To calculate the values of the degree of dissociation for formic acid and plot degree of dissociation against concentration. Also plot logarithm of concentration versus degree of dissociation. Concept introduction: Degree of dissociation for formic acid is calculated from the relation of the degree of dissociation and concentration given below: K= ( C ο ) ( α 2 ) ( 1-α ) A graph of degree of dissociation versus concentration of acid is plotted. The logarithm of concentration versus degree of dissociation graph is plotted.
To calculate the values of the degree of dissociation for formic acid and plot degree of dissociation against concentration. Also plot logarithm of concentration versus degree of dissociation. Concept introduction: Degree of dissociation for formic acid is calculated from the relation of the degree of dissociation and concentration given below: K= ( C ο ) ( α 2 ) ( 1-α ) A graph of degree of dissociation versus concentration of acid is plotted. The logarithm of concentration versus degree of dissociation graph is plotted.
Solution Summary: The author explains that the degree of dissociation for formic acid is calculated from the relation of degree and concentration.
Interpretation: To calculate the values of the degree of dissociation for formic acid and plot degree of dissociation against concentration. Also plot logarithm of concentration versus degree of dissociation.
Concept introduction: Degree of dissociation for formic acid is calculated from the relation of the degree of dissociation and concentration given below:
K=(Cο)(α2)(1-α)
A graph of degree of dissociation versus concentration of acid is plotted.
The logarithm of concentration versus degree of dissociation graph is plotted.
(b)
Interpretation Introduction
Interpretation:
Relationship of the degree of dissociation and initial concentration of an acid or a base has to be determined.
Concept introduction: Degree of dissociation for formic acid is calculated from the relation of the degree of dissociation and concentration given below:
K=(Cο)(α2)(1-α)
A graph of degree of dissociation versus concentration of acid is plotted.
The logarithm of concentration versus degree of dissociation graph is plotted.
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell