From the given options it should be determined that what will happen when volume of the system increased in the given reaction. Concept introduction: Chemical equilibrium is the state at which there is no further change in concentration of reactants and products. The rate of forward and backward reaction is equal at equilibrium. Le Chatelier’s principle states that the change in any factor such as temperature, pressure, concentration will cause the equilibrium to shift in such a direction so as to reduce the effect of the change.

Question

5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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Question

Chapter 15.6, Problem 2RC

Interpretation Introduction

Interpretation:

From the given options it should be determined that what will happen when volume of the system increased in the given reaction.

Concept introduction:

Chemical equilibrium is the state at which there is no further change in concentration of reactants and products. The rate of forward and backward reaction is equal at equilibrium.

Le Chatelier’s principle states that the change in any factor such as temperature, pressure, concentration will cause the equilibrium to shift in such a direction so as to reduce the effect of the change.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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