Draw the structure consistent with each description. a. ( 2 E , 4 E ) − octa − 2 , 4 − diene in the s − trans conformation b. ( 3 E , 5 Z ) − nona − 3 , 5 − diene in the s − trans conformation c. ( 3 Z , 5 Z ) − 4 , 5 − dimethyldeca − 3 , 5 − diene . Draw both the s -cis and s -trans conformations.

Question

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Answer 1

Textbook Question

Chapter 16, Problem 16.10P

Draw the structure consistent with each description.

a. ( 2 E , 4 E ) − octa − 2 , 4 − diene in the s − trans conformation

b. ( 3 E , 5 Z ) − nona − 3 , 5 − diene in the s − trans conformation

c. ( 3 Z , 5 Z ) − 4 , 5 − dimethyldeca − 3 , 5 − diene . Draw both the s-cis and s-trans conformations.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

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Students have asked these similar questions

Draw the structure of each compound.a. (Z)-penta-1,3-diene in the s-trans conformationb. (2E,4Z)-1-bromo-3-methylhexa-2,4-dienec. (2E,4E,6E)-octa-2,4,6-triened. (2E,4E)-3-methylhexa-2,4-diene in the s-cis conformation

b

draw all the molecule separately in chemdraw like in step 1 draw one compound , in step 2 draw another , for the last compound draw structure and arrow and written part below and above it

Answer 2

Textbook Question

Chapter 16, Problem 16.10P

Draw the structure consistent with each description.

a. ( 2 E , 4 E ) − octa − 2 , 4 − diene in the s − trans conformation

b. ( 3 E , 5 Z ) − nona − 3 , 5 − diene in the s − trans conformation

c. ( 3 Z , 5 Z ) − 4 , 5 − dimethyldeca − 3 , 5 − diene . Draw both the s-cis and s-trans conformations.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Textbook Question

Chapter 16, Problem 16.10P

Draw the structure consistent with each description.

a. ( 2 E , 4 E ) − octa − 2 , 4 − diene in the s − trans conformation

b. ( 3 E , 5 Z ) − nona − 3 , 5 − diene in the s − trans conformation

c. ( 3 Z , 5 Z ) − 4 , 5 − dimethyldeca − 3 , 5 − diene . Draw both the s-cis and s-trans conformations.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

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Answer 4

Textbook Question

Chapter 16, Problem 16.10P

Draw the structure consistent with each description.

a. ( 2 E , 4 E ) − octa − 2 , 4 − diene in the s − trans conformation

b. ( 3 E , 5 Z ) − nona − 3 , 5 − diene in the s − trans conformation

c. ( 3 Z , 5 Z ) − 4 , 5 − dimethyldeca − 3 , 5 − diene . Draw both the s-cis and s-trans conformations.

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

Answer 8

Expert Solution

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 13

Answer to Problem 16.10P

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 1

Answer 14

Explanation of Solution

The given name is (2E,4E)−octa−2,4−diene. The word root used in this is oct. It means structure contains eight carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is E. Thus, it means that the two double bonds are present on the opposite side.

Thus, the correct structure of (2E,4E)−octa−2,4−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 2

Figure 1

Answer 15

Conclusion

The structure corresponding to (2E,4E)−octa−2,4−diene in the s−trans conformation is shown in Figure 1.

Answer 16

Expert Solution

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Interpretation Introduction

(b)

Interpretation: The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−cis conformation is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E or trans isomer, whereas when two higher priority groups are present on the same side then it is Z or cis isomer.

Answer 21

Answer to Problem 16.10P

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown as:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 3

Answer 22

Explanation of Solution

The given name is (3E,5Z)−nona−3,5−diene. The word root used in this is non. It means structure contains nine carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used are E and Z. Thus, it means that the stereochemistry at one double bond is trans and at other is cis.

Thus, the correct structure of (3E,5Z)−nona−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 4

Figure 2

Answer 23

Conclusion

The structure corresponding to (3E,5Z)−nona−3,5−diene in the s−trans conformation is shown in Figure 2.

Answer 24

Expert Solution

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.

Thus, the correct structure to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown below.

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 6

Figure 3

Conclusion

The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is shown in Figure 3.

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Interpretation Introduction

(c)

Interpretation: The structure corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 29

Answer to Problem 16.10P

The structures corresponding to s−trans and s−cis conformation of (3Z,5Z)−4,5−dimethyldeca−3,5−diene are:

PKG ORGANIC CHEMISTRY, Chapter 16, Problem 16.10P , additional homework tip 5

Answer 30

Explanation of Solution

The given name is (3Z,5Z)−4,5−dimethyldeca−3,5−diene. The word root used in this is dec. It means structure contains ten carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. The prefix used is Z. Thus, it means that the two double bonds are present on the same side.