ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1.6, Problem 13P
Interpretation Introduction
Interpretation:
The structural formulas of the constitutionally isomeric compounds having given molecular formula are to be written.
Concept introduction:
Constitutional isomers having the same molecular formula differ in the order in which their atoms are connected.
In each structure, the carbon atom must have four bonds.
Each nitrogen atom must have three bonds.
Each oxygen atom must have two bonds.
Halogen atoms must have one bond each.
Unshared electron pairs on nitrogen, oxygen, and halogen atoms must be included in the structure.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Problem 1.17
(a) Draw a second resonance structure for A. (b) Why can't a second resonance structure
be drawn for B?
CH₂
C=C
CH₂
A
NH₂
H
CH₂
HI
N-H
c=c
CH₂ H
B
Problem 1.41
Write the condensed structure of a compound that contains only carbon and hydrogen atoms and that has
Part A
two sp³ hybridized carbons.
Express your answer as a condensed structural formula.
α
Submit
ΑΣΦ
В
Part B
Y
V
CH₂CH₂ H
A chemical reaction does not occur for this question.
X
Previous Answers Request Answer
X Incorrect; Try Again; 4 attempts remaining
ΑΣΦ
?
one sp³ hybridized carbon and two sp² hybridized carbons.
Express your answer as a condensed structural formula.
Submit Request Answer
?
A chemical reaction does not occur for this question.
PROBLEM 1.11
Use curved arrows to show the redistribution of valence electrons in converting resonance contributing
structure (a) to (b) and then (b) to (c). Also show, using curved arrows, how (a) can be converted to (c)
without going through (b).
Ö:
•~-~-
CH₂-C
→ CH3-C+
(a)
(b)
80%
O
CH₂-C
(c)
Ö
Chapter 1 Solutions
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
Ch. 1.1 - How many electrons does carbon have? How many are...Ch. 1.1 - Referring to the periodic table as needed, write...Ch. 1.2 - Species that have the same number of electrons are...Ch. 1.2 - Which of the following ions possess a noble gas...Ch. 1.2 - Prob. 5PCh. 1.3 - Prob. 6PCh. 1.3 - Problem 1.7 All of the hydrogens are bonded to...Ch. 1.4 - Problem 1.8 In which of the compounds...Ch. 1.4 - Indicate the direction of the dipole for the...Ch. 1.5 - Prob. 10P
Ch. 1.5 - The following inorganic species will be...Ch. 1.5 - Prob. 12PCh. 1.6 - Prob. 13PCh. 1.6 - Problem 1.14 Nitrosomethane and formaldoxime both...Ch. 1.6 - Prob. 15PCh. 1.7 - All of the bonds in the carbonate ion (CO32-) are...Ch. 1.7 - Prob. 17PCh. 1.8 - Prob. 18PCh. 1.8 - Prob. 19PCh. 1.9 - Sodium borohydride, NaBH4, has an ionic bond...Ch. 1.9 - Prob. 21PCh. 1.10 - Which of the following compounds would you expect...Ch. 1.11 - Using the curved arrow to guide your reasoning,...Ch. 1.11 - Prob. 24PCh. 1.11 - Prob. 25PCh. 1.12 - Prob. 26PCh. 1.12 - Prob. 27PCh. 1.12 - Prob. 28PCh. 1.12 - Prob. 29PCh. 1.12 - Prob. 30PCh. 1.13 - Which is the stronger acid, H2O or H2S? Which is...Ch. 1.13 - Prob. 32PCh. 1.13 - Prob. 33PCh. 1.13 - Hypochlorous and hypobromous acid (HOClandHOBr)...Ch. 1.13 - Prob. 35PCh. 1.13 - Prob. 36PCh. 1.14 - What is the equilibrium constant for the following...Ch. 1.14 - Prob. 38PCh. 1.14 - Prob. 39PCh. 1.15 - Write an equation for the Lewis acid/Lewis base...Ch. 1 - Write a Lewis formula for each of the following...Ch. 1 - Prob. 42PCh. 1 - Write structural formulas for all the...Ch. 1 - Prob. 44PCh. 1 - Expand the following structural representations so...Ch. 1 - Each of the following species will be encountered...Ch. 1 - Consider Lewis formulas A, B, and C: H2 C -NN:...Ch. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - Prob. 50PCh. