 - Consider the reaction .
Does the gold catalyst...Ch. 16 - Does a catalyst increase reaction rate by the same...Ch. 16 - In a classroom demonstration, hydrogen gas and...Ch. 16 - Prob. 16.83PCh. 16 - Prob. 16.84PCh. 16 - Prob. 16.85PCh. 16 - Consider the following reaction energy...Ch. 16 - Prob. 16.87PCh. 16 - Prob. 16.88PCh. 16 - A slightly bruised apple will rot extensively in...Ch. 16 - Prob. 16.90PCh. 16 - Prob. 16.91PCh. 16 - Prob. 16.92PCh. 16 - Prob. 16.93PCh. 16 - The citric acid cycle is the central reaction...Ch. 16 - Prob. 16.95PCh. 16 - Prob. 16.96PCh. 16 - Prob. 16.97PCh. 16 - Prob. 16.98PCh. 16 - For the reaction A(g) + B(g) ⟶ AB(g), the rate is...Ch. 16 - The acid-catalyzed hydrolysis of sucrose occurs by...Ch. 16 - At body temperature (37°C), the rate constant of...Ch. 16 - Is each of these statements true? If not, explain...Ch. 16 - Prob. 16.103PCh. 16 - Suggest an experimental method for measuring the...Ch. 16 - Prob. 16.105PCh. 16 - Many drugs decompose in blood by a first-order...Ch. 16 - Prob. 16.107PCh. 16 - Prob. 16.108PCh. 16 - Prob. 16.109PCh. 16 - Prob. 16.110PCh. 16 - Prob. 16.111PCh. 16 - Prob. 16.112PCh. 16 - Prob. 16.113PCh. 16 - Prob. 16.114PCh. 16 - Prob. 16.115PCh. 16 - Prob. 16.116PCh. 16 - Prob. 16.117PCh. 16 - Prob. 16.118PCh. 16 - The growth of Pseudomonas bacteria is modeled as a...Ch. 16 - Prob. 16.120PCh. 16 - Prob. 16.121PCh. 16 - Prob. 16.122PCh. 16 - Prob. 16.123PCh. 16 - Prob. 16.124PCh. 16 - Prob. 16.125PCh. 16 - Human liver enzymes catalyze the degradation of...Ch. 16 - Prob. 16.127PCh. 16 - Prob. 16.128P
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