Introduction To General, Organic, And Biochemistry
Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 15, Problem 43P
Interpretation Introduction

Interpretation:

To arrange the given compound in order of increasing boiling point: CH3 CH2 CH2 CH3, CH3 CH2 CH2 OH, and CH3 CH2 CH2 NH2..

Boiling point values from lowest to highest are -0.5° C, 7.2° C, and 77.8° C.

Concept introduction:

The temperature at which the external pressure of the surrounding of liquid is equal to the vapor pressure is known as boiling point. So, the boiling point of the liquid depends upon the atmospheric pressure.

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage
Which carbocation is more stable?
Are the products of the given reaction correct?  Why or why not?

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Introduction To General, Organic, And Biochemistry

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