The electron dot structure of ( I 3 − ) has to be drawn. Concept Introduction: Valence electrons are represented by dots placed around the chemical symbol. The valance electrons are placed around the elements (atoms) maximum electrons can fill around the atom. First fill the single electron around the atom and paired the electrons. The valance electron for iodine atom is seven. Total valence electrons in triiodide anion are counted and electron dot structure for the anion is written. When iodine ( I 2 ) is mixed in an aqueous solution of potassium iodide ( KI ) , an acid-base reaction occurs. Iodide anion ( I − ) from potassium iodide acts as a Lewis base and iodine ( I 2 ) acts as a Lewis acid.
The electron dot structure of ( I 3 − ) has to be drawn. Concept Introduction: Valence electrons are represented by dots placed around the chemical symbol. The valance electrons are placed around the elements (atoms) maximum electrons can fill around the atom. First fill the single electron around the atom and paired the electrons. The valance electron for iodine atom is seven. Total valence electrons in triiodide anion are counted and electron dot structure for the anion is written. When iodine ( I 2 ) is mixed in an aqueous solution of potassium iodide ( KI ) , an acid-base reaction occurs. Iodide anion ( I − ) from potassium iodide acts as a Lewis base and iodine ( I 2 ) acts as a Lewis acid.
Solution Summary: The author explains how the electron dot structure of (I_3-) is drawn.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 16, Problem 123SCQ
(a)
Interpretation Introduction
Interpretation:
The electron dot structure of (I3−) has to be drawn.
Concept Introduction:
Valence electrons are represented by dots placed around the chemical symbol. The valance electrons are placed around the elements (atoms) maximum electrons can fill around the atom. First fill the single electron around the atom and paired the electrons.
The valance electron for iodine atom is seven. Total valence electrons in triiodide anion are counted and electron dot structure for the anion is written. When iodine (I2) is mixed in an aqueous solution of potassium iodide (KI), an acid-base reaction occurs. Iodide anion (I−) from potassium iodide acts as a Lewis base and iodine (I2) acts as a Lewis acid.
(b)
Interpretation Introduction
Interpretation:
The chemical reaction has to be written by indicating the Lewis acid and Lewis base.
Concept Introduction:
Lewis definition:
A Lewis acid is a substance that can accept and share an electron pair.
A Lewis base is a substance that can donate and share an electron pair.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
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