Bundle: Chemistry In Focus: A Molecular View Of Our World, 7th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card
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Chapter 15, Problem 3SC
Interpretation Introduction

Interpretation:

The structures of ethyl-2-methylbutanoate and civetone are to be examined and upon opening a bottle containing the mixture of these two, which one would dominate initial smell is to be determined.

Concept introduction:

Civetone is an unsaturated macrocyclic ketone produced by the civet oil and it is one of the oldest ingredient of perfume.

Bundle: Chemistry In Focus: A Molecular View Of Our World, 7th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card, Chapter 15, Problem 3SC

Civetone

Graham’s law states that the rate of diffusion is inversely proportional to the square root of mass of its particles.

Molar mass is defined as the ratio of moles (n) and mass of the element.

n=massmolarmass

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2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2
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Chapter 15 Solutions

Bundle: Chemistry In Focus: A Molecular View Of Our World, 7th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card

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