The polymerization of 2,2-dimethyloxirane should be derived by anionic mechanism. Concept Introduction: Anionic polymerization: Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium. Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 15.2, Problem 11P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be derived by anionic mechanism.

Concept Introduction:

Anionic polymerization: Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization: The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 2

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 15.2, Problem 11P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be derived by anionic mechanism.

Concept Introduction:

Anionic polymerization: Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization: The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 15.2, Problem 11P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be derived by anionic mechanism.

Concept Introduction:

Anionic polymerization: Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization: The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 15.2, Problem 11P

(a)

Interpretation Introduction