Chapter 16, Problem 16.39QP

(a)

Interpretation Introduction

Interpretation:

The $\text{pH}$ and $\text{pOH}$ of the given aqueous solution at ${25}^{\circ }\text{C}$ has to be calculated

Concept Information:

In strong acids, the ionization of acid is complete.  This implies that the concentration of the hydrogen ion or hydronium ion will be equal to the initial concentration of the acid at equilibrium.

Strong bases: Strong bases are formed from alkali metals and alkaline earth metals of Group IA and IIA respectively.

Strong base dissociates into its constituent ions.

$\text{pOH}$: The $\text{pOH}$ of a solution is defined as the negative base-10 logarithm of the hydroxide ion ${\text{[OH}}^{\text{-}}\text{]}$ concentration. $\text{pOH}$ scale is analogous to pH scale.

$\text{pOH}\text{=}{\text{-log[OH}}^{\text{-}}\text{]}$

Relationship between $\text{pH}$ and $\text{pOH}$:

$\text{pOH}$ is similar to $\text{pH}$.  The only difference is that in $\text{pOH}$ the concentration of hydroxide ion is used as a scale while in $\text{pH}$, the concentration of hydronium ion is used.

The relationship between the hydronium ion concentration and the hydroxide ion concentration is given by the equation,

$\text{pH}\text{+}\text{pOH}\text{=}\text{14,}\text{at}\text{25}{}^{\text{o}}\text{C}$

As $\text{pOH}$ and $\text{pH}$ are opposite scale, the total of both has to be equal to 14.

(b)

Interpretation Introduction

Interpretation:

The $\text{pH}$ and $\text{pOH}$ of the given aqueous solution at ${25}^{\circ }\text{C}$ has to be calculated

Concept Information:

In strong acids, the ionization of acid is complete.  This implies that the concentration of the hydrogen ion or hydronium ion will be equal to the initial concentration of the acid at equilibrium.

Strong bases: Strong bases are formed from alkali metals and alkaline earth metals of Group IA and IIA respectively.

Strong base dissociates into its constituent ions.

$\text{pOH}$: The $\text{pOH}$ of a solution is defined as the negative base-10 logarithm of the hydroxide ion ${\text{[OH}}^{\text{-}}\text{]}$ concentration. $\text{pOH}$ scale is analogous to pH scale.

$\text{pOH}\text{=}{\text{-log[OH}}^{\text{-}}\text{]}$

Relationship between $\text{pH}$ and $\text{pOH}$:

$\text{pOH}$ is similar to $\text{pH}$.  The only difference is that in $\text{pOH}$ the concentration of hydroxide ion is used as a scale while in $\text{pH}$, the concentration of hydronium ion is used.

The relationship between the hydronium ion concentration and the hydroxide ion concentration is given by the equation,

$\text{pH}\text{+}\text{pOH}\text{=}\text{14,}\text{at}\text{25}{}^{\text{o}}\text{C}$

As $\text{pOH}$ and $\text{pH}$ are opposite scale, the total of both has to be equal to 14.

(c)

Interpretation Introduction

Interpretation:

The $\text{pH}$ and $\text{pOH}$ of the given aqueous solution at ${25}^{\circ }\text{C}$ has to be calculated

Concept Information:

In strong acids, the ionization of acid is complete.  This implies that the concentration of the hydrogen ion or hydronium ion will be equal to the initial concentration of the acid at equilibrium.

Strong bases: Strong bases are formed from alkali metals and alkaline earth metals of Group IA and IIA respectively.

Strong base dissociates into its constituent ions.

$\text{pOH}$: The $\text{pOH}$ of a solution is defined as the negative base-10 logarithm of the hydroxide ion ${\text{[OH}}^{\text{-}}\text{]}$ concentration. $\text{pOH}$ scale is analogous to pH scale.

$\text{pOH}\text{=}{\text{-log[OH}}^{\text{-}}\text{]}$

Relationship between $\text{pH}$ and $\text{pOH}$:

$\text{pOH}$ is similar to $\text{pH}$.  The only difference is that in $\text{pOH}$ the concentration of hydroxide ion is used as a scale while in $\text{pH}$, the concentration of hydronium ion is used.

The relationship between the hydronium ion concentration and the hydroxide ion concentration is given by the equation,

$\text{pH}\text{+}\text{pOH}\text{=}\text{14,}\text{at}\text{25}{}^{\text{o}}\text{C}$

As $\text{pOH}$ and $\text{pH}$ are opposite scale, the total of both has to be equal to 14.