ORGANIC CHEMISTRY - LOOSELEAF W/CONNECT
6th Edition
ISBN: 9781266060144
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 15, Problem 47P
a. Explain why protonation of pyrrole occurs at
b. Explain why A is more acidic than C, the conjugate acid of pyridine.
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61. Give the products of the following acid-base reactions and indicate whether reactants or products are favored at equilibrium. (Use the pk, values that are
given in Section 2.3.)
CH,NH; =
a. CH,COH + CH;0
b. CH,CH,OH + NH,
c. CH;COH +
d. CH;CH,OH + HCI =
The acids are HCl, H2SO4, and HC2H3O2.
19. Choose the correct reagents/reactants to synthesize the following compound.
1. NaH
1. NaH
A.
OH 2.
OH 2.
Br
Br
3. H3O*
С.
1. NaH
1. NaH
HO
2.
HO
2.
Br
Br
3. H;0*
B.
D.
Chapter 15 Solutions
ORGANIC CHEMISTRY - LOOSELEAF W/CONNECT
Ch. 15.2 - Prob. 1PCh. 15.2 - Problem 17.2 What orbitals are used to form the...Ch. 15.3 - Prob. 4PCh. 15.3 - Problem-17.5 What is the structure of propofol,...Ch. 15.6 - Prob. 7PCh. 15.8 - Prob. 8PCh. 15.8 - Prob. 11PCh. 15.8 - Prob. 12PCh. 15.8 - Problem 17.16 Rank the following compounds in...Ch. 15.8 - Problem 17.17 Draw the seven resonance structures...
Ch. 15 - 17.23 Name each compound and state how many lines...Ch. 15 - Prob. 21PCh. 15 - Prob. 22PCh. 15 - 17.27 Give the IUPAC name for each compounds.
a....Ch. 15 - 17.28 Draw a structure corresponding to each...Ch. 15 - 17.29 a. Draw the 14 constitutional isomers of...Ch. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - 17.38
How many electrons does C contain?
How...Ch. 15 - Prob. 36PCh. 15 - 17.40 Explain the observed rate of reactivity of...Ch. 15 - 17.41 Draw a stepwise mechanism for the following...Ch. 15 - Prob. 39PCh. 15 - 17.43 Draw additional resonance structures for...Ch. 15 - Prob. 41PCh. 15 - Prob. 42PCh. 15 - 17.46 Which compound in each pair is the stronger...Ch. 15 - 17.47 Treatment of indene with forms its...Ch. 15 - Prob. 45PCh. 15 - 17.49 Draw the conjugate bases of pyrrole and...Ch. 15 - 17.50 a. Explain why protonation of pyrrole occurs...Ch. 15 - Prob. 48PCh. 15 - Prob. 49PCh. 15 - 17.53 How many signals does each compound...Ch. 15 - 17.54 Which of the diethylbenzene isomers (ortho,...Ch. 15 - 17.55 Propose a structure consistent with each...Ch. 15 - 17.56 Propose a structure consistent with each...Ch. 15 - 17.57 Thymol (molecular formula ) is the major...Ch. 15 - 17.58 You have a sample of a compound of molecular...Ch. 15 - 17.59 Explain why tetrahydrofuran has a higher...Ch. 15 - 17.60 Rizatriptan (trade name Maxalt) is a...Ch. 15 - 17.61 Zolpidem (trade name Ambien) promotes the...Ch. 15 - 17.62 Answer the following questions about...Ch. 15 - 17.63 Stanozolol is an anabolic steroid that...Ch. 15 - Prob. 61P
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- The base methylamine ( CH3NH₂) has a Kb of 5.0 x 10-4. A closely related base, trimethylamine ( (CH3)3N), has a Kb of 7.4 x 10-5. a Which of the two bases is stronger? methylamine trimethylamine Correct Since methylamine has the larger K₁, methylamine is the stronger base. b Calculate the pH of a 0.38 M solution of the stronger base. pH =arrow_forward78) Why are primary alcohols more acidic than tertiary alcohols, in general? Because tertiary alcohols have less acidic hydrogens. Because primary alcohols have less electron-donating groups which create more effective charge separation between oxygen and hydrogen atom, making it more acidic. Because primary alcohols are more polar than tertiary alcohols. Because primary alcohols have less electron-donating groups which decrease electron density on oxygen, making it more susceptible for H+ to depart from the structure.arrow_forwardArrange the compounds in order of decreasing basicity A. ethylamine B. 2-aminoethanol C. 3-amino-1-propanolarrow_forward
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