Student Solutions Manual for Ball's Physical Chemistry, 2nd
Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 16, Problem 16.12E
Interpretation Introduction

Interpretation:

The Lande g factor for a D54 state of the Fe atom using both equations 16.12 and 16.13 is to be calculated.

Concept Introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μBMLB

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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