The given species, CHClBrF is optically active or not has to be given. Concept Introduction: The atom which is bonded to all four different groups is said to be chiral. Optical activity: Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active. Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

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Answer 1

Question

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

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Answer 3

Question

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

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Answer 4

Question

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

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Answer 5

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 6

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 7

Chapter 15, Problem 15.35P

(a)

Interpretation Introduction

Interpretation:

The given species, CHClBrF is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given species, NBrCl2H+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given species, PFClBrI+ is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given species, SeFClBrH is optically active or not has to be given.

Concept Introduction:

The atom which is bonded to all four different groups is said to be chiral.

Optical activity:

Molecules which have the tendency to rotate the plane polarized light are said to be optically active. Chiral molecules are optically active.

Molecules which cannot rotate the plane polarized light are optically inactive. Achiral molecules are optically inactive.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 15.2 - Prob. 15.1AFP Ch. 15.2 - Prob. 15.1BFP Ch. 15.2 - Prob. 15.2AFP Ch. 15.2 - Prob. 15.2BFP Ch. 15.2 - How many peaks appear in the NMR spectrum of each...Ch. 15.2 - Prob. B15.2P Ch. 15.2 - Prob. B15.3P Ch. 15.3 - Prob. 15.3AFP Ch. 15.3 - Prob. 15.3BFP Ch. 15.4 - Prob. 15.4AFP

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