The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested. Concept Introduction: Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition. Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically. Addition Reaction: It is a type of reaction in which two reactants adding together to form a single product. It can be said as a reverse reaction of elimination reaction. It is a characteristic reaction of alkane . Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs Stereoisomers a re isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space. Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

Question

Provide the reasonable steps to achieve the following synthesis.

Answer 1

Question

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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Answer 2

Question

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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Answer 3

Question

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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Answer 4

Question

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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Answer 5

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

Answer 6

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

Answer 7

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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Ch. 15.1 - Explain how these Grignard reagents would react...Ch. 15.1 - Recalling the reactions of alcohols from Chapter...Ch. 15.2 - Prob. 15.3P Ch. 15.2 - Show how to prepare each Gilman reagent in Example...Ch. 15.2 - Predict the product of the following reaction.Ch. 15.2 - Show how the following compound could be prepared...Ch. 15 - Complete these reactions involving lithium...Ch. 15 - Show how to convert 1-bromopentane to each of...Ch. 15 - Prob. 15.9P Ch. 15 - Show how to prepare each compound from the given...

Solution Summary: The author explains Simmons-Smith reaction, which is ultrasonication improves the rate of formation of organic zinc compounds. Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs.

Chapter 15 Solutions