Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 15.5, Problem 13P

(a)

Interpretation Introduction

Interpretation:

The three segment of 1,4-polymerized product of 1,3-butadiene has to be drawn.

Concept introduction:

Polymers:

Monomers combine together to form polymers.  Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.

Two types of polymers:

  • Synthetic and biopolymers.
  • DNA is an example for biopolymer and these type of polymers are synthesized by cells.
  • Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.

Two types of synthetic polymers:

  • Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
  • Chain growth polymers are formed by the monomer addition to the end of a growing chain.
  • Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.

(b)

Interpretation Introduction

Interpretation:

The three segment of 1,2-polymerized product of 1,3-butadiene has to be drawn.

Concept introduction:

Polymers:

Monomers combine together to form polymers.  Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.

Two types of polymers:

  • Synthetic and biopolymers.
  • DNA is an example for biopolymer and these type of polymers are synthesized by cells.
  • Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.

Two types of synthetic polymers:

  • Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
  • Chain growth polymers are formed by the monomer addition to the end of a growing chain.
  • Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.

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14.44 Ignoring stereoisomers, draw all products that form by addition of HBr to (E)-hexa-1,3,5-triene.
Include stereochemistry Leven though the solutions manual does 14.43 Draw the products formed when each compound is treated with one not) equivalent of HBr. a. b. C.
14.41 Label each pair of compounds as stereoisomers, conformations, or constitutional isomers: (a) A and B; (b) A and C; (c) A and D; (d) C and D. A B C D
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