(a) Interpretation: The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated. Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R − NH 2 . Amines can be classified as primary amine, secondary amine, and tertiary amine. In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group. In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group. In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Question

Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5

Answer 1

Question

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5

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What is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?

Answer 2

Question

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 3

Question

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 4

Question

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 5

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 6

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 7

Chapter 16, Problem 16.4E

Interpretation Introduction

(a)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The classification of the given structure of amine as primary, secondary, or tertiary amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 14

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Answer 15

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Answer 25

Ch. 16 - Prob. 16.1E Ch. 16 - Prob. 16.2E Ch. 16 - Prob. 16.3E Ch. 16 - Prob. 16.4E Ch. 16 - Prob. 16.5E Ch. 16 - Prob. 16.6E Ch. 16 - Prob. 16.7E Ch. 16 - Prob. 16.8E Ch. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....

Solution Summary: The author explains that amines are nitrogen-containing organic compounds. They can be classified as primary, secondary, and tertiary amines.

Chapter 16 Solutions