Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 15, Problem 15A.5P
Interpretation Introduction
Interpretation:
The dimensions of the given monoclinic unit cell have to be determined.
Concept Introduction:
Volume of a monoclinic unit cell
Density
Where,
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When 2-bromo-93-dimethylbutane is heated with sodium methoxide, one majors.. në la formed.
4th attempt
Part 1 (0.5 point)
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Draw the major alkene product and all other byproducts. Be sure to include lone-pair electrons and charges.
Part 2 (0.5 point)
What type of mechanism is occuring?
Choose one:
AS1
3rd attempt
X
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41
See Hint
Part 1 (0.5 point)
Feedback
See Periodic Table See Hint
Complete the mechanism for the E1 reaction below by following the directions written above each of the five boxes. Be sure to include lone pair
electrons and nonzero formal charges.
2nd attempt
1 Provide the missing curved arrow notation.
E+
RUDDA
1st attempt
Feedback
See Periodic Table
See Hint
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See Periodic Table See Hint
Chapter 15 Solutions
Atkins' Physical Chemistry
Ch. 15 - Prob. 15A.1STCh. 15 - Prob. 15B.1STCh. 15 - Prob. 15B.3STCh. 15 - Prob. 15C.1STCh. 15 - Prob. 15C.2STCh. 15 - Prob. 15A.1DQCh. 15 - Prob. 15A.2DQCh. 15 - Prob. 15A.3DQCh. 15 - Prob. 15A.1AECh. 15 - Prob. 15A.1BE
Ch. 15 - Prob. 15A.2AECh. 15 - Prob. 15A.2BECh. 15 - Prob. 15A.3AECh. 15 - Prob. 15A.3BECh. 15 - Prob. 15A.4AECh. 15 - Prob. 15A.4BECh. 15 - Prob. 15A.1PCh. 15 - Prob. 15A.2PCh. 15 - Prob. 15A.3PCh. 15 - Prob. 15A.4PCh. 15 - Prob. 15A.5PCh. 15 - Prob. 15A.6PCh. 15 - Prob. 15A.7PCh. 15 - Prob. 15A.8PCh. 15 - Prob. 15A.9PCh. 15 - Prob. 15B.1DQCh. 15 - Prob. 15B.2DQCh. 15 - Prob. 15B.3DQCh. 15 - Prob. 15B.1AECh. 15 - Prob. 15B.1BECh. 15 - Prob. 15B.2AECh. 15 - Prob. 15B.2BECh. 15 - Prob. 15B.3AECh. 15 - Prob. 15B.3BECh. 15 - Prob. 15B.4AECh. 15 - Prob. 15B.4BECh. 15 - Prob. 15B.5AECh. 15 - Prob. 15B.5BECh. 15 - Prob. 15B.6AECh. 15 - Prob. 15B.6BECh. 15 - Prob. 15B.7AECh. 15 - Prob. 15B.7BECh. 15 - Prob. 15B.11AECh. 15 - Prob. 15B.11BECh. 15 - Prob. 15B.12AECh. 15 - Prob. 15B.12BECh. 15 - Prob. 15B.1PCh. 15 - Prob. 15B.2PCh. 15 - Prob. 15B.3PCh. 15 - Prob. 15B.4PCh. 15 - Prob. 15B.6PCh. 15 - Prob. 15B.7PCh. 15 - Prob. 15C.1DQCh. 15 - Prob. 15C.2DQCh. 15 - Prob. 15C.1AECh. 15 - Prob. 15C.2AECh. 15 - Prob. 15C.2BECh. 15 - Prob. 15C.3AECh. 15 - Prob. 15C.3BECh. 15 - Prob. 15C.4AECh. 15 - Prob. 15C.4BECh. 15 - Prob. 15C.5AECh. 15 - Prob. 15C.5BECh. 15 - Prob. 15C.1PCh. 15 - Prob. 15C.2PCh. 15 - Prob. 15C.3PCh. 15 - Prob. 15C.4PCh. 15 - Prob. 15C.5PCh. 15 - Prob. 15C.7PCh. 15 - Prob. 15C.8PCh. 15 - Prob. 15C.9PCh. 15 - Prob. 15D.1DQCh. 15 - Prob. 15D.1AECh. 15 - Prob. 15D.1BECh. 15 - Prob. 15D.2AECh. 15 - Prob. 15D.2BECh. 15 - Prob. 15D.3AECh. 15 - Prob. 15D.3BECh. 15 - Prob. 15D.1PCh. 15 - Prob. 15D.2PCh. 15 - Prob. 15E.1DQCh. 15 - Prob. 15E.1AECh. 15 - Prob. 15E.1BECh. 15 - Prob. 15E.2AECh. 15 - Prob. 15E.2BECh. 15 - Prob. 15E.3AECh. 15 - Prob. 15E.3BECh. 15 - Prob. 15E.5PCh. 15 - Prob. 15F.1DQCh. 15 - Prob. 15F.1AECh. 15 - Prob. 15F.1BECh. 15 - Prob. 15F.2AECh. 15 - Prob. 15F.2BECh. 15 - Prob. 15F.3AECh. 15 - Prob. 15F.3BECh. 15 - Prob. 15F.4AECh. 15 - Prob. 15F.4BECh. 15 - Prob. 15F.5AECh. 15 - Prob. 15F.5BECh. 15 - Prob. 15G.1DQCh. 15 - Prob. 15G.2DQCh. 15 - Prob. 15G.1AECh. 15 - Prob. 15G.1BECh. 15 - Prob. 15.1IA
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- Heating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of Sy1. 3rd attempt h Draw curved arrow(s) to show how the alcohol reacts with phosphoric acid. TH © 1 0 0 +1% # 2nd attempt Feedback H Ju See Periodic Table See Hint H Jud See Periodic Table See Hintarrow_forwardPart 2 (0.5 point) 0- Draw the major organic product with the correct geometry. 10 1: 70000 х く 1st attempt Part 1 (0.5 point) Feedback Please draw all four bonds at chiral centers. P See Periodic Table See Hintarrow_forwardHeating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of S№1. 2nd attempt 0 See Periodic Table See Hint Draw the organic intermediate from the first step (no byproducts) and draw curved arrow(s) to show how it reacts. TH +11: 1st attempt Feedback H H H C F F See Periodic Table See Hintarrow_forward
- This molecule undergoes an E1 mechanism when stirred in methanol. 3rd attempt CH₂OH CH₂OH 6148 O See Periodic Table. See Hint Draw 3 chemical species including formal charges and lone pairs of electrons. Add the missing curved arrow notation. H N O O SA 3 Br Iarrow_forwardComplete the mechanism for the E1 reaction below by following the directions written above each of the five boxes. Be sure to include lone pair electrons and nonzero formal charges. 1st attempt Y 0 + Provide the missing curved arrow notation. 01: See Periodic Table See Hint H C Br Iarrow_forwardPlease help answer number 2. Thanks in advance.arrow_forward
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