Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Question
Chapter 15, Problem 15F.2AE
Interpretation Introduction
Interpretation:
Molar susceptibility of benzene has to be calculated.
Concept Introduction:
Molar magnetic susceptibility can be calculated using the following formula.
Where,
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In the following reaction, what quantity in moles of CH₃OH are required to give off 4111 kJ of heat? 2 CH₃OH (l) + 3 O₂ (g) → 2 CO₂ (g) + 4 H₂O(g) ∆H° = -1280. kJ
Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
Chapter 15 Solutions
Atkins' Physical Chemistry
Ch. 15 - Prob. 15A.1STCh. 15 - Prob. 15B.1STCh. 15 - Prob. 15B.3STCh. 15 - Prob. 15C.1STCh. 15 - Prob. 15C.2STCh. 15 - Prob. 15A.1DQCh. 15 - Prob. 15A.2DQCh. 15 - Prob. 15A.3DQCh. 15 - Prob. 15A.1AECh. 15 - Prob. 15A.1BE
Ch. 15 - Prob. 15A.2AECh. 15 - Prob. 15A.2BECh. 15 - Prob. 15A.3AECh. 15 - Prob. 15A.3BECh. 15 - Prob. 15A.4AECh. 15 - Prob. 15A.4BECh. 15 - Prob. 15A.1PCh. 15 - Prob. 15A.2PCh. 15 - Prob. 15A.3PCh. 15 - Prob. 15A.4PCh. 15 - Prob. 15A.5PCh. 15 - Prob. 15A.6PCh. 15 - Prob. 15A.7PCh. 15 - Prob. 15A.8PCh. 15 - Prob. 15A.9PCh. 15 - Prob. 15B.1DQCh. 15 - Prob. 15B.2DQCh. 15 - Prob. 15B.3DQCh. 15 - Prob. 15B.1AECh. 15 - Prob. 15B.1BECh. 15 - Prob. 15B.2AECh. 15 - Prob. 15B.2BECh. 15 - Prob. 15B.3AECh. 15 - Prob. 15B.3BECh. 15 - Prob. 15B.4AECh. 15 - Prob. 15B.4BECh. 15 - Prob. 15B.5AECh. 15 - Prob. 15B.5BECh. 15 - Prob. 15B.6AECh. 15 - Prob. 15B.6BECh. 15 - Prob. 15B.7AECh. 15 - Prob. 15B.7BECh. 15 - Prob. 15B.11AECh. 15 - Prob. 15B.11BECh. 15 - Prob. 15B.12AECh. 15 - Prob. 15B.12BECh. 15 - Prob. 15B.1PCh. 15 - Prob. 15B.2PCh. 15 - Prob. 15B.3PCh. 15 - Prob. 15B.4PCh. 15 - Prob. 15B.6PCh. 15 - Prob. 15B.7PCh. 15 - Prob. 15C.1DQCh. 15 - Prob. 15C.2DQCh. 15 - Prob. 15C.1AECh. 15 - Prob. 15C.2AECh. 15 - Prob. 15C.2BECh. 15 - Prob. 15C.3AECh. 15 - Prob. 15C.3BECh. 15 - Prob. 15C.4AECh. 15 - Prob. 15C.4BECh. 15 - Prob. 15C.5AECh. 15 - Prob. 15C.5BECh. 15 - Prob. 15C.1PCh. 15 - Prob. 15C.2PCh. 15 - Prob. 15C.3PCh. 15 - Prob. 15C.4PCh. 15 - Prob. 15C.5PCh. 15 - Prob. 15C.7PCh. 15 - Prob. 15C.8PCh. 15 - Prob. 15C.9PCh. 15 - Prob. 15D.1DQCh. 15 - Prob. 15D.1AECh. 15 - Prob. 15D.1BECh. 15 - Prob. 15D.2AECh. 15 - Prob. 15D.2BECh. 15 - Prob. 15D.3AECh. 15 - Prob. 15D.3BECh. 15 - Prob. 15D.1PCh. 15 - Prob. 15D.2PCh. 15 - Prob. 15E.1DQCh. 15 - Prob. 15E.1AECh. 15 - Prob. 15E.1BECh. 15 - Prob. 15E.2AECh. 15 - Prob. 15E.2BECh. 15 - Prob. 15E.3AECh. 15 - Prob. 15E.3BECh. 15 - Prob. 15E.5PCh. 15 - Prob. 15F.1DQCh. 15 - Prob. 15F.1AECh. 15 - Prob. 15F.1BECh. 15 - Prob. 15F.2AECh. 15 - Prob. 15F.2BECh. 15 - Prob. 15F.3AECh. 15 - Prob. 15F.3BECh. 15 - Prob. 15F.4AECh. 15 - Prob. 15F.4BECh. 15 - Prob. 15F.5AECh. 15 - Prob. 15F.5BECh. 15 - Prob. 15G.1DQCh. 15 - Prob. 15G.2DQCh. 15 - Prob. 15G.1AECh. 15 - Prob. 15G.1BECh. 15 - Prob. 15.1IA
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