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Which compound in each of the following pairs...Ch. 1 - With a pKa of 11.6, hydrogen peroxide is a...Ch. 1 - The structure of montelukast, an antiasthma drug,...Ch. 1 - One acid has a pKa of 2, the other has a pKa of 8....Ch. 1 - Calculate Ka for each of the following acids,...Ch. 1 - Rank the following in order of decreasing acidity....Ch. 1 - Rank the following in order of decreasing...Ch. 1 - Consider 1.0 M aqueous solutions of each of the...Ch. 1 - Prob. 63PCh. 1 - Prob. 64PCh. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - Amide Lewis Structural Formulas Lewis formulas are...Ch. 1 - Amide Lewis Structural Formulas Lewis formulas are...Ch. 1 - Amide Lewis Structural Formulas Lewis formulas are...Ch. 1 - Prob. 72DSPCh. 1 - Amide Lewis Structural Formulas Lewis formulas are...Ch. 1 - Amide Lewis Structural Formulas Lewis formulas are...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which of the the following elements are isotones? a) 12C, 13C, and 14C (c) 14C, 15N, and 160 (b) 40Ar, 40K, and 4°Ca c) O a) b) O No answer text provided.arrow_forwardProblem 1.11 Classify each pair of compounds as isomers or resonance structures. a N=C=O: and b. H :0: 11 0: and *C=N-O :0 H-O =0:arrow_forwardQUESTION 1 CH3 There are four cis-trans isomers of menthol including the one shown HO CH(CH), Which of the following structures are isomers of menthol. Choose all of them. CH3 HO CHCH3)2 CH3 HO ČH(CH 3)2 CH3 HO ČHỊCH 2arrow_forward
- QUESTION 3 Which of these structures represent the same compound? CH3 CH3CHCH₂CH₂CH3 CH3CH₂CH₂CHC H3 CH,CH,CHCH,CHy (A) (B) O A and B are the same compound. A and C are the same compound. B and C are the same compound All three structures represent the same compound. CH3 The three structures represent three different compounds. (C) CH3arrow_forwardProblem 1.10 Use resonance structures to identify the areas of high and low electron density in the following compounds: (a) (c) (e) CH₂=CH-NO2 :0: || H-C- -NH₂ HOOd#D) (d) :O: || H-C- -CH=CH–NH2 (b) CH₂=CH-CN: (d) H- :O: -OCH3 (f) CH3O-CH=CH-C=N:arrow_forward1.57 Which compound in each of the following pairs would you expect to have the greater dipole moment u? Why? (a) HF or HCI (b) HF or BF3 (c) (CH3)3CH or (CH3)3CCI (d) CHCl3 or CCI F (e) CH3NH₂ or CH₂OH (f) CH3NH₂ or CH₂NO₂arrow_forward
- QUESTION 2 Which molecular formula is correct for a saturated compound (containing no double or triple bond/s)? (a) (b) (c) C4H8F2 CAH8S C5H9 C6H6 C4H40 (e) A (e) B. (b) C (d) D.(a) E. (c)arrow_forwardWhat is the name of the compound shown below? (A) (B) (e) CRT n-octane n-pentane n-propane n-hexane u hontana H₂ H H Harrow_forward2.44 For each of the following compounds, draw a constitutional isomer with the same functional groups: (a) CH3 (b) OCH3 (c) CH3CH2CH2C=N CH3CHCH2CH2B (d) (e) CH3CH2CHO (f) CH2CO2H ноarrow_forward
- Expand the following structural representations so as to more clearly show all the atoms and any unshared electron pairs. 1.60 (g) (a) Naphthalene: sometimes used as a moth repellent A component of high-octane gasoline OCCH3 (b) (h) СОН Occurs in bay and verbena oil Aspirin (c) (i) CH3 Pleasant-smelling substance found in marjoram oil Nicotine: a toxic substance present in tobaccoarrow_forwardNAMING SULFIDES PROBLEM 3: 1. Name the following compounds using common name and IUPAC name. (a) 앤a CH;CHSCH;CH3 (b) SCH3 2. Draw the condensed structural formula of the following: (a) Dimethyl sulfide (b) 2-Methylthiolbutanearrow_forwardPlease don't provide handwriting solutionarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY