Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 15, Problem 44PP
Interpretation Introduction

Interpretation: The structure of a given molecular formula C9H18 to be predicted using 1HNMR and 13CNMR spectra.

Concept Introduction:

1HNMR : The 1HNMR spectrum gives information on the different electronic environment of protons. The number of signal (proton types) generated in 1HNMR are predicted by performing symmetry operations (rotation or reflection symmetry).

The 13CNMR spectrum gives information on the different electronic environments of carbon. As like 1HNMR , the number of signals generated in 13CNMR are predicted by performing symmetry operations (rotation or reflection symmetry). Only chemical shift values are reported in the spectrum but not the multiplicity and integration values because the coupling between two neighboring 13C13C nuclei are weakly involved due to the low abundance of 13C isotopes of carbon atom.

HDI Calculation:

HDI=2(C)+2+N-H-X2whereCrepresentthenumberofcarbonNrepresentthenumberofnitrogenHrepresentthenumberofhydrogenXrepresentthenumberofhalogen.

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Chapter 15 Solutions

Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy

Ch. 15.5 - Prob. 8PTSCh. 15.5 - Ethyl 3-ethoxypropanoate is a solvent used in the...Ch. 15.5 - Prob. 10CCCh. 15.6 - Prob. 4LTSCh. 15.6 - Prob. 11PTSCh. 15.6 - Prob. 12PTSCh. 15.6 - Prob. 13PTSCh. 15.6 - Prob. 14ATSCh. 15.7 - Prob. 5LTSCh. 15.7 - Prob. 15PTSCh. 15.7 - The volatile organic compounds (VOCs) produced by...Ch. 15.7 - Prob. 17CCCh. 15.7 - Prob. 18CCCh. 15.8 - Prob. 6LTSCh. 15.8 - Prob. 19PTSCh. 15.9 - Prob. 7LTSCh. 15.9 - Prob. 21PTSCh. 15.9 - The familiar odor produced when rain falls on dry...Ch. 15.10 - Prob. 8LTSCh. 15.10 - Prob. 23PTSCh. 15.10 - Prob. 24PTSCh. 15.10 - Neurotransmitters are small molecules that are...Ch. 15.12 - Prob. 9LTSCh. 15.12 - Prob. 26PTSCh. 15.12 - Prob. 27ATSCh. 15.13 - Prob. 10LTSCh. 15.13 - Prob. 28PTSCh. 15.13 - Prob. 29PTSCh. 15.13 - Prob. 30PTSCh. 15 - Prob. 32PPCh. 15 - Prob. 33PPCh. 15 - Prob. 34PPCh. 15 - Prob. 35PPCh. 15 - Prob. 36PPCh. 15 - Prob. 37PPCh. 15 - Prob. 38PPCh. 15 - Prob. 39PPCh. 15 - Prob. 40PPCh. 15 - Prob. 41PPCh. 15 - Prob. 42PPCh. 15 - Prob. 43PPCh. 15 - Prob. 44PPCh. 15 - Prob. 45PPCh. 15 - Prob. 46PPCh. 15 - Prob. 47PPCh. 15 - Prob. 48PPCh. 15 - Prob. 49PPCh. 15 - Prob. 50PPCh. 15 - Prob. 51PPCh. 15 - Prob. 52PPCh. 15 - Prob. 53PPCh. 15 - Prob. 54PPCh. 15 - Prob. 55PPCh. 15 - Prob. 56PPCh. 15 - Propose the structure of a compound that exhibits...Ch. 15 - Prob. 58PPCh. 15 - Prob. 59PPCh. 15 - Prob. 60PPCh. 15 - Prob. 61PPCh. 15 - Prob. 62PPCh. 15 - Prob. 63IPCh. 15 - Prob. 64IPCh. 15 - Prob. 65IPCh. 15 - Prob. 66IPCh. 15 - Prob. 67IPCh. 15 - Prob. 68IPCh. 15 - Prob. 69IPCh. 15 - Prob. 70IPCh. 15 - Prob. 71IPCh. 15 - Prob. 72IPCh. 15 - Prob. 73IPCh. 15 - Prob. 74IPCh. 15 - Prob. 75IPCh. 15 - Prob. 76IPCh. 15 - Prob. 77IPCh. 15 - Prob. 78CPCh. 15 - Compound 1 can serve as a precursor in the...Ch. 15 - Prob. 81CP
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