Chemistry
4th Edition
ISBN: 9780393919370
Author: Thomas R. Gilbert
Publisher: NORTON
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Chapter 16, Problem 16.47QP
Interpretation Introduction
Interpretation: The compounds that acts as a Bronsted-Lowry acid and the Bronsted-Lowry base in an aqueous solution of methylamine,
Concept introduction: An acid is defined as a compound which donates a proton and a proton acceptor is known as base according to Bronsted-Lowry theory.
To determine: The compounds that acts as a Bronsted-Lowry acid and the Bronsted-Lowry base in an aqueous solution of methylamine,
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 16 Solutions
Chemistry
Ch. 16.1 - Prob. 1PECh. 16.2 - Prob. 2PECh. 16.2 - Prob. 3PECh. 16.3 - Prob. 4PECh. 16.3 - Prob. 5PECh. 16.4 - Prob. 6PECh. 16.6 - Prob. 7PECh. 16.6 - Prob. 8PECh. 16.7 - Prob. 9PECh. 16.8 - Prob. 10PE
Ch. 16.8 - Prob. 11PECh. 16.8 - Prob. 12PECh. 16.8 - Prob. 13PECh. 16.10 - Prob. 17PECh. 16.10 - Prob. 18PECh. 16 - Prob. 16.1VPCh. 16 - Prob. 16.2VPCh. 16 - Prob. 16.3VPCh. 16 - Prob. 16.4VPCh. 16 - Prob. 16.5VPCh. 16 - Prob. 16.6VPCh. 16 - Prob. 16.7VPCh. 16 - Prob. 16.8VPCh. 16 - Prob. 16.9VPCh. 16 - Prob. 16.10VPCh. 16 - Prob. 16.11QPCh. 16 - Prob. 16.12QPCh. 16 - Prob. 16.13QPCh. 16 - Prob. 16.14QPCh. 16 - Prob. 16.15QPCh. 16 - Prob. 16.16QPCh. 16 - Prob. 16.17QPCh. 16 - Prob. 16.18QPCh. 16 - Prob. 16.19QPCh. 16 - Prob. 16.20QPCh. 16 - Prob. 16.21QPCh. 16 - Prob. 16.22QPCh. 16 - Prob. 16.23QPCh. 16 - Prob. 16.24QPCh. 16 - Prob. 16.25QPCh. 16 - Prob. 16.26QPCh. 16 - Prob. 16.27QPCh. 16 - Prob. 16.28QPCh. 16 - Prob. 16.29QPCh. 16 - Prob. 16.30QPCh. 16 - Prob. 16.31QPCh. 16 - Prob. 16.32QPCh. 16 - Prob. 16.33QPCh. 16 - Prob. 16.34QPCh. 16 - Prob. 16.35QPCh. 16 - Prob. 16.36QPCh. 16 - Prob. 16.37QPCh. 16 - Prob. 16.38QPCh. 16 - Prob. 16.39QPCh. 16 - Prob. 16.40QPCh. 16 - Prob. 16.42QPCh. 16 - Prob. 16.43QPCh. 16 - Prob. 16.44QPCh. 16 - Prob. 16.45QPCh. 16 - Prob. 16.46QPCh. 16 - Prob. 16.47QPCh. 16 - Prob. 16.48QPCh. 16 - Prob. 16.49QPCh. 16 - Prob. 16.50QPCh. 16 - Prob. 16.51QPCh. 16 - Prob. 16.52QPCh. 16 - Prob. 16.53QPCh. 16 - Prob. 16.54QPCh. 16 - Prob. 16.55QPCh. 16 - Prob. 16.56QPCh. 16 - Prob. 16.57QPCh. 16 - Prob. 16.58QPCh. 16 - Prob. 16.59QPCh. 16 - Prob. 16.60QPCh. 16 - Prob. 16.61QPCh. 16 - Prob. 16.62QPCh. 16 - Prob. 16.63QPCh. 16 - Prob. 16.64QPCh. 16 - Prob. 16.65QPCh. 16 - Prob. 16.66QPCh. 16 - Prob. 16.67QPCh. 16 - Prob. 16.68QPCh. 16 - Prob. 16.69QPCh. 16 - Prob. 16.70QPCh. 16 - Prob. 16.71QPCh. 16 - Prob. 16.72QPCh. 16 - Prob. 16.73QPCh. 16 - Prob. 16.74QPCh. 16 - Prob. 16.75QPCh. 16 - Prob. 16.76QPCh. 16 - Prob. 16.77QPCh. 16 - Prob. 16.78QPCh. 16 - Prob. 16.79QPCh. 16 - Prob. 16.80QPCh. 16 - Prob. 16.81QPCh. 16 - Prob. 16.82QPCh. 16 - Prob. 16.83QPCh. 16 - Prob. 16.84QPCh. 16 - Prob. 16.85QPCh. 16 - Prob. 16.86QPCh. 16 - Prob. 16.87QPCh. 16 - Prob. 16.88QPCh. 16 - Prob. 16.89QPCh. 16 - Prob. 16.90QPCh. 16 - Prob. 16.91QPCh. 16 - Prob. 16.92QPCh. 16 - Prob. 16.93QPCh. 16 - Prob. 16.94QPCh. 16 - Prob. 16.95QPCh. 16 - Prob. 16.96QPCh. 16 - Prob. 16.97QPCh. 16 - Prob. 16.98QPCh. 16 - Prob. 16.99QPCh. 16 - Prob. 16.100QPCh. 16 - Prob. 16.101QPCh. 16 - Prob. 16.102QPCh. 16 - Prob. 16.103QPCh. 16 - Prob. 16.104QPCh. 16 - Prob. 16.105QPCh. 16 - Prob. 16.106QPCh. 16 - Prob. 16.107QPCh. 16 - Prob. 16.108QPCh. 16 - Prob. 16.109QPCh. 16 - Prob. 16.110QPCh. 16 - Prob. 16.111QPCh. 16 - Prob. 16.112QPCh. 16 - Prob. 16.113QPCh. 16 - Prob. 16.114QPCh. 16 - Prob. 16.115QPCh. 16 - Prob. 16.116QPCh. 16 - Prob. 16.117QPCh. 16 - Prob. 16.118QPCh. 16 - Prob. 16.119QPCh. 16 - Prob. 16.120QPCh. 16 - Prob. 16.121QPCh. 16 - Prob. 16.122QPCh. 16 - Prob. 16.123QPCh. 16 - Prob. 16.124QPCh. 16 - Prob. 16.125QPCh. 16 - Prob. 16.126QPCh. 16 - Prob. 16.127QPCh. 16 - Prob. 16.128QPCh. 16 - Prob. 16.129QPCh. 16 - Prob. 16.130QPCh. 16 - Prob. 16.131QPCh. 16 - Prob. 16.132QPCh. 16 - Prob. 16.133QPCh. 16 - Prob. 16.134QPCh. 16 - Prob. 16.135QPCh. 16 - Prob. 16.136QPCh. 16 - Prob. 16.137QPCh. 16 - Prob. 16.138QPCh. 16 - Prob. 16.139QPCh. 16 - Prob. 16.140QPCh. 16 - Prob. 16.141QPCh. 16 - Prob. 16.142QPCh. 16 - Prob. 16.143QPCh. 16 - Prob. 16.144QPCh. 16 - Prob. 16.145QPCh. 16 - Prob. 16.146QPCh. 16 - Prob. 16.147QPCh. 16 - Prob. 16.148QPCh. 16 - Prob. 16.149QPCh. 16 - Prob. 16.150QPCh. 16 - Prob. 16.151APCh. 16 - Prob. 16.152APCh. 16 - Prob. 16.153APCh. 16 - Prob. 16.154APCh. 16 - Prob. 16.155APCh. 16 - Prob. 16.156APCh. 16 - Prob. 16.157APCh. 16 - Prob. 16.158APCh. 16 - Prob. 16.159APCh. 16 - Prob. 16.160APCh. 16 - Prob. 16.161APCh. 16 - Prob. 16.162APCh. 16 - Prob. 16.163APCh. 16 - Prob. 16.164APCh. 16 - Prob. 16.165APCh. 16 - Prob. 16.166APCh. 16 - Prob. 16.167APCh. 16 - Prob. 16.168APCh. 16 - Prob. 16.169APCh. 16 - Prob. 16.170APCh. 16 - Prob. 16.171APCh. 16 - Prob. 16.173APCh. 16 - Prob. 16.174AP
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