
Concept explainers
(a)
Interpretation:
The number of moles and the number of grams of the given solute in a given solutionhave to be calculated.
Concept Introduction:
The composition of a solution can be defined by expressing its concentration. The concentrations of solutions can be expressed in different ways, which are involved in the quantity of solute and the quantity of solution or solvent. Various methodsare usedto describe the concentration of the solution quantitatively. Some commonly used quantitative concentration terms are percent by mass, percent by volume, molarity, molality and mole fraction.
Molarity: Molarity is defined as the number of moles of solute present in one liter of the solution.
In expression,
Again
(a)

Answer to Problem 27A
Number of moles | Number of grams | |
127 mL of 0.105 M HNO3 | 0.0133 mol | 0.84 gm |
Explanation of Solution
Data given: Molarity of HNO3 solution= 0.105 M
Volume of HNO3 solution = 127 mL = 0.127 L
(b)
Interpretation:
The number of moles and the number of grams of the given solute in a given solutionhave to be calculated.
Concept Introduction:
The composition of a solution can be defined by expressing its concentration. The concentrations of solutions can be expressed in different ways, which are involved in the quantity of solute and the quantity of solution or solvent. Various methods are used to describe the concentration of the solution quantitatively. Some commonly used quantitative concentration terms are percent by mass, percent by volume, molarity, molality and mole fraction.
Molarity: Molarity is defined as the number of moles of solute present in one liter of the solution.
In expression,
Again
(b)

Answer to Problem 27A
Number of moles | Number of grams | |
155 mL of 15.1 M NH3 | 2.34 mol | 39.79 gm |
Explanation of Solution
Data given: Molarity of NH3 solution= 15.1 M
Volume of NH3 solution = 155 mL = 0.155 L
(c)
Interpretation:
The number of moles and the number of grams of the given solute in a given solutionhave to be calculated.
Concept Introduction:
The composition of a solution can be defined by expressing its concentration. The concentrations of solutions can be expressed in different ways, which are involved in the quantity of solute and the quantity of solution or solvent. Various methods are used to describe the concentration of the solution quantitatively. Some commonly used quantitative concentration terms are percent by mass, percent by volume, molarity, molality and mole fraction.
Molarity: Molarity is defined as the number of moles of solute present in one liter of the solution.
In expression,
Again
(c)

Answer to Problem 27A
Number of moles | Number of grams | |
2.51 L of 2.01 × 10-3 M KSCN | 0.005 mol | 0.49 gm |
Explanation of Solution
Data given: Molarity of KSCN solution= 2.01 × 10-3M
The volume of KSCN solution = 2.51 L
(d)
Interpretation:
The number of moles and the number of grams of the given solute in a given solutionhave to be calculated.
Concept Introduction:
The composition of a solution can be defined by expressing its concentration. The concentrations of solutions can be expressed in different ways, which are involved in the quantity of solute and the quantity of solution or solvent. Various methods are used to describe the concentration of the solution quantitatively. Some commonly used quantitative concentration terms are percent by mass, percent by volume, molarity, molality and mole fraction.
Molarity: Molarity is defined as the number of moles of solute present in one liter of the solution.
In expression,
Again
(d)

Answer to Problem 27A
Number of moles | Number of grams | |
12.2 mL of 2.45 M HCl | 0.03 mol | 1.1 gm |
Explanation of Solution
Data given: Molarity of HCl solution= 2.45 M
Volume of HCl solution= 12.2 mL = 0.0122 L
Chapter 15 Solutions
World of Chemistry, 3rd edition
- Order the following series of compounds from highest to lowest reactivity to electrophilic aromatic substitution, explaining your answer: 2-nitrophenol, p-Toluidine, N-(4-methylphenyl)acetamide, 4-methylbenzonitrile, 4-(trifluoromethyl)benzonitrile.arrow_forwardOrdene la siguiente serie de compuestos de mayor a menor reactividad a la sustitución aromática electrofílica, explicando su respuesta: ácido bencenosulfónico, fluorobenceno, etilbenceno, clorobenceno, terc-butilbenceno, acetofenona.arrow_forwardCan I please get all final concentrations please!arrow_forward
- State the detailed mechanism of the reaction of benzene with isopropanol in sulfuric acid.arrow_forwardDo not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction. For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 -> NO2 + NO3_(K1) NO2 + NO3 →> N2O5 (k-1) → NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Give the expression for the acceptable rate. (A). d[N₂O] dt = -1 2k,k₂[N205] k₁+k₂ d[N₂O5] (B). dt =-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³ (C). d[N₂O] dt =-k₁[N₂O] + k₁[N205] - K3 [NO] [N205] (D). d[N2O5] =-k₁[NO] - K3[NO] [N₂05] dtarrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
- For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardR lactam or lactone considering as weak acid or weak base and whyarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





