Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 15.5, Problem 12P
Draw a short segment of gutta-percha.
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The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
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Scheme 5
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Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
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[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
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P.
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(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
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(v)
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Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
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(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 15 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 15.2 - Prob. 1PCh. 15.2 - Prob. 2PCh. 15.2 - Prob. 3PCh. 15.2 - Prob. 4PCh. 15.2 - List the following groups of monomers in order...Ch. 15.2 - List the following groups of monomers in order...Ch. 15.2 - Prob. 7PCh. 15.2 - Why does methyl methacrylate not undergo cationic...Ch. 15.2 - Which monomer and which type of initiator would...Ch. 15.2 - Prob. 10P
Ch. 15.2 - Prob. 11PCh. 15.5 - Draw a short segment of gutta-percha.Ch. 15.5 - Prob. 13PCh. 15.6 - Prob. 14PCh. 15.8 - Prob. 15PCh. 15.8 - Prob. 16PCh. 15.8 - Prob. 17PCh. 15.8 - a. Propose a mechanism for the formation of the...Ch. 15.8 - Propose a mechanism for the formation of Melmac.Ch. 15.8 - Explain why, when a small amount of glycerol is...Ch. 15.10 - Prob. 21PCh. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 23PCh. 15 - Draw the structure of the monomer or monomers used...Ch. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - Prob. 28PCh. 15 - A particularly strong and rigid polyester used for...Ch. 15 - Prob. 30PCh. 15 - Prob. 31PCh. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Delrin (polyoxymethylene) is a tough...
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