Introduction To Chemistry
5th Edition
ISBN: 9781259911149
Author: BAUER, Richard C., Birk, James P., Marks, Pamela
Publisher: Mcgraw-hill Education,
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Question
Chapter 15, Problem 2PP
Interpretation Introduction
Interpretation:
The new nuclide formed is to be identified and the given equation for the nuclear reaction is to be balanced.
Concept Introduction:
In beta emission, a neutron is converted into a proton. So, the mass number remains the same but, atomic number increases by 1. In the process, mass number as well as atomic number is conserved. The total mass number or atomic number of the reactants equals the sum of the mass numbers or
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 15 Solutions
Introduction To Chemistry
Ch. 15 - Prob. 1QCCh. 15 - Prob. 2QCCh. 15 - Prob. 3QCCh. 15 - Prob. 4QCCh. 15 - Prob. 5QCCh. 15 - Prob. 6QCCh. 15 - Prob. 1PPCh. 15 - Prob. 2PPCh. 15 - Prob. 3PPCh. 15 - Prob. 4PP
Ch. 15 - Prob. 5PPCh. 15 - Prob. 6PPCh. 15 - Prob. 7PPCh. 15 - Prob. 8PPCh. 15 - Prob. 9PPCh. 15 - Prob. 10PPCh. 15 - Prob. 11PPCh. 15 - Prob. 1QPCh. 15 - Prob. 2QPCh. 15 - Prob. 3QPCh. 15 - Prob. 4QPCh. 15 - Prob. 5QPCh. 15 - Prob. 6QPCh. 15 - Prob. 7QPCh. 15 - Prob. 8QPCh. 15 - Prob. 9QPCh. 15 - Prob. 10QPCh. 15 - Prob. 11QPCh. 15 - Prob. 12QPCh. 15 - Prob. 13QPCh. 15 - Prob. 14QPCh. 15 - Prob. 15QPCh. 15 - Prob. 16QPCh. 15 - Prob. 17QPCh. 15 - Prob. 18QPCh. 15 - Prob. 19QPCh. 15 - Prob. 20QPCh. 15 - Prob. 21QPCh. 15 - Prob. 22QPCh. 15 - Prob. 23QPCh. 15 - Prob. 24QPCh. 15 - Prob. 25QPCh. 15 - Prob. 26QPCh. 15 - Prob. 27QPCh. 15 - Prob. 28QPCh. 15 - Prob. 29QPCh. 15 - Prob. 30QPCh. 15 - Prob. 31QPCh. 15 - Prob. 32QPCh. 15 - Prob. 33QPCh. 15 - Prob. 34QPCh. 15 - Prob. 35QPCh. 15 - Prob. 36QPCh. 15 - Prob. 37QPCh. 15 - Prob. 38QPCh. 15 - Prob. 39QPCh. 15 - Prob. 40QPCh. 15 - Prob. 41QPCh. 15 - Prob. 42QPCh. 15 - Prob. 43QPCh. 15 - Prob. 44QPCh. 15 - Prob. 45QPCh. 15 - Prob. 46QPCh. 15 - Prob. 47QPCh. 15 - Prob. 48QPCh. 15 - Prob. 49QPCh. 15 - Prob. 50QPCh. 15 - Prob. 51QPCh. 15 - Prob. 52QPCh. 15 - Prob. 53QPCh. 15 - Prob. 54QPCh. 15 - Prob. 55QPCh. 15 - Prob. 56QPCh. 15 - Prob. 57QPCh. 15 - Prob. 58QPCh. 15 - Prob. 59QPCh. 15 - Prob. 60QPCh. 15 - Prob. 61QPCh. 15 - Prob. 62QPCh. 15 - Prob. 63QPCh. 15 - Prob. 64QPCh. 15 - Prob. 65QPCh. 15 - Prob. 66QPCh. 15 - Prob. 67QPCh. 15 - Prob. 68QPCh. 15 - Prob. 69QPCh. 15 - Prob. 70QPCh. 15 - Prob. 73QPCh. 15 - Prob. 74QPCh. 15 - Prob. 75QPCh. 15 - Prob. 76QPCh. 15 - Prob. 77QPCh. 15 - Prob. 78QPCh. 15 - Prob. 79QPCh. 15 - Prob. 80QPCh. 15 - Prob. 81QPCh. 15 - Prob. 82QPCh. 15 - Prob. 83QPCh. 15 - Prob. 84QPCh. 15 - Prob. 85QPCh. 15 - Prob. 86QPCh. 15 - Prob. 87QPCh. 15 - Prob. 88QPCh. 15 - Prob. 89QPCh. 15 - Prob. 90QPCh. 15 - Prob. 91QPCh. 15 - Prob. 92QPCh. 15 - Prob. 93QPCh. 15 - Prob. 94QPCh. 15 - Prob. 95QPCh. 15 - Prob. 96QPCh. 15 - Prob. 97QPCh. 15 - Prob. 98QPCh. 15 - Prob. 99QPCh. 15 - Prob. 100QPCh. 15 - Prob. 101QPCh. 15 - Prob. 102QPCh. 15 - Prob. 103QPCh. 15 - Prob. 104QPCh. 15 - Prob. 105QPCh. 15 - Prob. 106QPCh. 15 - Prob. 107QPCh. 15 - Prob. 108QPCh. 15 - Prob. 109QPCh. 15 - Prob. 110QPCh. 15 - Prob. 111QPCh. 15 - Prob. 112QPCh. 15 - Prob. 113QPCh. 15 - Prob. 114QPCh. 15 - Prob. 115QPCh. 15 - Prob. 116QPCh. 15 - Prob. 117QPCh. 15 - Prob. 118QPCh. 15 - Prob. 119QPCh. 15 - Prob. 120QPCh. 15 - Prob. 121QPCh. 15 - Prob. 122QPCh. 15 - Prob. 123QP
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