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Acid-Base Properties of Elements and Their Oxides
The ion
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- Write chemical equations that show the indicated behavior in aqueous solution for each of the following chemical species. a. HOCl behaves as a BrnstedLowry acid b. NH3 behaves as a BrnstedLowry base c. H2PO4 behaves as a BrnstedLowry acid d. CO32 behaves as a BrnstedLowry basearrow_forwardEthanol (ethyl alcohol), CH3CH2OH, can act as a BrnstedLowry acid. Write the chemical equation for the reaction of ethanol as an acid with hydroxide ion, OH. Ethanol can also react as a BrnstedLowry base. Write the chemical equation for the reaction of ethanol as a base with hydronium ion, H3O+. Explain how you arrived at these chemical equations. Both of these reactions can also be considered Lewis acid base reactions. Explain this.arrow_forwardWrite chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2CO3 (carbonic acid) b. H2C3H2O4 (malonic acid)arrow_forward
- Without writing an equation, specify the molecular ratio in which each of the following acidbase pairs will react. a. HCl and KOH b. H2CO3 and KOH c. HCl and Ca(OH)2 d. H2CO3 and Ca(OH)2arrow_forwardWrite a balanced chemical equation to represent each of the following acidbase neutralization reactions. a. HCl and LiOH b. HNO3 and Ba(OH)2 c. H2SO4 and NaOH d. KOH and H3PO4arrow_forwardHydrazine, N2H4 (having the structure H2NNH2), and its derivatives have been used as rocket fuels. Draw the Lewis electron-dot formula for the hydrazine molecule. Describe the geometries expected about the nitrogen atoms in this molecule. Why would you expect hydrazine to be basic? Which substance, NH3 or N2H4, would you expect to be more basic? Why? Write the chemical equation in which hydrazine reacts with hydrochloric acids to form the salt N2H5Cl. Consider the positive ion of this salt. How does its basic character compare with that of NH3 and N2H4? Explain.arrow_forward
- Acids You make a solution by dissolving 0.0010 mol of HCl in enough water to make 1.0 L of solution. a Write the chemical equation for the reaction of HCl(aq) and water. b Without performing calculations, give a rough estimate of the pH of the HCl solution. Justify your answer. c Calculate the H3O+ concentration and the pH of the solution. d Is there any concentration of the base OH present in this solution of HCl(aq)? If so, where did it come from? e If you increase the OH concentration of the solution by adding NaOH, does the H3O+ concentration change? If you think it does, explain why this change occurs and whether the H3O+ concentration increases or decreases. f If you were to measure the pH of 10 drops of the original HCl solution, would you expect it to be different from the pH of the entire sample? Explain. g Explain how two different volumes of your original HCl solution can have the same pH yet contain different moles of H3O+. h If 1.0 L of pure water were added to the HCl solution, would this have any impact on the pH? Explain.arrow_forwardThe structure of ethylene diamine is illustrated in study question 76. Is this compound a Brnsted acid, a Brnsted base, a Lewis acid or a Lewis base, or some combination of these.arrow_forwardWrite chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2C2O4 (oxalic acid) b. H2C4H4O6 (tartaric acid)arrow_forward
- To measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?arrow_forwardWrite a balanced chemical equation to represent each of the following acidbase neutralization reactions. a. HCl and NaOH b. HNO3 and KOH c. H2SO4 and LiOH d. Ba(OH)2 and H3PO4arrow_forwardClassify each of the following acids as monoprotic, diprotic, or triprotic. a. HClO3 (chloric acid) b. HC3H5O4 (glyceric acid) c. H3C6H5O7 (citric acid) d. H3PO4 (phosphoric acid)arrow_forward
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