(a) Interpretation: The individual transitions that are allowed for D 1 → P 1 transition are to be stated. Concept introduction: The change in energy ( Δ E ) of the state depends on the strength of the magnetic field ( B ) and the z-component quantum number ( M L ) in the presence of magnetic field. The expression for the change in energy ( Δ E ) is written below. Δ E = μ B ⋅ M L ⋅ B The value of ( M L ) can be positive, negative or zero. Hence, the change in energy ( Δ E ) can be positive, negative or zero. The change in energy ( Δ E ) of the state is equal to the amount of splitting.

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Answer 1

Question

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Answer 2

Question

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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Answer 3

Question

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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Answer 4

Question

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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Answer 5

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Answer 6

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Answer 7

Chapter 16, Problem 16.11E

Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1→P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μB⋅ML⋅B

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1E Ch. 16 - Prob. 16.2E Ch. 16 - Prob. 16.3E Ch. 16 - Prob. 16.4E Ch. 16 - Prob. 16.5E Ch. 16 - Prob. 16.6E Ch. 16 - Prob. 16.7E Ch. 16 - Prob. 16.8E Ch. 16 - Prob. 16.9E Ch. 16 - Prob. 16.10E

Solution Summary: The author explains that the change in energy of (Delta E) depends on the strength of the magnetic field and the z-component quantum number.

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Chapter 16 Solutions