
EP BASIC CHEMISTRY-STANDALONE ACCESS
6th Edition
ISBN: 9780134999890
Author: Timberlake
Publisher: PEARSON CO
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Chapter 15.1, Problem 16PP
(a)
Interpretation Introduction
Interpretation: Indicate whether each of the following describes the oxidizing agent or the reducing agent in an
The substance that is reduced
Concept Introduction: Oxidation is the loss of electrons and reduction is the gain of electrons.
(b)
Interpretation Introduction
Interpretation: Indicate whether each of the following describes the oxidizing agent or the reducing agent in an oxidation-reduction reaction:
The substance that losses electrons
Concept Introduction: Oxidation is the loss of electrons and reduction is the gain of electrons.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 15 Solutions
EP BASIC CHEMISTRY-STANDALONE ACCESS
Ch. 15.1 - Identify each of the following as an oxidation or...Ch. 15.1 - Identify each of the following as an oxidation or...Ch. 15.1 - Prob. 3PPCh. 15.1 - Prob. 4PPCh. 15.1 - Prob. 5PPCh. 15.1 - Prob. 6PPCh. 15.1 - Prob. 7PPCh. 15.1 - Prob. 8PPCh. 15.1 - Prob. 9PPCh. 15.1 - Prob. 10PP
Ch. 15.1 - Prob. 11PPCh. 15.1 - Prob. 12PPCh. 15.1 - What is the oxidation number of the specified...Ch. 15.1 - What is the oxidation number of the specified...Ch. 15.1 - Prob. 15PPCh. 15.1 - Prob. 16PPCh. 15.1 - Prob. 17PPCh. 15.1 - Prob. 18PPCh. 15.1 - Prob. 19PPCh. 15.1 - Prob. 20PPCh. 15.2 - Balance each of the following half-reactions in...Ch. 15.2 - Prob. 22PPCh. 15.2 - Prob. 23PPCh. 15.2 - Use the half-reaction method to balance each of...Ch. 15.2 - Use the half-reaction method to balance each of...Ch. 15.2 - Use the half-reaction method to balance each of...Ch. 15.3 - Use the activity series in Table 15.3 to predict...Ch. 15.3 - Use the activity series in Table 15.3 to predict...Ch. 15.3 - Prob. 29PPCh. 15.3 - Prob. 30PPCh. 15.3 - Prob. 31PPCh. 15.3 - Prob. 32PPCh. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - Prob. 36PPCh. 15.4 - What we call "tin cans" are really iron cans...Ch. 15.4 - Prob. 38PPCh. 15.4 - Prob. 39PPCh. 15.4 - Prob. 40PPCh. 15.4 - Prob. 41PPCh. 15.4 - Prob. 42PPCh. 15 - Prob. 43UTCCh. 15 - Prob. 44UTCCh. 15 - Prob. 45UTCCh. 15 - Prob. 46UTCCh. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - Prob. 50UTCCh. 15 - Prob. 51UTCCh. 15 - Prob. 52UTCCh. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - Which of the following are oxidation-reduction...Ch. 15 - Which of the following are oxidation-reduction...Ch. 15 - In the mitochondria of human cells, energy is...Ch. 15 - Prob. 58APPCh. 15 - Prob. 59APPCh. 15 - Prob. 60APPCh. 15 - Prob. 61APPCh. 15 - Prob. 62APPCh. 15 - Prob. 63APPCh. 15 - Write the balanced half-reactions and a balanced...Ch. 15 - Prob. 65APPCh. 15 - Use the activity series in Table 15.3 to predict...Ch. 15 - Prob. 67APPCh. 15 - Prob. 68APPCh. 15 - Prob. 69APPCh. 15 - Prob. 70APPCh. 15 - Prob. 71APPCh. 15 - In an acidic dry-cell battery, the following...Ch. 15 - Steel bolts made for sailboats are coated with...Ch. 15 - Copper cooking pans are stainless steel pans...Ch. 15 - Prob. 75CPCh. 15 - Prob. 76CPCh. 15 - Prob. 77CPCh. 15 - The following problems are related to the topics...Ch. 15 - The following problems are related to the topics...Ch. 15 - The following problems are related to the topics...Ch. 15 - Prob. 81CPCh. 15 - Prob. 82CPCh. 15 - Prob. 83CPCh. 15 - Prob. 84CPCh. 15 - Prob. 85CPCh. 15 - Prob. 86CPCh. 15 - Prob. 87CPCh. 15 - Prob. 88CP
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