Consider the reaction:
A reaction mixture at equilibrium at 175 K contains
Want to see the full answer?
Check out a sample textbook solutionChapter 15 Solutions
Chemistry: Structure and Properties (2nd Edition)
- Distinguish between the terms equilibrium constant and reaction quotient. When Q = K, what does this say about a reaction? When Q K, what does this say about a reaction? When Q K. what does this say about a reaction?arrow_forwardSulfur oxychloride, SO2Cl2, decomposes to sulfur dioxide and chlorine gases. SO2Cl2(g)SO2(g)+Cl2(g) At a certain temperature, the equilibrium partial pressures of SO2, Cl2, and SO2Cl2 are 1.88 atm, 0.84 atm, and 0.27 atm, respectively. (a) What is K at that temperature? (b) Enough Cl2 condenses to reduce its partial pressure to 0.68 atm. What are the partial pressures of all gases when equilibrium is reestablished?arrow_forwardGaseous acetic acid molecules have a certain tendency to form dimers. (A dimer is a molecules formed by the association of two identical, simpler molecules.) The equilibrium constant Kp at 25C for this reaction is 1.3 103. a If the initial pressure of CH3COOH monomer (the simpler molecule) is 7.5 103 atm, what are the pressures of monomer and dimer when the system comes to equilibrium? (The simpler quadratic equation is obtained by assuming that all of the acid molecules have dimerized and then some of it dissociates to monomer.) b Why do acetic acid molecules dimerize? What type of structure would you draw for the dimer? c As the temperature decreases, would you expect the percentage of dimer to increase or decrease? Why?arrow_forward
- A solution is prepared by dissolving 0.050 mol of diiodocyclohexane, C5H10I2, in the solvent CCl4.The total solution volume is 1.00 L When the reaction C6H10I2 C6H10 + I2 has come to equilibrium at 35 C, the concentration of I2 is 0.035 mol/L. (a) What are the concentrations of C6H10I2 and C6H10 at equilibrium? (b) Calculate Kc, the equilibrium constant.arrow_forwardKc for the decomposition of ammonium hydrogen sulfide is 1.8 104 at 25 C. NH4HS(s) NH3(g) + H2S(g) (a) When the pure salt decomposes in a flask, what are the equilibrium concentrations of NH3 and H2S? (b) If NH4HS is placed in a flask already containing 0.020 mol/L of NH3 and then the system is allowed to come to equilibrium, what are the equilibrium concentrations of NH3 and H2S?arrow_forwardThe equilibrium constant Kc for the synthesis of methanol, CH3OH. CO(g)+2H2(g)CH3OH(g) is 4.3 at 250C and 1.8 at 275C. Is this reaction endothermic or exothermic?arrow_forward
- Lexan is a plastic used to make compact discs, eyeglass lenses, and bullet-proof glass. One of the compounds used to make Lexan is phosgene (COCl2), an extremely poisonous gas. Phosgene decomposes by the reaction COCl2(g)CO(g)+Cl2(g) for which Kp 6.8 109 at 100C. If pure phosgene at an initial pressure of 1.0 atm decomposes, calculate the equilibrium pressures of all species.arrow_forwardConsider the equilibrium H2(g)+S(s)H2S(g)When this system is at equilibrium at 25C in a 2.00-L container, 0.120 mol of H2, 0.034 mol of H2S, and 0.4000 mol of S are present. When the temperature is increased to 35C, the partial pressure of H2 increases to 1.56 atm. (a) What is K for the reaction at 25C? (b) What is K for the reaction at 35C?arrow_forwardConsider the following system at equilibrium at 25C: PCl3(g)+Cl(g)PCl5(g)G=92.50KJ What will happen to the ratio of partial pressure of PCl5 to partial pressure of PCI3 if the temperature is raised? Explain completely.arrow_forward
- A mixture of SO2, O2, and SO3 at 1000 K contains the gases at the following concentrations: [SO2] = 5.0 103 mol/L, [O2] = 1.9 103 mol/L, and [SO3] = 6.9 103 mol/L. Is the reaction at equilibrium? If not, which way will the reaction proceed to reach equilibrium? 2 SO2(g) + O2(g) 2 SO3(g) Kc = 279arrow_forwardThe reaction, 3 H2(g) + N2(g) (g), has the fol lowing equilibrium constants at the temperatures given: atT=25°C,K= 2.8 X 104 at T = 500°C, A = 2.4 X IO"7 At which temperature are reactants favored? At which temperature are products favored? YVhat can you say about the reaction if the equilibrium constant is 1.2 at 127°C?arrow_forwardKp for the following reaction is 0.16 at 25 C: 2 NOBr(g) 2 NO(g) + Br2(g) The enthalpy change for the reaction at standard conditions is + 16.3 kJ/mol-rxn. Predict the effect of the following changes on the position of the equilibrium; that is, state which way the equilibrium will shift (left, right, or no change) when each of the following changes is made. (a) adding more Br2(g) (b) removing some NOBr(g) (c) decreasing the temperature (d) increasing the container volumearrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning