Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Textbook Question
Chapter 15, Problem 54E
- Account for formation of the following series of oxides in terms of the electron configurations of the elements and the discussion of ionic compounds in Section 2.7 GI:
K2O, CaO, Sc2O3, Ti02, V205, CrO3.
Oxide | K20(s) | Ca0(s) | Ti02(s) | V205(s) |
Alff | -363.2 | -635.1 | -938.7 | -1550.6 |
Calculate the enthalpy changes in the following general reaction for each case:
MnOm(s) + H2(g) ->nM(s) + mH2O(g)
(You will need to write the balanced equation for each case and then compute ΔH°. )(d) Based on the data given, estimate a value ofΔHf ° for Sc203(s).
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 15 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 15.2 - Molybdenum metal must absorb radiation with a...Ch. 15.2 - Titanium metal requires a photon with a minimum...Ch. 15.2 - Prob. 15.2.1PECh. 15.2 - Classify each of the following statements as...Ch. 15.3 - Prob. 15.3.1PECh. 15.3 -
6 38 Indicate whether energy is emitted or...Ch. 15.3 - Using Equation 6.5. calculate the energy of an...Ch. 15.3 - Prob. 15.4.2PECh. 15.4 - The visible emission lines observed by Balmer all...Ch. 15.4 - Prob. 15.5.2PE
Ch. 15.4 - Prob. 15.6.1PECh. 15.4 - The hydrogen atom can absorb light of wavelength...Ch. 15.5 - Prob. 15.7.1PECh. 15.5 - Prob. 15.7.2PECh. 15.5 - Use the de Brogue relationship to determine the...Ch. 15.5 - Prob. 15.8.2PECh. 15.6 - Neutron diffraction is an important technique for...Ch. 15.6 - The electron microscope has been widely used to...Ch. 15.6 - Prob. 15.10.1PECh. 15.6 - An AM radio station broadcasts at 1010 kHz, and...Ch. 15.6 - One type of sunburn occurs on exposure to UV light...Ch. 15.6 - Prob. 15.11.2PECh. 15.7 - Prob. 15.12.1PECh. 15.7 - A stellar object is emitting radiation at 3.55 mm....Ch. 15 - Prob. 1DECh. 15 - Prob. 1ECh. 15 - Identify the group of elements that corresponds to...Ch. 15 - Prob. 3ECh. 15 - Using the periodic table as a guide, write the...Ch. 15 -
Arrange Be, C, K, and Ca in order of increasing...Ch. 15 - Prob. 6ECh. 15 - Prob. 7ECh. 15 - Prob. 8ECh. 15 - Consider the isoelectronic ions F- and Na+. (a)...Ch. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - Prob. 12ECh. 15 - Give the values for n, I,and mlfor each orbital in...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Which of the following represent impossible...Ch. 15 - For the table that follows, write which orbital...Ch. 15 - Sketch the shape and orientation of the following...Ch. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - Two possible electron configurations for an Li...Ch. 15 -
6.70 An experiment called the Stern—Gerlach...Ch. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - What are "valence electrons"? What are "core...Ch. 15 - For each element, indicate the number of valence...Ch. 15 - Write the condensed electron configurations for...Ch. 15 - Write the condensed electron configurations for...Ch. 15 - Identify the specific element that corresponds to...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - In an experiment to study the photoelectric...Ch. 15 - Prob. 39ECh. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - Prob. 44ECh. 15 - Prob. 45ECh. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - [6.100] The Chemistry and Life box in Section 6.7...Ch. 15 - Prob. 49ECh. 15 - [6.104] In the experiment shown schematically...Ch. 15 - Microwave ovens use microwave radiation to heat...Ch. 15 - Prob. 52ECh. 15 - The discovery of hafnium, element number 72,...Ch. 15 - Account for formation of the following series of...Ch. 15 - Prob. 55ECh. 15 - The two most common isotopes of uranium are 235U...Ch. 15 - Hypothetical elements X and Y form a molecule XY2,...Ch. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Prob. 63ECh. 15 - Prob. 64ECh. 15 - Consider the following statements about first...Ch. 15 - Prob. 66ECh. 15 - Prob. 67ECh. 15 -
Write the electron configurations for (a) Ga3+...Ch. 15 - Prob. 69AECh. 15 - Prob. 70AECh. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - Prob. 73AECh. 15 - Prob. 74AECh. 15 - Consider the hypothetical reaction A(g) 2B(g). A...Ch. 15 - 15.76 As shown in Table 15.2, the equilibrium...Ch. 15 - Prob. 77AECh. 15 - Prob. 78AECh. 15 - Prob. 79AECh. 15 - Prob. 80AECh. 15 - Prob. 81AECh. 15 - Prob. 82AECh. 15 - Prob. 83AECh. 15 - Prob. 84AECh. 15 - Prob. 85AECh. 15 - Prob. 86AECh. 15 - Prob. 87AECh. 15 - Prob. 88AECh. 15 - Prob. 89AECh. 15 - Prob. 90AECh. 15 - Prob. 91AECh. 15 - Prob. 92AECh. 15 - Prob. 93IECh. 15 - Prob. 94IECh. 15 - Prob. 95IECh. 15 - Prob. 96IECh. 15 - Write the equilibrium-constant expression for the...Ch. 15 - In Section 11.5, we defined the vapor pressure of...Ch. 15 - Prob. 99IECh. 15 - Prob. 100IE
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